The work is focused on the possible use of secondary raw materials of the energy industry in the construction industry, particularly in concrete applications, where as the main raw material of the binder composition are used solid fluidized bed combustion residues - filter and ground. The aim of this work is to prepare concrete or concretes based on solid residues from fluidized bed combustion, that will fulfill or at least approximately approach by their parameters to commonly used concretes based on portland cement. The experimental part is divided into several chapters, at first the results of analyzes of feedstock and solid residues from fluidized bed combustion, portland cement and calcium hydroxide. Other chapters describe proposals for alternative binders, concrete, characterization and testing. Mainly were observed changing properties of the prepared concretes by changing the ratio of binders and aggregates. In tests were evaluated mainly mechanical properties and phase composition.

In the past three decades, a new group of concrete admixtures, termed &ldquo / superplasticizers&rdquo / , were introduced to the concrete industry. They have gained wide acceptance because of their many advantages. The addition of superplasticizers to concrete improves the workability and strength of concrete. In this study, the effect of the chemical structure of poly (4-styrenesulfonic acid-co-maleic acid) sodium salt (SSAMA), which contains both sulfonic and carboxylic acid groups, which is a new superplasticizer, was analyzed. Two different molecular weights of PEG (polyethylene glycol monomethyl ether) were grafted to this water-soluble copolymer at different weight compositions. The structures of synthesized copolymers were verified by FTIR and NMR analyses. The molecular weight difference of the grafted copolymers with different side chain lengths was determined by dilute solution viscosimetry. The effects of chemical structure of grafted copolymers on the fluidity of cement paste and the mechanical properties of the mortars were investigated. The zeta potential measurements revealed the interactions between the cement particles and polycarboxylate type superplasticizers. The maximum fluidity was achieved for the PEG grafted copolymer with the weight ratio 3:3. The mechanical properties of this copolymer showed the highest flexural and compressive strength compared to other copolymers. The addition of various Li salts to SSAMA affected the ionic medium, therefore, the dispersion performance of cement paste and the mechanical properties of the mortars improved. The mixture of LiCl: SSAMA in 1:1 mol ratio exhibited the maximum fluidity compared to other Li salts and their compositions. This mixture gave the highest flexural strength but the mixture of Li2CO3 in 1:1 composition gave the highest compressive strength in each salt mixtures.

Preplaced aggregate concrete (PAC) is produced by grouting high workability cement based grouts among the voids of compacted coarse aggregate mass. Because of its low shrinkage, PAC has been used for many repair jobs like; tunnel lines, dams and bridge piers. Moreover, it has been used for underwater construction. Grout has a major effect on the properties of produced PAC and well defined grout controls the properties of resulted PAC. The effect of types and amount of powder materials, admixtures, sand and water content on the properties of fresh and hardened grout for the production of PAC have been investigated. Tests on hardened grout and PAC properties have also been carried out to investigate the most important effects. A correlation between hardened properties of grout and PAC has also been analyzed. Grout rheology using four different gradation sands at two different cement-sand and at different w/c ratios ratios has been identified experimentally; no added chemical admixtures or mineral additives had first employed, then superplasticizer (SP) was added at 2% and 1%, and finally a combination of 1% SP and pulverized fuel ash (Pfa) at 20% of the cement weight was employed for all mixes. Grout tests have included two point workability tests by the Viskomat NT, flow time funnel test, Colcrete flow meter test, and water bleeding test. After that, eighteen grout mixes with high workability were produced using three different sands at three w/c ratios and two c/s ratios with 1% SP and Pfa at 20% of the cement weight were designed. Eighteen hardened grout and PAC then produced and their compressive strength and sorptivity were tested. Grout rheology can be defined by the rheology of cement paste employed and the internal distance between sand particles. The effect of sand surface texture on grout rheology is important at very low internal distances. Fresh grout yield stress is the most important property which gives the same degree of sensitivity for all grouts regardless the material type and content used in the mix. There are strong relations between compressive strength of grout and PAC, but less correlation between them in sorptivity test because of the effect high quantity of coarse aggregate of PAC. Sorptivity of PAC is low comparing with different kinds of concrete suggesting its advantage for underwater construction.

