Please read the abstract in the section 00front of this document / Dissertation (MEng (Geotechnical Engineering))--University of Pretoria, 2006. / Civil Engineering / unrestricted

A new approach towards waste management in a mining environment is developed and applied. This dissertation specifically studies the storage and management of tailings in the platinum industry as well as the associated environmental impacts. The product is an alteration of conventional tailings storage methodologies, to a sustainable design strategy in order to minimise environmental impact and optimise social and natural conditions. Factors influencing Tailings Disposal Facility design is: geo-technical stability, public safety, economic considerations, visual impact, water, soil and air pollution, local social context and end land use goals. Each are discussed from an environmental and social impact point of view in order to arrive at a sustainable landform (Tailings Disposal Facility) design. / Dissertation (ML (Prof))--University of Pretoria, 2006. / Architecture / unrestricted

M.Sc. / The Merriespruit Tailings dam disaster killed seventeen (17) people and covered a part of Virginia with approximately 2.5 million cubic metres of tailings, causing such an emotional uproar that all resources were focused on repairing the dam and addressing some of the social issues. Little attention was given to the environment. The identified need in this study was therefore to investigate the consequences of the disaster on the environment, a need which derives from the uniqueness of this particular disaster and its consequences. The Department of Minerals and Energy require the submission of an Environmental Management Program Report (EMPR) on all prospecting and mining operations. It is clear that, in the compilation of such an EMPR, Harmony Gold Mine neglected to establish a Management Plan to regulate the physical impact of the disaster on the environment, mainly because no attention was given to disasters in the Aide-Memoir. A Management Plan was established by adapting existing formats of management plans to the uniqueness of this disaster. By following the procedure stipulated in the Management Plan it can be ensured that Environmental Management requirements will be effectively integrated into either the project management actions and contracts or operational systems and processes for the following issues: • Water management • Storm water control • Waste management • Dust • Aesthetics and socio-economic implications • Rehabilitation of the area. The investigation showed that the disaster exerted a definite negative influence on the environment, which can be managed by taking preventative measures stipulated in the Management Plan. However, one of the main issues identified in this study is that storm water management has been problematic for a period of time. It is therefore noted that some attention should be given to establishing a wetland system to contain the storm water runoff. Although this study does not focus on the socio-economic impacts in detail, it is recommended that these impacts are considered as it is evidently problematic. The primary aim of this study was to compile an EMP in order to manage, and possibly mitigate, the physical impact of the disaster on the immediate environment, an aim which clearly was accomplished. Harmony Gold Mine can benefit from the compilation of this EMT, as management goals were set and feasible means of achieving them were specified.

South Africa has an array of mining commodities which all play an integral role in our everyday surroundings, income, and most importantly, in the economy of the country. These mining activities also produce vast amounts of discard material, better known as tailings material, which is stored in different ways after extraction has taken place. Usually, storage entails the construction of tailings storage facilities, normal discard or tailings dumps. The upper surfaces of these anthropogenic structures are usually unstable and are, in most cases, characterised by different forms of erosion. This can be due to the chemical and physical properties of the materials of which they are constructed, but mainly due to unstable construction geomorphology, steep slopes, which leads to poor water run-off management and subsequent instability. Therefore, these structures need to be actively managed in order to increase and maintain their stability. Grass establishment, as a stabilisation technique, is the most effective out of all of the techniques, but there are certain constraints regarding this method (Titshall et al. 2013). The most costly constraint is nutrient supplementation during aftercare phases. In order to minimize this cost, new and innovative technologies need to be explored, and trialled. The contribution of soil biological processes in this regard was assessed, in order to minimise anthropogenic inputs. These biological processes refer to the fixation of atmospheric nitrogen by nodular root bacteria that grow on a group of plants referred to as legumes. These bacteria, also known as rhizobia, live in a symbiotic relationship with the host plant where they receive energy in the form of nutrients by trading nitrogen, which is an essential plant nutrient. Nine different tailings materials from different commodities available from South African Mines were selected. For a control medium, a well-drained soil type with an apedel structure and a clay content of approximately 6% was selected in order to promote optimal natural growth. These materials were chemically and physically analysed in order to develop a more holistic understanding on a micro scale level, as well as to ascertain possible constraints in this regard. Pot trials were selected as the experimental method in order to apply more specific control over root growth, plant development and growing conditions. The experimental data were collected over one growing season for both live forms. For this study, seven legume species were selected for establishment in the tailings materials in order to investigate their establishment potential in the growth mediums and their ability to fixate nitrogen. Based on the data, specific species were identified as viable options to include in future tailings amelioration projects; it can be assumed that the nitrogen produced by these species will be available in the growth medium for uptake by neighbouring plants that lack this biological function. These plants will also play a vital role in the long-term sustainable development of vegetation in the anthropogenic growth mediums. Sericea lespedeza had the highest enrichment ability during this study. / MSc (Environmental Sciences), North-West University, Potchefstroom Campus, 2015

