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No description available.

No description available.

No description available.

No description available.

L’objectif de ce travail est d’étudier les transitions de phases sol-gel et isotrope-nématique dans des suspensions de smectites dioctaédriques en fonction de la morphologie et de la nature minéralogique des argiles. Bien que tous les systèmes étudiés présentent une transition sol-gel à de faibles fraction volumique, la transition cristal-liquide isotrope-nématique n’a pu être identifiée que dans le cas de suspensions de smectites ayant un déficit de charge tétraédrique. L’effet de la localisation de la charge sur le comportement colloïdal a été déterminée à l’aide de la diffusion des rayons X aux petits angles (SAXS) et par des mesures rhéologiques. La nature des interactions électrostatiques dans ces suspensions est purement répulsive et rejette l’idée d’une structure tridimensionnelle de type « château de carte ». Cependant, les smectites ayant un déficit de charge tétraédrique sont plus répulsives et ont des propriétés viscoélastiques plus faibles que celles ayant un déficit octaédrique. Il a également été montré que la dépendance en taille de particules de la position de la transition sol-gel était liée à une statistique de piégeage hydrodynamique des plaquettes d’argile. Finalement, l’application de champs externes (électrique et magnétique) a permis d’obtenir l’alignement de la phase nématique tandis que dans la phase isotrope, le champ électrique induit un ordre antinématique parfait. Afin de préserver l’ordre induit, ces suspensions ont été polymérisées sous champ permettant l’obtention de nanocomposites orientées et structurés / The aim of this work is to study sol-gel and isotropic-nematic phases transitions in suspensions of dioctahedral smectites depending on the morphology and mineralogical nature of clays. Although all the systems studied exhibit a sol-gel at low volume fraction, the liquid-crystalline isotropic-nematic transition could be identified only in the case of smectites with tetrahedral charge deficit. The effect of charge location on the colloidal behavior was determined using small-angle X-ray scattering (SAXS) and rheological measurements. The nature of electrostatic interactions in these suspensions is purely repulsive and rejects the idea of the so-called “house of card” network. However, smectites with a charge deficit located in the tetrahedron are more repulsive and their viscoelastic properties are lower than octahedrally substituted clays. It was also shown that the particle size dependence of the volume fraction corresponding to the sol-gel transition c was related to a simple statistical hydrodynamic trapping of clay platelets. Finally, the application of external fields (electric and magnetic) has resulted in the alignment of the nematic phase while in the isotropic phase, the electric field induces a perfect antinematic order. To preserve the induced alignment, these suspensions were polymerized under the field to obtain perfectly aligned and patterned nanocomposites

As followup to our recent detection of a pre-transit signal around HD 189733 b, we obtained full pre-transit phase coverage of a single planetary transit. The pre-transit signal is again detected in the Balmer lines but with variable strength and timing, suggesting that the bow shock geometry reported in our previous work does not describe the signal from the latest transit. We also demonstrate the use of the Ca II H and K residual core flux as a proxy for the stellar activity level throughout the transit. A moderate trend is found between the pre-transit absorption signal in the 2013 data and the Ca II H flux. This suggests that some of the 2013 pre-transit hydrogen absorption can be attributed to varying stellar activity levels. A very weak correlation is found between the Ca II H core flux and the Balmer line absorption in the 2015 transit, hinting at a smaller contribution from stellar activity compared to the 2013 transit. We simulate how varying stellar activity levels can produce changes in the Balmer line transmission spectra. These simulations show that the strength of the 2013 and 2015 pre-transit signals can be reproduced by stellar variability. If the pre-transit signature is attributed to circumplanetary material, its evolution in time can be described by accretion clumps spiraling toward the star, although this interpretation has serious limitations. Further high-cadence monitoring at H alpha is necessary to distinguish between true absorption by transiting material and short-term variations in the stellar activity level.

