Water chemistry in rivers is impacted by a variety of natural and anthropogenic processes including agricultural runoff, urban runoff, storm runoff, groundwater inputs, and the built environment. In this study we used trace element concentrations (including As, B, Ce, Co, Cu, Li, Mn, Rb, Sb, Sr, Tl, V, and Zn) and continuous measurements of flow rates and specific conductance to investigate dynamic processes affecting water quality in a rapidly urbanizing agricultural area typical of the western U.S. The middle Provo River, located in northern Utah, USA, was selected as the study area because it is well instrumented with water quality stations and streamflow gauges. We sampled 6 sites on the middle Provo River and 15 sites on tributaries in the watershed a minimum of 5 times between April 2014 and March 2015 to evaluate potential contributions from surface water and groundwater inputs to the Provo River. Additional water samples were collected at 13 cold, thermal, and mixed cold/thermal springs in Heber Valley during summer 2014 to evaluate regional groundwater chemistry. Samples were also collected during two storm events including high frequency sampling in a tributary and road-puddle samples to characterize potential storm runoff chemistry. Specific conductance data loggers were deployed in tributaries to monitor effects of precipitation and other runoff on the middle Provo River at 15-min intervals. See Table 1 for a summary of sampling events. Middle Provo River water chemistry is impacted by natural groundwater inputs as well as surface water tributaries. Li, B, Sr, As concentrations increased dramatically (3-10 fold) downstream of the confluence with a major tributary, Snake Creek. Snake Creek had average As concentrations of ~15 µg/L above the confluence with Provo River and accounted for roughly 20% of the flow to the middle Provo River, but increased the As concentration in Provo River ~4 fold. Thermal springs had ~20 and ~80 times higher concentrations of As and Li, respectively, relative to cold springs and was found to be a major contributor of trace elements to Snake Creek and the middle Provo River. Cl mixing calculations indicated that groundwater contributions increased downstream with up to 15% of the flow to the middle Provo River being contributed within the most downstream reach. Tributaries were found to impact the Provo River based on specific conductance fluxes in tributaries corresponding to fluxes in the river. Notably, Spring Creek, a dominantly agricultural tributary, accounts for >40% of the annual V load and >18% of the annual U, Mn, Pb, Ba, La, and Ce loads to the middle Provo River. The trace elements B, Li, As, and Sr which are found in high concentrations in groundwater, were strongly correlated with Provo River specific conductance and may indicate a potential method of predicting select trace element concentrations in the middle Provo River based on specific conductance data. Filtered puddle samples collected during a storm event had higher concentrations of Co, Cu, V, and Zn, but lower concentrations of major and select trace elements including As, Li, and Sr, relative to the middle Provo River. This study has implications for understanding water quality in complex coupled human-natural systems.

The relationship between rainfall and runoff was examined for twelve selected Arizona watersheds. Expedient runoff volume model coefficients and runoff curve number model parameters were examined using standardized structure, with modifications to adjust the model for small initial abstractions and large watershed storage capacity. Forest-land management practices were examined for their effects on curve number coefficients. The effects of rainfall characteristics were also evaluated with respect to changes they induce in curve number populations. Evaluations included a runoff fraction, a simple multiplier of storm volume to produce runoff volume. The accuracy of this model is promising for more permeable watersheds.

No description available.

Storm water quality can have a significant impact on receiving water bodies. The chief recipients of these impacts are aquatic life in the receiving water body and downstream water users. Over the last few decades, legislation, regulations, institutions and facilities have evolved to recognize the impact of urban storm water on receiving streams. This increased emphasis has caused contaminants in storm water to be identified as a major concern. This developing concern has generated an increased interest in the water quality of our streams and lakes and emphasized the need for more monitoring efforts. With the passage of the National Pollutant Discharge Elimination System (NPDES) Phase II requirements, small municipalities are responsible for storm water impacts on receiving waters within their jurisdiction. For the purposes of NPDES Phase II requirements, small municipalities are identified as these municipalities that are typically composed of 10,000 but less than 100,000 in population. The purpose of this dissertation is to develop a manual for use by the staff of small municipalities in meeting the requirements prescribed by changes initiated in the NPDES Phase II regulations. Attempts were made to comply with these requirements within a very limited manpower and budget framework and to develop procedures that would allow for permit compliance using testing equipment that was both reliable and robust. The users' manual provides valuable guidance in the establishment of a knowledge base for characterization of the watersheds selected for study. Chapter 3 of the dissertation contains a users' manual, designed for use by municipal staff members in their efforts to comply with the NPDES Phase II requirements. Using the techniques and equipment capabilities developed during the writing of the users' manual a characterization of three watersheds within Denton County, Texas was developed. Non-storm water samples were taken from each of the streams and a baseline analysis was established. The three watersheds represented agricultural, suburban and urban settings. Storm water samples were obtained from multiple storms within all three watersheds and data analysis used to determine the character and impact of urban runoff. Determination of the constituents for analysis was based on monitoring requirements of the NPDES Phase I and II requirements for owners and operators of municipal separate storm sewer systems (MS4) and on the Texas Pollutant Discharge Elimination System (TPDES) Multi-Sector General Permit (MSGP). The three watersheds were determined to have multiple statistically significant differences for some parameters between their Base Flows and Storm Flows. The impact of urban runoff on the receiving waters of these three drainage systems was clearly demonstrated throughout the testing period.

