Yes / Recycled aggregate concrete filled stainless steel tube (RAC-FSST) is a new type of composite member combining the advantage of stainless steel and RAC. In this paper, a total of twenty-four RAC-FSST stub columns were tested under axial load, considering the influences of coarse recycled aggregate (CRA) content, steel ratios and compressive strengths of RAC. The obtained results, including the failure patterns, responses of axial load vs. deformation, stress states of external stainless steel tube and inner RAC and confinement effects, were systematically analyzed. Results indicated that all specimens presented good ductility and high residual strengths after reaching the maximum axial load. The elastic stiffness of RAC-FSSTs obviously declined with the increasing CRA content, while the strain at the ultimate load was larger. The inclusion of CRA could advance the occurrence of the confinement and lead to lower confining stress. Based on the experimental results, an analytical model with consideration of confinement action was developed to predict the axial response of RAC-FSST stub columns. Besides, the current design provisions for the normal CFST and RAC-FST members were employed to evaluate their applicability to RAC-FSSTs. In general, the design rules EN 1994-1-1:2004, GB 50936-2014 and T/CECS 625-2019 gave a conservative and relatively accurate prediction on ultimate strength of RAC-FSST stub columns. / This work was supported by the National Natural Science Foundation.

The geotechnical properties of municipal solid waste (MSW) such as compressibility, shear strength and stiffness are of prime importance in design and construction of landfills. However, it is not well clear how the stress-strain and strength characteristics vary with time as the biodegradation of waste continues in the landfill. There is also a need to address the variability of MSW properties and their role in landfill design. The present thesis proposes models for the analyses of stress-strain response of MSW in undrained and drained conditions. The proposed models are based on critical state soil mechanics concept and the modified cam clay model is extended to consider the effects of creep and biodegradation. The models are examined with reference to experimental data and published results of MSW in the form of stress strain response. In addition, the experimental results and the data from published literature are also compared with predictions from hyperbolic model. The proposed models are able to capture the stress strain response of MSW in undrained and drained condition adequately. The applicability of proposed model is presented in terms of shear strength ratio, stiffness ratio and settlement for typical landfill cases. In order to examine the influence of model parameters on shear strength, stiffness ratio and settlement, multilinear regression equations are developed based on response surface method (RSM) for different coefficients of variation (COVs). The effect of variability associated with model parameters is examined using reliability analysis. For better understanding, the present thesis is divided into following seven chapters. Chapter 1 is an introductory chapter, in which the need for use of the constitutive models and its use in engineering response analysis of MSW is presented. Further, the organization of thesis is also presented. Chapter 2 presents various studies with regard to the engineering properties of MSW available in the literature. Different models and approaches proposed by various researchers for the prediction of stress-strain response, time dependent behavior and settlement analysis of the MSW are presented. The uncertainty associated with engineering properties and available methods for reliability analysis and the use of response surface method are presented. Finally, based on the literature review, the scope of the thesis and summary of chapter are presented at the end. Chapter 3 presents composition of MSW, detailed description of the sample preparation, methods adopted in the experimental program and test results of one dimensional compression and consolidated undrained tests. Based on the experimental observations, a constitutive model for municipal solid waste for undrained condition in the framework of modified cam clay model considering mechanical creep and biodegradation mechanisms is proposed. It also provides detailed description of the selection of the input parameters required for the proposed model. Further, the detailed derivation of proposed model and the discussion on evaluation of the input model parameters from triaxial and consolidation tests are presented. The model is examined with reference to the experimental data and published results. The stress strain behavior of MSW is compared with the prediction of stress strain response from hyperbolic model. The comparison of stress strain response is well captured using proposed model for all levels of strain. The major conclusions from the study are presented at the end. Chapter 4 presents experimental results of consolidated drained tests. A constitutive model for MSW for drained condition in the framework of modified cam clay model considering mechanical creep and biodegradation mechanisms is proposed. The model is examined with reference to the experimental data and data from published literature. In addition, stress strain behavior of MSW is compared with the predictions from hyperbolic model. The comparison of stress strain response is well captured using proposed model for all levels of strain. The major conclusions from the study are presented at the end. Chapter 5 presents the applicability of proposed models in terms of shear strength ratio and stiffness ratio for a typical landfill condition. Based on response surface method (RSM), multilinear response surface equations are developed for different variables ( M, λ.b.c.d.Edg ) for different percentages of strain for 10 and 20% COVs of the model parameters. The effect of variability of model parameters is presented in terms of results of reliability analysis for specified performance functions. The major conclusions from the study are presented at the end. Chapter 6 presents an approach for the settlement evaluation of MSW for a typical landfill case of 30 m high. Based on RSM, multilinear response surface equations are developed for the calculation of MSW settlement for 30 years for 10 and 20% COVs. The effect of variability of model parameters is evaluated in term of reliability index for performance function specified in terms of landfill capacity. The major conclusions from the study are presented at the end. Chapter 7 presents a brief summary and conclusions from the various studies reported in the present thesis.