Supernovae (SNe) are energetic explosions that signal the end of a star's life. These events and the supernova remnants (SNRs) they leave behind play a central role in stellar feedback by adding energy and momentum and metals to the interstellar medium (ISM). Emission associated with these feedback processes, especially atomic and molecular line emission as well as thermal and nonthermal continuum emission is known to be enhanced in regions of high density, such as dense circumstellar matter (CSM) around SNe and molecular clouds (MCs). In this thesis, I begin with a brief overview of the physics of SN shocks in Chapter 1, focusing on a foundation for studying pan-chromatic signatures of interactions between SNe and dense environments. In Chapter 2, I examine an unusual SN with signatures of CSM interaction in the form of narrow lines of hydrogen (Type IIn) and thermal continuum emission. This SN appears to belong to a class of Type Ia SNe that shares spectroscopic features with Type IIn SNe. I discuss the difficulties of decomposing spectra in a regime where interaction occurs between SN ejecta and CSM, potentially confusing the underlying SN type. This is followed by a discussion of rebrightening that occurred at late-time in 𝐵 and 𝑉 band photometry of this SN, possibly associated with clumpy or dense CSM at large distances from the progenitor. In Chapter 3, I examine synchrotron emission from Cassiopeia A, observed in the 𝐾ₛ band over multiple epochs. The synchrotron emission is generally diffuse over the remnant, but there is one location in the southwest portion of the remnant where it appears to be enhanced and entrained as knots of emission in the SNR ejecta. I evaluate whether the 𝐾ₛ band knots are dominated by synchrotron emission by comparing them to other infrared and radio imaging that is known to be dominated by synchrotron emission. Concluding that they are likely synchrotron-emitting knots, I measure the magnetic field strength and electron density required for their evolution over the ~ 10 yr baseline they were observed and find 𝐵 ≈ 1.3-5.8 mG and 𝑛ₑ≈ 1,000-15,000 cm⁻³. The magnetic field strengths appear enhanced beyond values required by the adiabatic strong shock limit, arguing in favor of other forms of magnetic field amplification in the shock. In Chapter 4, I again discuss Cassiopeia A and interaction between the remnant and nearby MCs as seen at mid-infrared and millimeter wavelengths. I report detection of a SNR-MC interaction and analyze its signatures in broadened molecular lines. I extend this analysis in Chapter 5 to a large survey for SNR-MC interactions in the ¹²CO 𝐽=2-1 line. Although broadened ¹²CO 𝐽=2-1 line emission should be detectable toward virtually all SNR-MC interactions, I find relatively few examples; therefore, the number of interactions is low. This result favors mechanisms other than supernova feedback as the basic trigger for star formation. In addition, I find no significant association between TeV gamma-ray sources and MC interactions, contrary to predictions that SNR-MC interfaces are the primary venues for cosmic ray acceleration. I end this dissertation in Chapter 6 with a brief summary of my results and two extensions of this work: examining the late-time radio light curves of CSM-interacting SNe for signatures of radio synchrotron emission and dense or clumpy CSM at large distances from the progenitor and re-observing SNR-MC interactions in ¹²CO 𝐽=3-2 in order to verify the presence of shock-heated molecular gas and perform a census on the densities and temperatures of post-shock molecular gas.

The study of Supernova Remnants (SNRs) is fundamental to understanding the chemical enrichment and magnetism in galaxies, including our own Milky Way. In an effort to understand the connection between the morphology of SNRs and the Galactic Magnetic Field (GMF), we have examined the radio images of all known SNRs in our Galaxy and compiled a large sample that have an axisymmetric morphology, which we define to mean SNRs with a bilateral or barrel-shaped morphology, in addition to one-sided shells. We selected the cleanest examples and model each of these at their appropriate Galactic position using two GMF models, one of which includes a vertical halo component, and another that is oriented entirely parallel to the plane. Since the magnitude and relative orientation of the magnetic field changes with distance from the Sun, we analyze a range of distances, from 0.5 to 10 kpc in each case. Using a physically motivated model of an SNR expanding into an ambient GMF that includes a vertical halo component, we find it is possible to reproduce observed morphologies of many SNRs in our sample. These results strongly support the presence of an off-plane, vertical component to the GMF, and the importance of the Galactic field on SNR morphology. Our approach also provides a potentially new method for determining distances to SNRs, or conversely, distances to features in the large-scale GMF if SNR distances are known. The mechanism for acceleration of cosmic rays in SNRs is another outstanding question in the field. To investigate this, the same sample of axisymmetric SNRs was again modelled, but this time using two competing, and physically motivated, Cosmic Ray Electron (CRE) acceleration cases: quasi-perpendicular and quasi-parallel. We find that the quasi-perpendicular CRE acceleration case is much more consistent with the data than the quasi-parallel CRE acceleration case, with G327.6+14.6 (SN1006) being a notable exception. We propose that SN1006 may be an example of a case where both quasi-parallel and quasi-perpendicular acceleration is simultaneously at play in a single SNR. / October 2016

In 2009 Bañados, Silk and West described the possibility of principally unbounded collision energies in the centre-of-mass frame for the particle collisions in the vicinity of black holes. Their work attracted a big response. This thesis aims to summarise the results of a number of the articles about the topic and puts these results into a new, broader context. It also presents some generalisations of the existing results, especially for models of magnetised black holes. The main subject of interest is the question, whether the unbounded collision energies can be achieved in a single-scattering or multiple-scattering process which was first formulated by Grib, Pavlov and Zaslavskii. Variety of methods is summarised. A considerable attention is paid to the limiting near-horizon description, which is further developed in order to derive new links and relations among known results, particularly between the purely theoretical work dealing with the geometry of degenerate horizons and their vicinity and more astrophysical articles about magnetic fluxes. Powered by TCPDF (www.tcpdf.org)