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Waste-to-Energy : A study on Reaction Kinetics of Tropical Wood SawdustTita, Bertrand Asongwe January 2016 (has links)
The reaction kinetics of Iroko and Mahogany were studied using TGA. The pyrolysis process was achieved using six different heating rates of 2,5,8,12,15 and 20˚C. A 15˚C/min heating rate was used for gasification in steam at different temperatures while varying the concentrations of nitrogen and steam in the process. The kinetic parameters, activation energy and pre exponential factor, were obtained by implementing two chosen kinetic models. These models are: Friedman’s Iso-conversional Method, Flynn-Wall-Ozawa Method (FWO). There were substantial differences in the values of the kinetic triplets found from the experiments. Due to the substantial differences in the values, it was not the best way to perform this kind of analysis (which is the traditional way) but instead to use pure regression analysis; but using it for the whole data set (that means for all heating rates) and minimize the difference with experimental data.
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Effects of ozonation on cooling water systemsMosugelo, Keneetswe Lilian 26 July 2010 (has links)
Cooling water systems are needed to dissipate heat. The mist from open system cooling towers has been implicated as a source of infections of Legionella pneumophila. As a result biocide is added to cooling water systems, but the addition of biocide worsens biofouling, scaling and corrosion. Increasing environmental pressure has resulted in a move away from biocides which are usually chlorine based chemicals, so that the use of ozone instead has recently been reported as a way of controlling microbiological growth. This study aims to compare the corrosion rates (using calculated and measured surface areas) of different metals exposed to chemically treated and ozone treated cooling water in an industrial cooling water system. The types of corrosion were also observed and recorded. The scales from different components of the cooling systems as well as scale from chemically and ozone treated D tower water were characterized qualitatively using X-ray diffraction (XRD), Thermo gravimetric Analysis (TGA) and Atomic Absorption Spectroscopy. The D tower is a cooling water circuit in which the cooling water is from the Vaal River. As expected, the stainless steel has the lowest corrosion rate of 0.000 milli inches/year followed by brass with 1.531 milli inches/year and lastly mild steel (2.098 milli inches/year). Water quality rather than the presence or absence of ozone determines the corrosion rate. This confirms the findings reported in the literature. Scale from chemically treated water contains many different compounds while scale from ozone treated contains only different polymorphs of CaCO3, which is present in the water source and magnesium calcite.
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Studies of the surface and bulk reactivity of calcium hydroxideYeates, David January 1989 (has links)
The physical characteristics and reactivity of a number of commercially available samples of calcium oxide and hydroxide were investigated. 'Fresh' and 'aged' (Le. exposed to the atmosphere) samples were characterised by Fourier Transform Infra-Red Spectroscopy, Thermo-Gravimetric Analysis, Nitrogen Adsorption, Water Adsorption, Scanning Electron Microscopy and Microprobe Analysis. From this slight differences in the 'fresh' samples were found to be due to various degrees of atmospheric ageing. The main process involved in the ageing process was confirmed to be carbonatation (or carbonation). This ageing process was then followed by analysing a sample of calcium hydroxide over a long time period (350 days) and by looking at variations in the process by exposure of the sample to various gases and vapours, i.e. water, dried carbon dioxide, deuterium oxide, ethanol and methanol. These experiments showed that the reaction probably proceeded by a direct reaction between the carbon dioxide gas and the solid and confirmed that water was important when considering the rate of the carbonatation reaction. This was thought to be due to its influence in disrupting the calcium hydroxide structure, thus allowing new surface to become available for reaction and allowing the formation of a bulk calcium carbonate structure. Water adsorption isotherms carried out on the calcium hydroxide at elevated temperatures (250°C and above) showed that outgassing at such temperatures caused a partial decomposition to calcium oxide but that the original calcium hydroxide structure remained intact. These isotherms also had negative hysteresis which was thought to be due to the take up of water in an expanded skeletal calcium hydroxide structure which was expelled from the structure when it fully reconstituted at higher relative pressures to reform calcium hydroxide.