The concept of reinforcement was developed in late 20th century and since then till the recent past there are many works carried out on the effect of fibers in imparting strength and stiffness to the soil. Experimental investigations on fiber reinforced soils showed an increase in shear strength and reduction in post peak loss of strength due to the reinforcement. Analytical/mechanistic models are developed to predict the stress-strain response of fiber reinforced soil (under discrete framework, energy dissipation methods, force equilibrium methods etc). Numerical investigations are also carried out, and it was observed that the presence of random reinforcing material in soils make the stress concentration diffuse more and restrict the shear band formation. Soil properties vary from point to point at micro level and influence stress mobilization. Hence, there is a need to carry out probabilistic analysis to capture the effects of uncertainties and variability in soil and their influence on stress-strain evolution. In the present thesis an attempt has been made to propose a mechanistic model that predicts the stress-strain response of fiber reinforced soil and also considers the effect of anisotropy of fibers. A stochastic/probabilistic model is developed that predicts the stochastic stress-strain response of fiber reinforced soil. In addition, probabilistic analysis is carried out to observe the effect of number of fibers across the shear plane in imparting shear resistance to soil. The mechanistic model and stochastic models are validated with reference to the experimental results of consolidated undrained (CU) triaxial tests on coir fiber reinforced red soil for different fiber contents. The entire thesis is divided into six chapters. Chapter-wise description is given below. Chapter one presents a general introduction to the works carried out on fiber reinforced soils and also the investigations carried out on probabilistic methodologies that takes into account the soil variability. Thus, the chapter gives an outline of the models developed under mechanistic and probabilistic frameworks in the thesis. The objectives and organization of the thesis are also presented. Chapter two presents a detailed review of literature on the role of fibers in fiber reinforced soil. The details of experimental investigations carried out and models developed are explained briefly. Also, the literature pertaining to the role of variability in soil on its engineering behavior is presented. Based on the literature presented in this chapter, concluding remarks are made. Chapter three presents the details of a new mechanistic model developed based on modified Cam-clay model. This model considers the effect of fiber content and also the effect of anisotropy due to fibers. The predictions from the mechanistic model are compared with the experimental results. Under anisotropic condition, as angles of inclination of fiber vary from 0° to 90° with the bedding plane, it is observed that the strength increment in the reinforced soil is not as significant as that observed in isotropic case. Horizontal fibers turn out to be most effective since they are subjected to maximum extension thereby inducing tensile resistance which in turn contributes for strength increase in fiber reinforced soil. Chapter four presents a new approach to predict the stochastic stress-strain response of soil. Non-homogeneous Markov chain (multi-level homogeneous Markov chain) modeling is used in the prediction of stochastic response of soil. The statistical variations in the basic variables are taken into account by considering the response quantities (viz. stress at a given strain or settlement at a given load level) as random. A bi-level Homogeneous Markov chain predicts the stochastic stress-strain response efficiently. The predicted results are in good agreement with the experimental results. An illustration of this model is done to predict the stochastic load-settlement response of cohesionless soil. A simple tri-level homogeneous Markov chain model is proposed to predict settlements of soil at a given load for an isolated square footing subjected to axial compression. A parametric study on the effect of correlation coefficient on the prediction of settlements is performed. Chapter five presents the results of probabilistic analysis carried out to determine the effect of number of fibers across the shear plane in improving the shear strength of soil. It is observed that as the percentage of fibers in the specimen increases, the probability of failure of specimen under the same stress condition reduces and thus the reliability of the fiber reinforced soil system increases. In Chapter six, a summary of the important conclusions from the various studies reported in the dissertation are presented.

