<p>Fresh groundwater quality and availability in coastal areas is affected by seawater intrusion into coastal aquifers, and coastal water quality and ecosystem status may be significantly affected by groundwater pollutants that are transported into coastal waters by submarine groundwater dis-charge (SGD). This thesis uses an overall regional perspective for investigating: i) seawater intru-sion and its possible control in sustainable coastal groundwater management; ii) SGD and its relevant quantification as one interacting part among the diverse main regional pathways of freshwater and tracer/pollutant inputs from land to sea; and iii) the integrated system functioning of both i) and ii) as main components of the same coastal groundwater system.</p><p>Results show that intensive pumping rates may be maintained for a long time before major re-gional seawater intrusion problems are recognized by too high salinities in pumped groundwater. After such late recognition, pumping wells are no longer useful and a common strategy of mov-ing groundwater pumping further upstream from the coast only increases the extent of the salt-water intrusion zone into the aquifer. An alternative strategy may be to control seawater intrusion through artificial groundwater recharge, for instance by sufficiently treated wastewater, which may considerably reduce long-term trends of salinity increase in pumped groundwater, even for small artificial recharge rates compared to pumping rates. In general, account for natural spatial-temporal variability and randomness may be essential for relevant prediction of groundwater dynamics for management purposes. Spatial and temporal randomness effects, however, may not be additive, but rather largely overlapping, with either spatial or temporal randomness being the dominating part that must be accounted for in predictive groundwater dynamics calculations. Aquifer depth is identified as an important control parameter in this context, yielding much greater temporal randomness effects in shallow than in deep aquifers.</p><p>Combined simulation results suggest a simple, approximately linear regional relationship between total SGD and its hydrologically determined freshwater component. Tidal oscillation may signifi-cantly affect such linear dependence of steady-state SGD, but primarily for low SGD conditions. High SGD appears to depend mainly on a dominant freshwater component, which effectively counteracts density-driven flow of seawater into the aquifer and thus decreases also effects of sea-level oscillation on the seawater component of total SGD. Comparative analysis between different SGD estimation methods in different reported high-SGD regions of the world indicates possible anomalously large regional SGD estimation from tracer concentrations in coastal waters, by confusing different main pathways of groundwater flow and pollutant inputs to the sea.</p>

Fresh groundwater quality and availability in coastal areas is affected by seawater intrusion into coastal aquifers, and coastal water quality and ecosystem status may be significantly affected by groundwater pollutants that are transported into coastal waters by submarine groundwater dis-charge (SGD). This thesis uses an overall regional perspective for investigating: i) seawater intru-sion and its possible control in sustainable coastal groundwater management; ii) SGD and its relevant quantification as one interacting part among the diverse main regional pathways of freshwater and tracer/pollutant inputs from land to sea; and iii) the integrated system functioning of both i) and ii) as main components of the same coastal groundwater system. Results show that intensive pumping rates may be maintained for a long time before major re-gional seawater intrusion problems are recognized by too high salinities in pumped groundwater. After such late recognition, pumping wells are no longer useful and a common strategy of mov-ing groundwater pumping further upstream from the coast only increases the extent of the salt-water intrusion zone into the aquifer. An alternative strategy may be to control seawater intrusion through artificial groundwater recharge, for instance by sufficiently treated wastewater, which may considerably reduce long-term trends of salinity increase in pumped groundwater, even for small artificial recharge rates compared to pumping rates. In general, account for natural spatial-temporal variability and randomness may be essential for relevant prediction of groundwater dynamics for management purposes. Spatial and temporal randomness effects, however, may not be additive, but rather largely overlapping, with either spatial or temporal randomness being the dominating part that must be accounted for in predictive groundwater dynamics calculations. Aquifer depth is identified as an important control parameter in this context, yielding much greater temporal randomness effects in shallow than in deep aquifers. Combined simulation results suggest a simple, approximately linear regional relationship between total SGD and its hydrologically determined freshwater component. Tidal oscillation may signifi-cantly affect such linear dependence of steady-state SGD, but primarily for low SGD conditions. High SGD appears to depend mainly on a dominant freshwater component, which effectively counteracts density-driven flow of seawater into the aquifer and thus decreases also effects of sea-level oscillation on the seawater component of total SGD. Comparative analysis between different SGD estimation methods in different reported high-SGD regions of the world indicates possible anomalously large regional SGD estimation from tracer concentrations in coastal waters, by confusing different main pathways of groundwater flow and pollutant inputs to the sea. / QC 20101012