South Africa has an array of mining commodities which all play an integral role in our everyday surroundings, income, and most importantly, in the economy of the country. These mining activities also produce vast amounts of discard material, better known as tailings material, which is stored in different ways after extraction has taken place. Usually, storage entails the construction of tailings storage facilities, normal discard or tailings dumps. The upper surfaces of these anthropogenic structures are usually unstable and are, in most cases, characterised by different forms of erosion. This can be due to the chemical and physical properties of the materials of which they are constructed, but mainly due to unstable construction geomorphology, steep slopes, which leads to poor water run-off management and subsequent instability. Therefore, these structures need to be actively managed in order to increase and maintain their stability. Grass establishment, as a stabilisation technique, is the most effective out of all of the techniques, but there are certain constraints regarding this method (Titshall et al. 2013). The most costly constraint is nutrient supplementation during aftercare phases. In order to minimize this cost, new and innovative technologies need to be explored, and trialled. The contribution of soil biological processes in this regard was assessed, in order to minimise anthropogenic inputs. These biological processes refer to the fixation of atmospheric nitrogen by nodular root bacteria that grow on a group of plants referred to as legumes. These bacteria, also known as rhizobia, live in a symbiotic relationship with the host plant where they receive energy in the form of nutrients by trading nitrogen, which is an essential plant nutrient. Nine different tailings materials from different commodities available from South African Mines were selected. For a control medium, a well-drained soil type with an apedel structure and a clay content of approximately 6% was selected in order to promote optimal natural growth. These materials were chemically and physically analysed in order to develop a more holistic understanding on a micro scale level, as well as to ascertain possible constraints in this regard. Pot trials were selected as the experimental method in order to apply more specific control over root growth, plant development and growing conditions. The experimental data were collected over one growing season for both live forms. For this study, seven legume species were selected for establishment in the tailings materials in order to investigate their establishment potential in the growth mediums and their ability to fixate nitrogen. Based on the data, specific species were identified as viable options to include in future tailings amelioration projects; it can be assumed that the nitrogen produced by these species will be available in the growth medium for uptake by neighbouring plants that lack this biological function. These plants will also play a vital role in the long-term sustainable development of vegetation in the anthropogenic growth mediums. Sericea lespedeza had the highest enrichment ability during this study. / MSc (Environmental Sciences), North-West University, Potchefstroom Campus, 2015

Mining operations, including crushing, grinding, smelting, refining, and tailings management, are a significant source of airborne metal and metalloid contaminants such as As, Pb, Cd and other potentially toxic elements. Dust particles emitted from mining operations can accumulate in surrounding soils, natural waters and vegetation at relatively high concentrations through wind and water transport. Human exposure to the dust can occur through inhalation and, especially in the case of children, incidental dust ingestion, particularly during the early years when children are likely to exhibit pica. Furthermore, smelting operations release metals and metalloids in the form of fumes and ultra-fine particulate matter, which disperses more readily than coarser soil dusts. Of specific concern, these fine particulates can be transported to the lungs, allowing contaminants to be transferred into the blood stream. The main aim of this research is to assess the role of atmospheric aerosol and dust in the transport of metal and metalloid contaminants from mining operations to assess the deleterious impacts of these emissions to ecology and human health. In a field campaign, ambient particulates from five mining sites and four reference sites were examined utilizing micro-orifice deposit impactors (MOUDI), total suspended particulate (TSP) collectors, a scanning mobility particle sizer (SMPS), and Dusttrak optical particle counters for an understanding of the fate and transport of atmospheric aerosols. One of the major findings from size-resolved chemical characterization at three mining sites showed that the majority of the contaminant concentrations were found in the fine size fraction (<1 micrometer). Further, metal and metalloids (e.g. As, Cd, and Pb) around smelting activities are significantly enriched in both the coarse and fine size fraction when compared to reference sites. Additionally, with dust events being a growing concern because of predicted climate change and mine tailings being a significant source for dust, high wind conditions around mine tailings were studied for dust generation. Relative humidity was found to play an important predicting role in atmospheric dust concentration. More generally, findings indicate mining activities remain a serious threat to human health and ecology despite the regulations in place to protect from their pollution.

