Surface tension of a polymer melt in a supercritical fluid is a principal factor in determining cell nucleation and growth in polymer microcellular foaming. Previous work has presented the surface tension of the amorphous polymer, polystyrene (PS), in supercritical CO2 determined by Axisymmetric Drop Shape Analysis-Profile (ADSA-P), together with theoretical calculations for a corresponding system. The dependences of the surface tension on temperature, pressure and polymer molecular weight were discussed and the physical mechanisms for three main experimental trends were explained using Self Consistent Field Theory (SCFT). This thesis introduces recent work on the surface tension measurement of the crystalline polymer, high density polyethylene (HDPE), in supercritical N2 under various temperatures and pressures. The surface tension was determined by ADSA-P and the results were compared with those of the amorphous polymer PS. The dependence of the surface tension on temperature and pressure, at temperatures above the HDPE melting point, ~125°C, was found to be similar to that of PS; that is, the surface tension decreased with increasing temperature and pressure. Below 125°C and above 100°C, HDPE underwent a process of crystallization, where the surface tension dependence on temperature was different from that above the melting point, i.e., decreased with decreasing temperature. Differential Scanning Calorimetry (DSC) characterization of the polymer was carried out to reveal the process of HDPE crystallization and relate this to the surface tension behavior. It was found that the amount of the decrease in surface tension was related to the rate of temperature change and hence the extent of polymer crystallization. In the second part of the thesis, surface tension dependences on temperature, pressure and clay concentrations were studied for HDPE nano-clay composites (HNC) and compared with pure HDPE. It was found the trends with temperature and pressure were the same with PS in CO2 and HDPE in N2; that is, the surface tension decreased with increasing temperature and pressure. In all nanocomposite samples, the surface tension decreased compared with pure HDPE. This could be a good explanation for the better polymer foaming quality with the addition of clay in the polymer. A minimum surface tension was found with the sample at ~3% concentration of clay. The degree of crystallinity of HNC was analyzed by Differential Scanning Calorimetry (DSC) at different clay concentrations. A minimumz crystallinity was also found at the clay concentration of 3%. The possible relationship between surface tension and polymer crystallinity was discussed.

The purpose of this thesis is to provide an overview of ETFE foil, as it applies to pneumatic cushion cladding, with a focus on creep behavior of the material. Characteristics of ETFE, including weight, optics, insulation, flexibility, environmental properties, fire performance, cushion span and other features are discussed, and, where possible, are compared to the characteristics of glass panels used in similar applications. Relevant chemical and mechanical properties of ETFE are given. Load carrying concepts of tension structures and inflated cushions are discussed, as well as structural design methods for ETFE cushions. Several prominent structures constructed using ETFE foil are introduced and benefits and design issues associated with these structures are reviewed. When used in cushion applications, ETFE films are placed in constant tension, and are therefore subject to creep. Quantifying this creep is desirable so that it can be predicted during the design phase. Therefore, this thesis summarizes the findings of other researchers in the area of creep of ETFE as well as the general mechanical behavior of the material, and presents the results of uniaxial creep tests done for the purpose of this study. These tests included 24 hour uniaxial creep tests done at four stress levels on both the transverse and longitudinal directions of three different brands of film. Two thicknesses of the third film were acquired and both were tested. The stress levels were chosen to coincide with typical design tensile stresses for ETFE film, and to be similar to the levels tested by other researchers. The effects of the different stresses, brands, directions and thicknesses are evaluated and discussed. Three seven day creep tests were also done on one of the films, each at a different stress level. Constitutive viscoelastic and viscoplastic models were developed to represent the 24-hour creep data. The viscoelastic models were based on a four-element Kelvin model and the viscoplastic models were based on a power-law model. The model parameters were determined from the data using linear least squares fitting. Models were also developed for the seven day creep data. Several of these models were based only upon the first 24 hours of data, and were used to determine the applicability of the 24-hour creep models to long-term behavior. It was found that while a viscoelastic model appears to fit long-term creep most closely, the 24-hour models are inadequate for modeling longer time frames. Another method is required for predicting long-term creep. Nonlinear fitting of the parameters is recommended as a possible alternative for creating more accurate models. Longer-term creep tests are also recommended. Tensile tests were also done on the films to confirm mechanical properties supplied by the film manufacturers. Good agreement to the given values was found in the test data.

Recent research studies have confirmed that curved I-girders are capable of developing substantial shear postbuckling resistance due to tension field action and have demonstrated that the AASHTO LRFD equations for the tension field resistance in straight I-girders may be applied to curved I-girders within specific limits. However, the corresponding demands on intermediate transverse stiffeners in curved I-girders are still largely unknown. Furthermore, a number of prior research studies have demonstrated that transverse stiffeners in straight I-girders are loaded predominantly by bending induced by their restraint of web lateral deflections at the shear strength limit state, not by in-plane tension field forces. This is at odds with present Specification approaches for the design of transverse stiffeners, which are based on (1) providing sufficient stiffener bending rigidity only to develop the shear buckling strength of the web and (2) providing sufficient stiffener area to resist the in-plane tension field forces. In this research, the behavior of one- and two-sided intermediate transverse stiffeners in straight and horizontally curved steel I-girders is investigated by refined full nonlinear finite element analysis. Variations in stiffener rigidity, panel aspect ratio, panel slenderness, and stiffener type are considered. New recommendations for design of transverse stiffeners in straight and curved I-girder bridges are developed by combining the solutions from the above FEA studies with the results from prior research.