Yttria-stabilized zirconia-based thermal barrier coating systems are the most widely used commercial coatings in the industry, with practical applications in aircraft engines and land-based power turbines. The purpose of thermal barriers is primarily to protect the substrate from high temperatures and also to increase its oxidation resistance. Currently, concerning the relatively frequent volcanic eruptions and increasing air traffic intensity in desert areas, increased attention is being paid to the development of new thermal and environmental coatings that will withstand the so-called CMAS attack and still successfully meeting the strictest requirements of the aerospace industry. Two newly developed experimental coatings consisting of three successive layers have been developed for this work. The upper two layers are thermal insulating ceramic coatings, where two different uppermost coatings were deposited. The first uppermost layer of the coating is a mixture of mullite and hexacelsian in a ratio of 70/30 wt. %. The second upper most type of coating consists of Al6Si2O13 + MgAl2O4 + BaCO3 in a ratio of 6:3:1 wt. %. The interlayer is made of the commercially utilized yttria-stabilized zirconia. The metallic CoNiCrAlY coating, which is directly deposited on the nickel-based superalloy MAR-M247, fulfils a compensatory function between the mechanical properties of the nickel superalloy and the ceramic coating. The thermal and environmental barrier system was deposited using air plasma spraying (APS) technology. The main objective of this work was to evaluate the effect of the newly developed thermal and environmental barrier coating, which has a high potential for the protection of component surfaces in an aggressive environment, on isothermical and thermomechanical fatigue behaviour of nickel-based superalloy MAR-M247. Low cycle fatigue tests were performed in strain control mode with constant strain amplitude on both uncoated and TEBC coated superalloy. Fatigue hardening/softening curves, cyclic stress-strain curves and fatigue life curves in the representation of total strain amplitude, plastic strain amplitude and stress amplitude on the number of cycles to failure were obtained. Microstructural analysis of MAR-M247 superalloy and a newly developed experimental coating was performed in a scanning electron microscope. The fatigue crack initiation sites were identified and the process of fatigue crack propagation was described. The dislocation arrangement after fatigue loading of MAR-M247 was investigated in a transmission electron microscope. The findings of isothermical and thermomechanical low cycle fatigue behaviour of uncoated and TEBC coated MAR-M247 superalloy and identification of damage mechanisms presented in this dissertation will improve the estimation of safe-life that is particularly relevant to aircraft engines components.

The compression behavior of a newly developed near eutectic Al-Si based cast alloy with three different microstructures has been investigated in the present work. Microstructures with modified and unmodified Si particles and matrix with different tempers are investigated. The main objective of this work is to understand the effect of heat treatment and modification on the fracture behavior of the alloy under compression. This alloy is subjected to compressive loading at different strain rates and temperatures during the operation of the engines. Hence, the effect of strain rates and temperatures is also considered. The compression tests are carried out at different strain rates from quasi-static to dynamic viz., 3*10-4 to 102/s and three different temperatures RT, 100°C and 200°C. Microstructure of the alloys studied predominantly consists of eutectic colonies of α-Al and Si with a few interspersed α-Al dendrites. Modified alloy has more globular Si particles than unmodified alloy. Heat treated alloys are found to have hardening precipitates S’ & Al7Cu4Ni and 3-7 atomic layer thick zones, which may be precursors to S’ phase. A variety of large intermetallics, viz., plate like particles Al4.5FeSi, Chinese script like particles Al19Fe4MnSi2 and bulky phase Al3NiCu are also observed in the alloys. Mechanical behavior of the alloys is found to be different for different microstructures. Modification improves strength and ductility. Heat treatment improves strength of the alloy at the expense of ductility. A transition in mechanical behavior is observed after a particular strain rate for all the alloys studied. This transition strain rate is dependent on heat treatment, Si particle size and temperature. This transition can be explained on the basis of dislocation-precipitate and dislocation-Si particle interactions. Work hardening behavior of the alloys depends on the matrix microstructure in the unmodified alloys, and both matrix and particles play a role in the modified alloy. A statistically robust quantitative micro structural analysis has been carried out after compressing the samples at various strain rates and temperatures. The unique contribution of this work is the understanding of combined effect of strain rate and temperature on Si particle fracture characteristics in the alloy with different microstructures. From the fracture characteristics of Si particles, it is concluded that both dislocation pile-up mechanism and fibre loading are responsible for particle fracture in the modified alloy, whereas the fibre loading mechanism alone is sufficient to explain the particle fracture characteristics in the unmodified alloy. Si particles in the modified condition are found to cleave along the lowest surface energy planes {112} & {110} and the particles with orientations {112} & {111} are more prone to fracture. In addition to Si particle fracture, elongated Fe rich intermetallic particles are also seen to show peculiar fracture behavior. The Al4.5FeSi intermetallics with (100) as the plane of the plate cleave along (100) planes. This is a novel finding in this work and could have immense implications on the role of Fe impurities in the fracture behavior of these alloys. Moreover, since these cleavage fractures are seen to be more than 200 microns in size (which implies that the real penny shaped crack would be even larger) their role cannot be assumed to be negligible, as was previously thought. The load sharing between the Al matrix and eutectic Si particles are simulated by microstructure based finite element modeling. The program OOF (Object-Oriented Finite element analysis) is used to generate the finite element meshes for real microstructures with different Si morphology. The experimentally obtained stress – strain properties of the alloy is given as an input to describe the plastic behavior of the Al matrix, in the finite element simulation. This analysis helps to understand the effect of particle size, shape, orientation & clustering and matrix temper on the stress transferred to the Si particles. Combination of Electron Back-Scattered Diffraction (EBSD) and frequency shift, polarized micro-Raman technique is applied to validate the stress states in Si particles with {111} orientations. The stress at fracture of Si particles is also estimated from Raman technique. Even though the alloys with different microstructures show different mechanical behavior, the sequence of fracture mechanisms is found to be same for all the alloys. The failure occurs in three stages: cracking of Si particles at low strains, micro-crack formation along the fractured particles, micro-crack coalescence and propagation leading to final failure. Thus, the proposed analysis links various deformation mechanisms ranging from nano precipitate-dislocation interactions to micro short-fiber theory of load sharing by eutectic silicon along with coupled effect of strain rate and temperature. In addition, negative strain rate sensitivity is also observed in the lower strain rate regimes (3*10-4, 10-3& 102/s) at RT and 100°C for all the three alloys, and serrated flow is also observed in the same strain rate and temperature regimes. Some of the features of serrated flow can be explained by the dynamic strain aging model and some other features by precipitate shearing.