[Truncated abstract] It has become widely apparent throughout the world that the discharge of nitrogen contaminated groundwater is reducing surface water quality of marine coastal waters, and is subsequently contributing to the decline of benthic habitats such as seagrasses. A process-based understanding of submarine groundwater discharge (SGD) has lagged behind these impacts, and this lack of understanding is addressed by this thesis. This thesis, of the spatial and temporal complexity of SGD, has uncovered and answered questions regarding the sources, fate and transport of SGD in a complex coastal discharge environment. Radium isotope techniques, groundwater biogeochemical investigations and HAMSOM surface water modelling have identified the magnitude, transport and fate of SGD in Cockburn Sound, a semienclosed embayment in Western Australia. A temporal periodicity that encompassed end-of-winter, early-summer, late-summer and mid-winter regimes of hydrology and oceanography, was employed in field studies that spanned the years 2003, 2004 and 2005. ... The fate of the groundwater in the semi-enclosed embayment was investigated using knowledge of surface water currents. Localised regions of high groundwater influence were identified in the surface waters of the embayment, and through the application of a 3-dimensional hydrodynamic model (HAMSOM) it was discovered that, despite similar total volume residence times, variation in the surface flow regime resulted in very different fates for groundwater discharged to the embayment. For three of the four investigated seasonal regimes, groundwater discharged at the shoreline was shown to be rapidly exported out of the embayment (within approximately 1-3 days). During mid-winter very different wind and current regimes existed, resulting in the lateral transport of shoreline groundwater across the embayment, presenting potential for nutrient recirculation within the system for longer time periods (10+ days). Lateral transport of groundwater during mid-winter from the limestone region of the coastline, may contribute to peaks in phytoplankton biomass that have been reported to occur at this time. The investigations into spatial, temporal and biogeochemical dynamics of SGD provided for further dissertation of the processes that affect these dynamics, at a scale that was relevant to marine embayments, coastal aquifers and the coastal ecosystem. It is hoped that this thesis will contribute to a better understanding of the inputs, dynamics and impacts of SGD on coastal ecosystems and lead to improved management strategies for coastal zones.

Utilizing the analytical solution of the steady state sharp interface saltwater intrusion model in coastal aquifers, a multi-objective optimization formulation of pumping rates and well locations in a coastal aquifer is formulated to solve problems in water management practice. The proposed optimization problem uses progressive genetic algorithm technique and the method developed is applied to the previous work of Cheng et al. [2000]. Through this analysis, several other applications are provided to demonstrate the use of the model in practical applications. This work is the first to optimize pumping rates as well as well locations simultaneously in coastal aquifer management. Known the limitation of the analytical solution, the work is expanded to cover the physics of saltwater intrusion in a more realistic way. This is variable density flow in a variably saturated porous medium. In this method, mixing between two fluids such as saltwater and freshwater can be described and the porous medium is also expanded to cover saturated and unsaturated zones together. One of the objectives is to develop a three dimensional physical model, verify the model, and apply to various applications in coastal aquifers. The developed model, TechFlow, is used to investigate instability issues associated with the numerical solution of the Elder problem in the perspective that includes physical instability issues associated with density differences used in numerical solutions, sensitivity of the solution to idealization irregularity, and the importance of accurate estimation of the velocity field and its association to the grid density levels that is necessary to solve the problem accurately. Saltwater intrusion hydrodynamics in a beach under the influence of tidal effects is also investigated using TechFlow. Based on the results of TechFlow with the use of various boundary conditions for the transport equation, the saltwater intrusion hydrodynamics in a beach under the influence of tidal effects shows unique dynamics. These solutions are primarily affected by density differences, tidal effects on a mild slope, variably saturated porous medium and finite domain solution condition. TechFlow is also used to investigate saltwater upconing beneath pumping wells both two- and three-dimensional applications.

Optical parameters measured via absorption spectroscopy and high-resolution fluorescence spectroscopy were used to characterize dissolved organic matter (DOM) in the springshed of Kings Bay, a spring-fed estuary located on Florida's Springs Coast. Over the past 40 years, springs supplying groundwater to Kings Bay have shown an increase in nitrate concentration. The overall goal of this project was to fingerprint wells and spring sites with elevated nitrogen concentrations using CDOM optical properties and establish relationships between nutrient and optical parameters. Samples were obtained from various sites: springs, Kings Bay surface (KBS), wells, coastal waters in and at the mouth of Crystal River (Coast) and lakes and rivers (LNR), during dry and wet seasons. The relationships between the environmental parameters and traditional optical parameters which provide insight into source characteristics were analyzed. Excitation emission matrix spectroscopy (EEMS) provided information about the concentration and chemical nature of organic matter in the study area. CDOM optical properties combined with salinity clearly separated the sources of fixed nitrogen in the Bay. Northern springs with elevated dissolved inorganic nitrogen (DIN) concentration had lower salinities and showed a presence of protein peaks. CDOM concentration was negatively correlated with total nitrogen (TN) and DIN, which suggests that these are subjected to anthropogenic influences. Humic peaks dominated the composition of the southern springs. CDOM concentrations were much higher than in the northern springs and there was a positive correlation between CDOM and both TN and DIN. These findings suggest that the fixed nitrogen in the southern springs is naturally occurring organic matter and the low concentrations may partially be a result of subsurface mixing of saltwater and freshwater in the aquifer. Thus, hypothesis testing showed that there was a significant difference between northern and southern springs Hypothesis testing also showed that there is a significant and unexpected positive relationship between CDOM and salinity studying Kings Bay, which is due to the low CDOM concentration in the springs discharging fresh water. This unique dataset also determined that the intercept of the mixing line was significantly different form zero. This indicates that CDOM is present and detectable at very low concentrations. Parallel Factor Analysis (PARAFAC) was used to evaluate CDOM composition from excitation emission matrix spectra (EEMs) and five components were identified: two humic, two marine humic, and one protein-like. The marine-like components, peak M, were produced in the marine environment and in meteoric groundwater. The study found a unique groundwater marker for coastal regions. Northern Kings Bay sites were characterized by a protein-like component, which has been associated with wastewater. Additional optical and environmental parameters were used in discriminate analysis, which successfully identified the CDOM markers for both natural and anthropogenic sources of nutrients in the environment. It is vital to improve the analysis of water, nutrients, and carbon from groundwater discharge into the coastal zone. Elevated DIN concentrations in groundwater are a widespread problem in Florida and over the past 30 years many spring waters have shown an increase in DIN concentrations. Nutrient discharge into delicate coastal areas can lead to ecological concerns. Investigating CDOM and nutrient distribution together can be a beneficial tool that can help differentiate sources from riverine/lacustrine, estuarine, marine, groundwater, and sewage impacted categories.