Phytostabilization offers a less expensive alternative to traditional cap and plant methods for containing metalliferous mine tailings to prevent wind erosion and contamination of nearby communities and the environment. However, plant establishment during phytostabilization of pyritic legacy mine tailings in semiarid regions is challenging due to particularly extreme conditions including low pH, low organic carbon, low nutrients, and high toxic metal(loid) concentrations. Microorganisms drive major biogeochemical cycles in soils, however, the roles microorganisms play at the root – soil interface during phytostabilization, particularly in relation to plant health and metal immobilization, are not yet fully understood. The aims of this dissertation are to focus on bacterial communities associated with the roots of buffalo grass used in the phytostabilization of pyritic metalliferous mine tailings to: i) characterize bacterial diversity and communities of rhizosphere and bulk substrate, ii) delineate associations between rhizoplane bacterial colonization patterns and environmental and plant status parameters, and iii) develop an in situ method to visually assess associations between roots, bacteria, and metals. Key findings indicate that after addition of a compost amendment to alleviate the plant-growth inhibiting characteristics of mine tailings, rhizosphere and bulk substrate contain a diverse, plant-growth supporting bacterial community. As substrate re-acidifies due to compost erosion, an emergence of an iron (Fe)- and sulfur (S)-oxidizer and Fe-reducer dominated, less diverse community develops in the bulk and rhizosphere substrate, thus posing a threat to successful plant establishment. However, even at low pH, some plant-growth-promoting bacteria are still evident in the rhizosphere. On the rhizoplane (root surface), the relative abundance of metabolically active bacteria was positively correlated with plant health, verifying the strong association between plant health and bacteria. Furthermore, pH showed a strong association with the relative abundance of Alphaproteobacteria and Gammaproteobacteria on the rhizoplane. In relation to microbe-metal interactions on the root surface, results showed that Actinobacteria and Alphaproteobacteria colocalized with Fe-plaque and arsenic (As) contaminant on the root surface, indicating their potential role in adsorbing or cycling of these metal(loid)s. Developing a more thorough understanding of bacteria-root-metal interactions in relation to plant health and metal immobilization can help to improve phytostabilization efforts and success.

M.Sc. / Atmospheric emissions of dust and chemicals from gold mine tailings are ongoing environmental management issues on the Witwatersrand, where residential areas have developed in proximity to dumps. Residual amounts of cyanide, used as a chemical in the gold extraction process, are deposited with the mineral tailings. This study deals with the evaluation of population exposure to cyanide vapour emitted from gold mine tailings dams, an issue of environmental impact and public health concern. The first part of this study deals with the determination of the emission factors of cyanide vapour from three selected gold mine tailings dams: one under reclamation; one no longer operational; and one fully operational as a slimes deposition site. These three sites are located in the Boksburg area of the Ekurhuleni Metropolitan Municipality. Twelve samples were collected in all: six from the Cason (2628AAL91) mine dump (under reclamation in 2006); four from the ERPM tailings complex [comprising the dormant deposits 4/L/47, 4/L/48, 4/L/49 and 4/L/50, which are north of the N17 national highway; and the 2628ACL1 deposit, which is south of the N17]; and two from the Rooikraal (active) deposition site. All samples were collected in the year 2006. In the second part of the study, the obtained emission factors were used in an Industrial Source Complex dispersion model to measure the degree of population exposure to cyanide vapour for communities that are in proximity to the operational gold mine tailings dams in the Johannesburg Metropolitan Municipality. In the third part, a health risk assessment was carried out for communities in proximity to the selected gold mine tailings dams. The study revealed the average flux (± std. dev.) of Cason to be (4.7 ± 0.8) x 10-7 g m-2 s-1, the average flux of ERPM (3.9 ± 0.6) x 10-7 g m-2 s-1, the average flux of Rooikraal (1.7 ± 0.2) x 10-5 g m-2 s-1. The concentrations of cyanide vapour emitted from the older tailings deposits (sand) that are under reclamation and the dormant slimes dams are very low (and pose little health risk to occupants of adjacent land). However, HCN emission factors from operational tailings dams, which are receiving continuous depositions, are 3 to 80 times higher than the emission factors from dormant mine tailings. Ambient cyanide concentrations near the active tailings deposits may sometimes exceed selected international health standards. The average hourly, daily and annual dispersion model calculations for the Nasrec tailings deposition sites in Johannesburg revealed that 117 938, 18 722 and 8 130 people respectively were exposed to hydrogen cyanide concentrations that were above international (Ontario, Canada) standards. This raises environmental concerns that require institution of cyanide monitoring and setting of emission limits applicable to South African legal and environmental circumstances. These conclusions are based on a small number of emission factor determinations and hence these findings should be regarded as provisional. Further testing and verification are required for emission factors from a larger number of dormant, reworked and active tailings dams.