Superaustenitická korozivzdorná ocel typu 22Cr25NiWCoCu určená pro vysokoteplotní aplikace v energetickém průmyslu byla studována za podmínek nízkocyklové únavy při pokojové a zvýšené teplotě. Jednotlivé vzorky byly podrobeny různým zátěžným procedurám, což umožnilo studium materiálové odezvy spolu s mechanismem poškození. Křivky cyklického zpevnění/změkčení, cyklického napětí a Coffin-Mansonovy křivky byly vyhodnoceny. Únavová životnost materiálu byla diskutována s ohledem na uplatňované mechanismy poškození, které se vyvinuly za specifických zátěžných podmínek. Standardní izotermální únavové experimenty byly provedeny při pokojové a zvýšené teplotě. Hysterezní smyčky zaznamenané během cyklického zatěžování byly analyzovány pomocí zobecněné statistické teorie hysterezní smyčky. Pro různé amplitudy napětí byla určena jak distribuce hustoty pravděpodobnosti interních kritických napětí (dále PDF), tak rovněž zjištěn její vývoj během cyklického namáhání. Zjištěné průběhy PDF byly korelovány s vývojem povrchového reliéfu a vnitřního dislokačního uspořádání zdokumentované pro obě teploty pomocí rastrovací elektronové mikroskopie (SEM) vybavené technikou fokusovaného iontového svazku (FIB), která umožnila rovněž efektivní studium nukleace povrchových únavových trhlin. Při cyklickém zatížení při pokojové teplotě byla pozorována lokalizace cyklické plastické deformace do perzistentních skluzových pásů (PSP). V místech, kde tyto PSP vystupují na povrch materiálu byly pozorovány perzistentní skluzové stopy (PSS) tvořené extruzemi a intruzemi. Postupné prohlubování intruzí, zejména na čele nejhlubší intruze, vede k iniciaci únavové trhliny. Odlišný mechanismus tvorby trhlin byl zjištěn při únavové zkoušce při zvýšené teplotě, kde zásadní roli hrál vliv prostředí. Rychlá oxidace hranic zrn a jejich následné popraskání představuje dominantní mechanismus v I. stádiu nukleace trhlin. Aplikace desetiminutové prodlevy v tahové části zátěžného cyklu vedlo k vývoji vnitřního (kavitačního) poškozování. Mechanismy vnitřního poškozování byly studovány na podélných řezech rovnoběžných s napěťovou osou zkušebních vzorků. Trhliny a jejich vztah k hranicím zrn a dvojčat byly studovány pomocí difrakce zpětně odražených elektronů (EBSD). Vliv prodlevy na únavovou životnost byl korelován s vývojem povrchového reliéfu a vnitřního poškození. Vzorky z uvedené oceli byly rovněž podrobeny zkouškám termomechanické únavy (TMF), při nichž se v čase mění jak zátěžná síla tak i teplota. Termomechanické únavové zkoušky v režimu soufázném (in-phase) a protifázném (out-of-phase) byly provedeny jak s prodlevou, tak i bez ní. Ve všech případech bylo pozorováno rychlé cyklické zpevnění bez ohledu na použitou amplitudu deformace, u vzorků testovaných v out-of-phase režimu byla zjištěna tendence k saturaci. Zkoumáním povrchového reliéfu za pomocí technik SEM a FIB byla odhalena přednostní oxidace hranic zrn a následné praskání těchto hranic kolmo k ose zatížení. Prodlevy v cyklech při maximálním napětí vedly ke zvýšení amplitudy plastické deformace a následně ke creepovému poškození ve formě vnitřních kavit a trhlin. Interkrystalické šíření trhlin bylo pozorováno na vzorcích testovaných v režimu in-phase. Vývoj poškození v režimu out-of-phase nebyl principiálně ovlivněn zařazením prodlevy do zátěžného cyklu. Charakteristickým znakem namáhání v režimu out-of-phase je nukleace několika trhlin v homogenní oxidické vrstvě jdoucích napříč zrny kolmo k ose zatěžování.