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The static stability of a Tension Leg Platform (TLP) with an intact tendon system is principally provided by its tendons and hence quite different from those of a conventional ship or even a floating structure positioned by its mooring system. Because small deformations in tendons are capable of providing sufficient righting moment to a TLP, the contribution from the inclination of its hull is relatively insignificant, especially when its tendon system is intact. When the tendon system of a TLP is completely damaged, the static stability of a TLP behaves and is calculated in a similar manner as those of a conventional ship. In the case of a TLP with a partially damaged tendon system, the stability of a TLP may be provided by the deformation of its tendons and to a certain extent the inclination of its hull. Several hurricanes in recent years have raised concerns about the feasibility and the robustness of the TLP concept in the deep water Gulf of Mexico. To the best of our knowledge, existing publications on the research of static stability of TLPs are limited. This study investigates the static stability of different types of TLPs representing those deployed in the Gulf of Mexico, under three different scenarios. That is, a TLP with 1) an intact tendon system, 2) a partially damaged tendon system, and 3) a completely damaged tendon system. The four different types of TLP chosen for this study are 1) a conventional four-leg TLP, 2) three-leg mini TLP, 3) extended four-leg TLP and 4) mini four-leg TLP. To avoid buckling and yielding occurring in a tendon, we define that the maximum righting moment provided by an intact or partially damaged tendon system is reached when the tension in one or more tendons on the down tension leg becomes zero or when the tension in one or more tendons on the up tension leg starts to yield. This definition leads us to identify the most dangerous (or vulnerable) directions of met-ocean conditions to a TLP with an intact or partially damaged tendon system. Hence, our finding may also be used in the study on the pitch/roll dynamic stability of a TLP. The righting moments of each TLP in the three different scenarios are respectively computed and compared with related wind-induce static upsetting moment at certain velocities. By comparing their ratios, the static stability of a TLP and the redundancy of its tendon system may be revealed, which has important implication to the design of a TLP.

The purpose of this thesis is to design an innovative sickbed for the paralyzed patients. One goal of the sickbed is to avoid the occurrence of pressure ulcers. The other one is to tune the tensions of patient¡¦s muscles. To analyze the muscle tension, a simplified model for human body was proposed. This model divided the human body into 5 blocks when ignoring the arms and hands. It described the geometric relationships between the blocks and muscles under different body postures and external supports from the design sickbed. It was noted that the number of unknowns of the model was larger than the number of equations derived from the equilibrium conditions. An optimization method, which was to obtain a desired distribution of muscle tensions, was adopted to find the solutions for the unknowns. Among the possible supporting states, which included the body postures and supporting locations, the ones that met the desired tension distribution were searched. Then, the technique of Graph theory was used to obtain a set of supporting states that could avoid the occurrence of pressure ulcers. Finally, a preliminary design of the sickbed structure was discussed. If the relaxed condition of muscles was desired, the simulation study indicated that large number of supporting states could meet the purpose. That means there exist many body postures or supporting locations allowing the muscles of body in the relaxed condition. This feature allows one to choose a set of supporting states that two consecutive states own different supporting locations and prevents any spot of body from continuous loading. Such a supporting scheme should minimize the occurrence of pressure ulcers.

Reproduction de : Thèse doctorat : Chimie des matériaux : Reims : 2008. / Titre provenant de l'écran titre. Bibliogr. p. 190-198.

Thesis (Professional Degree)--University of Missouri, School of Mines and Metallurgy, 1922. / The entire thesis text is included in file. Typescript. Title from title screen of thesis/dissertation PDF file (viewed Feb. 22, 2010). Includes bibliographical references (p. 34-35).

Numerical simulations of combined buoyant and surface tension driven flow, also known as Rayleigh-Bénard-Marangoni (RBM) convection are conducted for heated fluid layers of small aspect ratio (defined as the ratio of the horizontal extent of the domain divided by the depth of the fluid) in square cross-section containers. A particular non-dimensionalization of the governing equations is developed in which the aspect ratio of the domain appears as a continuous parameter. The simulations extend and enhance existing experimental studies of the RBM convection phenomenon by mapping continuous solution branches in aspect ratio and Marangoni number parameter space. Key implementation aspects of the development of the adaptive mesh refinement (AMR) library libMesh are discussed, and a series of simulations of the RBM problem with a stick-slip boundary condition demonstrate the suitability of AMR for computing these flows. / text