The assemblage of ca. 6–4 Ma volcanic rocks exposed at the Sagehen Research station in the Truckee-Tahoe region of the northern Sierra Nevada, United States, is interpreted to be, within the Ancestral Cascades volcanic arc, a Lassen-type stratovolcano complex. Sagehen is of particular importance because it is one of the few Tertiary arc volcanic centres in California which has not been heavily glaciated during the Pleistocene. The volcanic rocks are variably porphyritic or aphanitic, including abundant plagioclase with clinopyroxene and amphibole. The rocks range from basalt to basaltic-andesite to andesite in composition. Basalts are olivineand clinopyroxene-bearing with minor phenocrysts of plagioclase. The basaltic-andesites are primarily pyroxene bearing while the andesites contain pyroxene-, plagioclase- and hornblende porphyritic phases. Sagehen arc lavas are calc-alkaline and enriched in the large ion lithophile elements and depleted in High Field Strength Elements. The basalts are depleted in Zr and Hf while the andesites are enriched with Zr and Hf relative to the middle rare earth elements. Compared to previously studied Ancestral Cascade arc samples, Sagehen region basalts have lower 143Nd/144Nd isotopic values that do not correspond to proposed mantle-lithosphere mixing lines, while the andesite samples appear to represent the interplay of these two components on a 87Sr/86Sr vs. 143Nd/144Nd. The trace element data and isotopic plots suggest that the melts that produced the basalts are from subduction modified mantle wedge peridotites that ponded near the base of the lithosphere similar to the generation of other subduction related calc-alkaline lavas along convergent continental margins. The andesitic samples appear to be the result of further modification through crustal assimilation as seen in the higher isotopic Sr contents in the andesites and Ce/Smpmn vs. Tb/Ybpmn plots. Finally, the proposed map units from Sylvester & Raines (2007) were found to contain various geochemical facies based on the samples collected indicating that some map units may have to be redefined or sub-divided.

No description available.

In North America, the acceleration of the eutrophication of surface waters due to nutrient pollution is still present. Soil studies have not entirely succeeded in linking nutrient and sediment losses to field hydrology because relationships between discharge and dissolved ions/sediments are complicated by a hysteresis effect which has been only described qualitatively. The objective of this thesis was to better understand the effects of hydrology on N, P, and sediment transfer from agricultural and forest soils to surface waters. This was done by developing a technique, called the H index, to quantify the hysteretic behaviour of ion and sediment transport in stream/overland water. The chemical and sediment concentrations in a stream of a forested watershed in the Sierra Nevada during snowmelt and in overland runoff of two agricultural fields during rain events in the Montreal area were examined. In the stream of the forested watershed, H indices for suspended sediment increased (looser hysteresis loop) with the availability of sediments and the lag between peaks in suspended sediment concentrations and discharge. In agricultural fields, nutrient concentrations increased with time during each event with presence of counterclockwise and clockwise hysteresis. The hysteretic behaviour of suspended sediments was not significantly related with either prior soil moisture content or rainfall characteristics. In order to simultaneously monitor P and N in the stream and soils of the forested watershed, a laboratory study was conducted to investigate the efficacy of various mixedbed exchange resins in absorbing dissolved organic and inorganic N and P. Results showed that mixed-bed resin was adequate for characterizing P on a short-time scale but longer exposure periods were required for N. Results from the resin exchange reveal the possibility that the spring time pulse of NOs'-N in stream water was due to the melting of the snowpack.

No description available.