A Dissertation submitted to the Faculty of Engineering, University of the Witwatersrand Johannesburg, in fulfillment of the requirements for the Degree of Master of Science in Engineering / High extractions of the platinum group metals' from a refractory tailings concentrate (PGM Concentration : Pt 81.5ppm, Pd 21.5ppm, Rh 17.5ppm) was achieved after short. low-temperature roasting and subsequent leaching with a zinc chloride based leach reagent containing nitric acid under atmospheric pressure at temperatures from 105-C to 120-C. [Abbreviated Abstract. Open document to view full version] / AC2017

School of Chemical and Metallurgical Engineering, Faculty of Engineering and Built in Environment, University of Witwatersrand, Johannesburg, South AfricaMay, 2016 / Trojan Nickel Mine in Bindura, Zimbabwe, produces nickel concentrates which, until 2008, were then processed at their smelter operations (Bindura Smelter and Refinery) and the subsequent product sent to the hydrometallurgical plant to produce nickel cathodes. However, due to economic challenges the smelter and hydrometallurgical plant operations were closed down in 2008. Currently, Trojan Mine produces nickel concentrates through flotation which are then sold to Glencore International, in China, for further processing. Since 2002, the MgO (also known as talc) content in the Trojan Nickel Mine final concentrates has increased from around 12% to a peak of 22%. The average MgO content in the concentrates for the year ending in March 2015 was 16.14%. An offtake agreement of sale was made with Glencore International, in China, whereby a penalty is charged for all concentrates with MgO levels greater than 5%. In the year 2015 alone, monthly revenue due to smelter penalties amounted to an estimated total of US$141 000. Higher MgO levels in the concentrates are prevalent when processing low grade ores, with nickel content ranging from 0.65-1.2%. This research focused on reducing the MgO content of the Trojan’s final concentrate to 12%; which was the smelter’s set target while it was still operational. In order to investigate the effect of pH and chemical depressants on the MgO levels in the concentrate, batch flotation tests were carried out at pH 8.95 and 10.2, using several guargum depressants namely: Betamin DZT 245 (standard), Cytec S9349, DLM PDE, DLM RS, and CMC (carboxy methyl cellulose) depressants namely: Depramin 177, 267 and 347, and ND 521, 522 and 523. The concentrates were collected at 1, 5, 15 and 25 minute intervals in order to understand the stage-wise recovery of nickel and MgO minerals. A flotation test, without a depressant, was also carried out in order to understand the kinetics of the gangue minerals. Stage addition of depressants was investigated, by adding another 50g/t dose of the DZT 245 depressant after 1 minute into the flotation test. Collector combination tests using SIPX, SIPX:NC228, SIPX:NC236 and SIPX:PNBX, were also carried out to determine the best reagent suite. To understand the recovery of nickel and MgO in the flotation circuit, a plant survey was carried out, and the particle size distribution (PSD) and assays of collected samples were determined. Flotation tests results indicated that DLM RS and DLM PDE guargum depressants had better selectivity towards MgO and higher nickel recoveries as compared to the Betamin DZT 245 depressant that is currently used in the plant. It is recommended that a plant trial be carried out using the DLM RS depressant, which further reduced the MgO and mass of concentrate recovered by 3.79% and 32% respectively. The stage recovery of MgO for a test carried out without a depressant showed that 57.7% of the MgO was recovered during the first five minutes of the test. Thus, there is need to effectively depress the fast floating MgO during the early stages of the flotation process. Nickel recovery and grade were increased by 2.7% and 2.1% respectively, after adding the second dose of the depressant after 1 minute into the flotation test. The results indicated that the fast floating MgO can depress the valuable mineral if the depressing effect of the depressant is short-lived, which in turn leads to reduced nickel recoveries. Hence, reducing the time between the two stage additions of the depressant in the plant will help further supress the fast floating MgO silicates. It was also noted that at least 60% of the nickel was recovered during the first five minutes of the tests. Hence, reducing the residence time of the rougher flotation bank would reduce MgO recovery into the concentrates without adversely affecting the nickel recoveries. Plant survey results showed that the scavenger bank feed that was deslimed, had less finer MgO particles and MgO content as compared to the rougher bank feed. This indicates that desliming before the coarse flotation process could reduce MgO slimes in the feed, reduce the recovery of MgO due to slime coatings in the final concentrates and the reagent consumption in the bank. Introducing the desliming unit could be beneficial since the desliming cyclones have low installation and operational costs. / MT2016