Geopolymers are amorphous to semi-crystalline aluminosilicate polymers which are formed from inorganic polycondensation reaction of a solid aluminosilicate precursor with an alkaline sodium hydroxide or silicate. The resulting materials exhibit high durability, resistance to aggressive environments, high temperature resistance and many other properties that make them have received much attention in recent years, not only in construction. This thesis describes the influence of additives commonly used in concrete and mortar (water reducing, superplasticizer, air-entraining, foamer and defoamer, anti-shrinkage, stabilization) on the behavior of metakaolin in geopolymer fresh and hardened state. It describes metakaolin geopolymer effect on rheological properties of fresh mixtures, compressive strength and flexural strength after 28 days and a density in the fresh and hardened state.

Preplaced aggregate concrete (PAC) is produced by grouting high workability cement based grouts among the voids of compacted coarse aggregate mass. Because of its low shrinkage, PAC has been used for many repair jobs like; tunnel lines, dams and bridge piers. Moreover, it has been used for underwater construction. Grout has a major effect on the properties of produced PAC and well defined grout controls the properties of resulted PAC. The effect of types and amount of powder materials, admixtures, sand and water content on the properties of fresh and hardened grout for the production of PAC have been investigated. Tests on hardened grout and PAC properties have also been carried out to investigate the most important effects. A correlation between hardened properties of grout and PAC has also been analyzed. Grout rheology using four different gradation sands at two different cement-sand and at different w/c ratios ratios has been identified experimentally; no added chemical admixtures or mineral additives had first employed, then superplasticizer (SP) was added at 2% and 1%, and finally a combination of 1% SP and pulverized fuel ash (Pfa) at 20% of the cement weight was employed for all mixes. Grout tests have included two point workability tests by the Viskomat NT, flow time funnel test, Colcrete flow meter test, and water bleeding test. After that, eighteen grout mixes with high workability were produced using three different sands at three w/c ratios and two c/s ratios with 1% SP and Pfa at 20% of the cement weight were designed. Eighteen hardened grout and PAC then produced and their compressive strength and sorptivity were tested. Grout rheology can be defined by the rheology of cement paste employed and the internal distance between sand particles. The effect of sand surface texture on grout rheology is important at very low internal distances. Fresh grout yield stress is the most important property which gives the same degree of sensitivity for all grouts regardless the material type and content used in the mix. There are strong relations between compressive strength of grout and PAC, but less correlation between them in sorptivity test because of the effect high quantity of coarse aggregate of PAC. Sorptivity of PAC is low comparing with different kinds of concrete suggesting its advantage for underwater construction. / Libyan High Education Ministry

The use of nanotechnology has become wide spread in all branches of science. Nanotechnology help us to understand microstructure and due to the world has started to produce new materials. One of many examples carbon nanotubes (CNTs). In diploma thesis I tried to find the way of successful introduction into concrete mixture. I was studying influence of CNTs and other nano particles and I was comparing them with referential samples (without CNTs). Also I tested the improvement of mechanical characteristics of concrete. The morphology of nano particles was studied using Scanning Electron Microscopy (SEM). The results show that introduction of nanoparticles to results in increasing strength and higher density. That is why High Performace Concrete so resistant and durable.

This work is devoted to study the influence of the composition on mechanical properties of high performance concret based on portland cement. 29 samples of high performance concrete (HPC) warying in composition were prepared. The constituents used for HPC preparation were: cement Aalborg White, silica fume, finelly ground blast furnace slag, finelly ground silica, calcinated bauxite and polycarboxylate based superplasticizer. The mechanical parameters (flexural and compressive strength) of the samples were observed after 7 and 28 days of moist curing. Compressive strength values after 28 days were in the range of 92 to 194 MPa and the flexural strength values were in the range of 7 to 23 MPa (without using of fiber reinforcement). The graphs showing mechanical parameters depending on the mixture composition were constructed and consequently evaluated.

