The research examined the relationships between the morphological structures and features of Arabic and English verbs. An examination of the corpus in the research, which compiled 2000 verbs and their translation from various texts, showed that correlation between verb aspects are minimal. Therefore it is admissible to say that there is no correlation between morphological aspects and categories of Arabic and English verbs. Through analysis of Arabic verb patterns, the research demonstrated the primacy of a morpheme as one of the significant linguistic structural units that incorporates semantic and syntactic features, and also as a pivotal translation unit. The data analysis also signified that genre variation in Arabic is well established and can be clearly identified through morphological aspects of the verb and their distribution in text types. / Master of Arts (Hons)

In this work, the relationship between grain boundary crystallography and grain boundary atomic structure is examined, using [1 0 0] - symmetric tilt grain boundaries in nickel. The structural unit model is used as a benchmark to evaluate the atomic structure description capacities of an emerging structural descriptor, the local environment representation, which itself is a refinement of the also-emergent Smooth Overlap of Atomic Positions (SOAP) descriptor. We show that the local environment representation encodes both the information of the structural unit model and additional information, such as distortion in the structural units and the arrangement of the structural units at the interface. The use of the local environment representation permits the use of a visualization tool known as SPRING to represent structural similarities between grain boundaries. With the SPRING representation, we produce objective evidence of a relationship between crystallography and atomic structure, at least for [1 0 0] - symmetric tilt grain boundaries.

During a whole period of time which fibre-reinforced polymers have been used in the building industry, in dominating bonding agent has been the organic resins. There is no doubt about their advantages, but at the same time, they have two weaknesses: they are not fire resistant and they have no resistance to high temperature. Those are the reasons why the research on alternative materials which could replace organic matrix has been undertaken. The goal of the work is to maintain mechanical properties of fibre-reinforced polymer with organic matrix. Of course, an emphasis is placed to fulfilling ecological standards which are required from ecological material. An aluminosilicate inorganic matrix can meet them all. It is non-flammable, does not produce any toxic matter in contact with fire and the energy consumption during production process is lower than in case of the organic matrix. This work includes study and analysis of selected raw materials as well as their influence and impact on final reaction products which are created in inorganic matrix. A part of this work is also a design of the inorganic matrix recipe.

Au cours de ce travail, nous avons étudié deux types de défauts interfaciaux: domaines d’inversion (DI) et joints de grains (JG) dans des semiconducteurs de structure wurtzite (nitrures- d’éléments III, ZnO et l’hétérostructure ZnO/GaN) en utilisant le MET haute résolution et la modélisation ab initio. Dans le cas des DI, nos analyses théoriques montrent qu'une configuration tête-à-tête avec une séquence d'empilement à l’interface AaBbAa-AcCaA (H4) est la structure la plus stable dans les composés binaires (nitrures et ZnO wurtzites). De plus, un gaz d’électrons (2DEG) ou de trous (2DHG) à 2 dimensions est formé pour les configurations « tête-à-tête » ou queue-à-queue. A l’interface ZnO/GaN, l'observation de MET très haute résolution a confirmé la configuration H4 avec une interface -Zn-O-Ga-N. Notre modélisation théorique a mis en évidence la formation d’un gas de trous à 2 dimensions à cette hétérointerface. Nous avons aussi réalisé l’étude topologique, théorique et par MET des joints de grains de rotation autour de l’axe [0001] dans ces matériaux. Dans le GaN, nous avons trouvé que les plans du joint sont simplement formés par des dislocations de type a déjà connues pour le matériau en couche mince. Par contre, dans ZnO, la théorie topologique est complétement démontrée, et la dislocation [101 ̅0] est une brique de base dans la constitution des joints de grains avec des cycles d’atomes 6-8-4-. / In this work, we investigated two kinds of interfacial defects: inversion domain boundaries (IDBs) and grain boundaries (GB) in wurtzite semiconductors (III-nitrides, ZnO and ZnO/GaN heterostructure) using high-resolution TEM and first-principle calculations. For IDBs, theoretical calculation indicated that a head-to-head IDB with an interfacial stacking sequence of AaBbAa-AcCaA (H4) is the most stable structure in wurtzite compounds. Moreover, 2-dimensional electron gas (2DEG) and 2-dimensional hole gas (2DHG) build up in head-to-head and tail-to-tail IDBs, respectively. Considering the IDB at the ZnO/GaN heterointerface, TEM observations unveiled the H4 configuration with a -Zn-O-Ga-N interface. Moreover the theoretical investigation also confirmed stability of this interface along with the corresponding formation of a 2DHG. A detailed topological, TEM and theoretical investigation of [0001] tilt Grain Boundaries (GBs) in wurtzite symmetry has also been carried out. In GaN, it is shown that the GBs are only made of separated a edge dislocations with 4, 5/7 and 8 atoms rings. For ZnO, a new structural unit: the [101 ̅0] edge dislocation made of connected 6-8-4-atom rings is reported for the first time, in agreement with an early theoretical report on dislocations and jogs in the wurtzite symmetry.