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Tese(doutorado) - Universidade Federal do Rio Grande, Programa de Pós–Graduação em Oceanografia Biológica, Instituto de Oceanografia, 2012. / Submitted by Cristiane Gomides (cristiane_gomides@hotmail.com) on 2013-12-15T10:09:04Z No. of bitstreams: 1 karina.pdf: 8139075 bytes, checksum: c30bac487b6f4defadafc03c71b60d50 (MD5) / Approved for entry into archive by Sabrina Andrade (sabrinabeatriz@ibest.com.br) on 2013-12-18T17:52:30Z (GMT) No. of bitstreams: 1 karina.pdf: 8139075 bytes, checksum: c30bac487b6f4defadafc03c71b60d50 (MD5) / Made available in DSpace on 2013-12-18T17:52:30Z (GMT). No. of bitstreams: 1 karina.pdf: 8139075 bytes, checksum: c30bac487b6f4defadafc03c71b60d50 (MD5) Previous issue date: 2012 / A alta produtividade na zona costeira e na Plataforma Continental do Sul do Brasil é dada pelo aporte de nutrientes, os quais são determinantes para a produção primária. As regiões de plataforma (Santa Marta-SC 28,60ºS e Albardão-RS 33,20ºS) foram selecionadas por apresentarem características diferenciadas em relação à topografia, sazonalidade e dinâmica das massas de água. Sendo assim, essas possuem diferentes mecanismos de fertilização, além dos aportes continentais. A proximidade à zona de Convergência Subtropical (CST) é determinante para a produtividade dessas regiões, visto que: no inverno, a intrusão da Água Subantártica de Plataforma na região do Albardão aumenta consideravelmente as concentrações de nutrientes na região e; no verão, a Água Central do Atlântico Sul resultado da CST aflora na região de Santa Marta, sendo responsável por 60% da produção nova local. Além disso, aportes subterrâneos foram evidenciados tanto na zona costeira quanto na região de plataforma. No extremo sul do Brasil verificou-se, mediante a variação espaço-temporal de isótopos naturais de rádio e radônio, a ocorrência de advecção de água subterrânea ao longo de toda a costa, desde a desembocadura da Lagoa dos Patos até as proximidades do Uruguai (média: 2,17± 0,2 cm d-1). Com a aplicação de modelos pré-estabelecidos, foi possível calcular os fluxosde nutrientes para a zona costeira (NIT: 21 105 mol d-1) e avaliar o potencial produtivo relacionado a essas descargas (2800 gC m-2 ano-1). Desse modo, entende-se que a parcela de água subterrânea deva ser definitivamente incluída no balanço de massas da região, uma vez que apresenta um potencial produtivo de 7 a 32 vezes maior quando comparado às outras regiões onde a estimativa foi realizada. / High productivity on the coastal region and on the Southern Brazil Continental Shelf is provided by the nutrient input which is fundamental to primary productivity. The regions of Santa Marta, SC (28.60ºS) and Albardão, RS (33.20ºS) were selected due to their special characteristics regarding the topography, seasonality and dynamics of their water mass. Therefore, these areas have different fertilization mechanisms besides the continental input. The proximity to the subtropical convergence zone (SCZ) is determinant in relation to productivity because, in winter, the intrusion of the Subantarctic Shelf Water (SSW) in the Albardão region considerably increases the nutrient concentration whereas, in summer, the South Atlantic Central Water (SACW) that results from the SCZ, moves to the Santa Marta region and is responsible for 60% of the new local production. In addition, subterraneous input was observed both on the coastal areas and on the shelf. In southern Brazil, spatial - time variations of radionuclides (Ra e Rn) show the occurrence of groundwater advection along the coast, from the mouth of Patos Lagoon to Uruguay rates (average: 2.17± 0.2 cm d - 1). Using mathematical models, it was possible to calculate the discharge of nutrients on the coastal zone (TIN: 21105 mol d - 1) and evaluate the productive potential regarding the Submarine Groundwater Discharge (2800 gC m - 2 y - 1). Thus, this study suggests that the portion of ground water should definitely be included in the mass budget of the region, since its productive potential is 7 to 32 times higher by comparison with other regions where this estimate was also carried out.