Vid betongframställning förekommer det spridningar i delmaterialens egenskaper som påverkar den färskaoch hårdnande betongen. Spridningarna i betongens delmaterial har studerats hos tre av Skanskas betongfabriker(Göteborg, Luleå och Norrköping), genom provuttag som analyserats hos Cementa Research.Provuttag har gjorts en gång per månad under ett års tid från fabrikerna. Delmaterialen som har analyseratsär ballast, cement, flytmedel och kalkfiller (endast hos Göteborg och Norrköping). Siktning av ballast0-8 mm har utförts med den traditionella siktningen. För kornstorlekar mindre än 0,25 mm, cement samtkalkfiller har lasersiktning använts.För att få en överskådlig bild över spridningarna hos delmaterialen har en analys utförts som illusteraravvikelserna med exakta siffror. Analysen har visat att den traditionella siktingen har mindre spridningjämfört med lasersiktning. Dessutom visar analysen att sättmåttet har större spridning jämfört med hållfastheten.För ballast 0-8 mm har minst spridning visats hos Luleå och störst hos Norrköping, däremot så har Luleåvisat störst spridning i ballast < 0,25 mm, cement, kalkfiller flytmedel och hållfasthet samtidigt som Göteborgvisat minst spridning i dessa och istället störst spridning i sättmått.För att få en överskådlig bild över vilka egenskapsförändringar som förväntas i betongen om respektivedelmaterial förändrats åt något håll har deskriptiv analys tillämpats parallellt med teoretisk analys. Dendeskriptiva analysen har avgränsats genom att undersöka hur förändringar i delmaterialen ballast, cement,kalkfiller och flytmedel påverkar sättmåttet och hållfastheten.Resultaten från den deskriptiva analysen har visat att en utökad mängd grövre ballast 0-8 mm ger upphovtill större sättmått och en utökad mängd finare ballast 0-8 mm ger högre hållfasthet för majoriteten avproverna. För ballast 0-8 mm < 0,25 mm har analysen visat att finare ballast < 0,25 mm ger upphov tillstörre sättmått. Hos Göteborg visar dessutom majoriteten av proverna högre hållfasthet för finare ballast< 0,25 mm.Prover från Göteborg har visat att grövre kalkfiller ger högre hållfasthet. Hos Norrköping visar dessutommajoriteten av proverna större sättmått för finare kalkfiller och högre hållfasthet för grövre kalkfiller.För cementet har analysen visat att majoriteten av proverna hos Luleå har gett upphov till större sättmåttför finare cement och högre hållfasthet för grövre cement. Hos Norrköping har analysen visat sammagällande hållfasthet, däremot tvärtom för sättmåttet, d.v.s. grövre cement har gett upphov till större sättmått.För flytmedel har majoriteten av proverna hos Luleå visat att högre torrhalt gett upphov till större sättmåttoch lägre torrhalt resulterat till högre hållfasthet. / During concrete production, property variations of the constituents occur that affect the fresh and hardenedconcrete. The variation in the constituents has been studied at three of Skanska’s concrete plants(Gothenburg, Luleå and Norrköping) through the samples analyzed at Cementa Research. Sampling atthese factories took place once per month over a one year period. The constituents that have been analyzedare aggregates, cement, superplasticizers and limestone filler (only in Gothenburg and Norrköping).Sieving of aggregates 0-8 mm has been conducted with traditional sieving. For grain sizes smaller than0.25 mm, cement and limestone filler laser sieving has been used.To get a clear picture of the variations in the constituents an analysis was performed that illustrated theexact figures of the discrepancies. Analyses show that the traditional sieving has less variation compared tolaser sighting. Moreover, the analysis shows that the slump has larger variations than the compressivestrength.Luleå showed the least variation for aggregates 0-8 mm while the largest variation was apparent at Norrkoping.However, Luleå has shown the largest variation in aggregates < 0.25 mm, cement, limestone filler,superplasticizers and compressive strength. Gothenburg on the other hand showed least variationamongst these while showing the largest variation in the slump.To better understand the property changes that are expected in the concrete of the respective the constituentsin either direction, both descriptive and theoretical analysis are applied simultaneously. The descriptiveanalysis has been limited to explore how changes in aggregates, cement, limestone fillers andsuperplasticizers affect the slump and compressive strength.The results of the descriptive analysis has shown that an increased amount of coarse aggregates 0-8 mmgives rise to larger slump and an increased amount of finer aggregates 0-8 mm gives greater compressivestrength to the majority of the samples. For aggregates 0-8 mm < 0.25 mm analysis has shown that fineraggregates < 0.25 mm give rise to greater slump. Analysis in Gothenburg also shows that the majority ofthe samples have higher compressive strength for the finer aggregates < 0.25 mm.Samples from Gothenburg have shown that coarser limestone filler provides higher compressive strength.Majority of the samples at Norrköping show greater slump for fine limestone filler and higher compressivestrength for coarse limestone filler.Analyses of cement have shown that the majority of the samples in Luleå have given rise to greater slumpfor finer cements and higher compressive strength for coarser cement. In Norrköping, the analysisdemonstrated the same compressive strength, however, to the contrary coarse cement has given rise togreater slump.Analysis of superplasticizers in Luleå show that the majority of the samples at higher dry content resultedin greater slump and at lower dry content resulted in higher compressive strength.