From the Proceedings of the 1978 Meetings of the Arizona Section - American Water Resources Assn. and the Hydrology Section - Arizona Academy of Science - April 14-15, 1978, Flagstaff, Arizona / The runoff curve number rainfall- runoff relationships may be defined in two ways: (1) by formula, which uses total storm rainfall and a curve number, but not intensity or duration descriptors; and (2) rainfall loss accounting using a 4, rate and a specific intensity duration distribution of the function i(t) = 1.5P(5(1 +24t /T)-(1/2)-1) /T, where i(t) is the intensity at time t for a storm of duration T. Thus, the curve number method is found to be a special case of φ index loss accounting. The two methods are reconciled through the identity 1.2S = φT, leading to the relationship CN - 1200/(12 +φT). The effects of rainfall intensity on curve number are felt through deviations from the necessary causative intensity - duration curve. Some sample alternate distributions are explored and the effects on curve number shown. Limitations are discussed.

From the Proceedings of the 1978 Meetings of the Arizona Section - American Water Resources Assn. and the Hydrology Section - Arizona Academy of Science - April 14-15, 1978, Flagstaff, Arizona / Discontinuous water quality data for the San Pedro River in southeastern Arizona is analyzed to illustrate the nature of water quality problems of ephemeral flow. The San Pedro drains a northerly-trending basin of 4,483 square miles, of which 696 are in Mexico and 3,787 in Arizona. Several questions arise in the consideration of a rational management plan: what is the necessity for protection of ephemeral flow quality when the channel consists of a dry wash much of the year, where there is little aquatic or wildlife to protect, and where occasional flow during flood conditions is put to little use by humans; and where and how do we use the ephemeral flow it is indeed decided to utilize it. Such questions as these form the basis of this discussion in an effort to bring out the point that water quality problems of ephemeral flow in arid areas differ from those in the humid zone. It is argued that in between the extremes of prohibiting or treating all runoff or eliminating all sources of pollution, there is actually little that can be done to control all sources of pollution in this typical arid stream, despite the fact that standards, for the most part unattainable, have been set for this flow.

From the Proceedings of the 1972 Meetings of the Arizona Section - American Water Resources Assn. and the Hydrology Section - Arizona Academy of Science - May 5-6, 1972, Prescott, Arizona / Storm runoff from the Tucson metropolitan area is unsuitable for most uses without processing. A lysimeter comprised of a grass and soil filter was constructed and is being evaluated as a water-quality treatment facility. The lysimeter is 200 feet long, 4 feet wide and 5 feet deep, and contains homogeneous calcareous loam covered by common grasses. Experimental apparatus was installed to divert less than a cubic foot per second of runoff from urbanized Arcadia Watershed. Runoff flows by gravity over the lysimeter, where surface inflow, surface outflow and subsurface outflow are measured and sampled. Four trials, each associated with a discrete runoff event, were conducted in the fall of 1971. Water samples were analyzed for inorganic chemical constituents, chemical oxygen demand (COD), coliforms, turbidity and sediment contents. Subsurface-outflow samples from initial trials were high in COD and total dissolved solids, representing soil flushing or leaching. Concentrations of inorganics reached a maximum value within a few hours of initial seepage, and then decreased. The peaking represents a salt build-up between trials. Concentrations of COD, coliforms, turbidity and sediment in subsurface-outflow samples decreased significantly during each trial. Surface-outflow samples had lower turbidity, COD, bacteria and sediment contents than surface-inflow samples. Turbidity, suspended and volatile solids, coliforms and COD in runoff samples may be reduced by grass and soil filtration. Increased grass development and soil settling work to produce a better quality effluent. Quantification of the lysimeter's effectiveness will be useful for urban watershed management.

From the Proceedings of the 1974 Meetings of the Arizona Section - American Water Resources Assn. and the Hydrology Section - Arizona Academy of Science - April 19-20, 1974, Flagstaff, Arizona / Semiarid environments exhibit certain hydrologic characteristics which must be taken into consideration for the effective modeling of the behavior of catchments in these areas. Convective storms, which cause most of the runoff, occur in high intensity and short duration during the summer months and are highly localized so that only a small portion of the catchment actually contributes flow to the storm hydrograph. Also, streams in semiarid catchments are ephemeral with flow occurring only about 1 percent of the time. This study attempts to develop a simple synthetic catchment model that reflects these features of the semiarid environment and for which (1) the simplifying assumptions do not preclude the inclusion of the important components of the runoff process, and (2) parameters of the equations representing the component processes have physical interpretation and are obtainable from basin characteristics so that the model may be applicable to ungaged sites. A reductionist approach is then applied in which the entire catchment is subdivided into a finite number of meshes and the various components of the runoff phenomenon are delineated within each mesh as independent functions of the catchment. Simplified forms of the hydrodynamic equations of flow are used to route flow generated from each mesh to obtain a complete hydrograph at the outlet point.

From the Proceedings of the 1978 Meetings of the Arizona Section - American Water Resources Assn. and the Hydrology Section - Arizona Academy of Science - April 14-15, 1978, Flagstaff, Arizona / The U.S. Environmental Protection Agency 's two-year 208 area-wide Water Quality Management Study for Pima County, Arizona, is discussed in terms of the specific problems of municipal wastewater effluent, industrial wastewater, urban stormwater runoff, land disposal of residual wastes, septic systems, and construction activities related to the City of Tucson urban area. The primary groundwater and the slow cycling of the hydrologic system in this arid urban environment reduce many water pollution problems to insignificant levels in the short term, (2) there does exist significant long-term pollution problems in the area. These problems include urban stormwater runoff and landfill leachate, and are related to the pollution of groundwater recharge and aquifer water supplies, and (3) there is a strong need for total water resource planning in arid urban areas which includes planning for wastewater reuse, water harvesting, and proper management of groundwater recharge systems.