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Nylon-6/Agricultural Filler CompositesAmintowlieh, Yasaman January 2010 (has links)
Preparation of thermoplastics composites using engineering thermoplastics and plant fibers or fillers is a technical challenge because the processing temperature of the thermoplastics is generally above the temperature of degradation of plant fibers of fillers. There have been numerous attempts for processing high melting point engineering thermoplastics like Nylon-6 with plant natural fibers and fillers. Low temperature processing methods, fiber modification or addition of additives which drops polymer melting point are some of proposed solutions for this problem.
The objective of this thesis was to develop a formulation using wheat straw (WS) as a reinforcing fiber for Nylon-6. The concentration of WS was 15 wt-%. The thermoplastic composites were prepared by mixing grinded wheat straw and Nylon-6 using a laboratory scale twin-screw extruder; follow by preparation of samples using injection moulding. The strategy investigated in this thesis was utilization of additives to lower the melting point or to decrease the viscosity of Nylon-6. Lithium chloride salt (LiCl) and N-Butyl benzene Sulfon amide plasticizer (N-BBSA) were used as process additives to decrease melting point and to reduce the processing temperature and time.
The addition of the wheat straw (15 wt-%) to the Nylon-6 increased modulus by 26.9 % but decreased the strength by 9.9 %. Effect of different level of these two additives on mechanical, thermal, physical properties and processability of the composite runs were studied. Addition of 4 wt-% LiCl was found to decrease the melting point from 222 °C to 191 °C, to increase modulus by 14 % in comparison to Nylon-6/wheat straw (15 wt-%). However, it decreased the processability and strength by 12.7 %.
Plasticizer was investigated to easing processability and decreasing the degradation by reducing the residence time in the extruder, it does not affect the melting point of Nylon-6. The addition of 4 wt-% of plasticizer (N-BBSA) increased modulus and strength only by 2.6 % and 3 %, respectively, in comparison to Nylon-6/wheat straw (15 wt-%) composites. The results of mechanical properties were used as a benchmark for comparisons among samples with different formulations (levels of additives) to find out levels of LiCl and N-BBSA for the best mechanical properties. It was found that samples with 2 wt-% LiCl and 2 wt-% of N-BBSA had 29.3 % higher tensile modulus than neat Nylon-6, while its strength was almost same as neat Nylon-6 and 6.3 % higher than Nylon-6/WS (15 wt-%). These results were used to correlate the mechanical properties as a function of percentage of salt and plasticizer in the formulation.
Differential scanning calorimetry (DSC) was used to evaluate the percentage of crystallinity and the melting point of the thermoplastic phase and thermal gravimetric analysis (TGA) was used to measure the thermal stability of different formulation. The kinetics of crystallization and degradation were evaluated using results from DSC and TGA, respectively. The activation energy for thermal degradation and the percentage of crystallinity of the thermoplastic composites were correlated to mechanical properties using linear regression. It was found that fiber degradation had a significant effect on strength but the effects of percentage of crystallinity on composites strength were insignificant. On the other hand, the percentage of crystallinity affects stiffness and impact strength. The ductility was a function of both crystallinity and thermal stability.
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Nylon-6/Agricultural Filler CompositesAmintowlieh, Yasaman January 2010 (has links)
Preparation of thermoplastics composites using engineering thermoplastics and plant fibers or fillers is a technical challenge because the processing temperature of the thermoplastics is generally above the temperature of degradation of plant fibers of fillers. There have been numerous attempts for processing high melting point engineering thermoplastics like Nylon-6 with plant natural fibers and fillers. Low temperature processing methods, fiber modification or addition of additives which drops polymer melting point are some of proposed solutions for this problem.
The objective of this thesis was to develop a formulation using wheat straw (WS) as a reinforcing fiber for Nylon-6. The concentration of WS was 15 wt-%. The thermoplastic composites were prepared by mixing grinded wheat straw and Nylon-6 using a laboratory scale twin-screw extruder; follow by preparation of samples using injection moulding. The strategy investigated in this thesis was utilization of additives to lower the melting point or to decrease the viscosity of Nylon-6. Lithium chloride salt (LiCl) and N-Butyl benzene Sulfon amide plasticizer (N-BBSA) were used as process additives to decrease melting point and to reduce the processing temperature and time.
The addition of the wheat straw (15 wt-%) to the Nylon-6 increased modulus by 26.9 % but decreased the strength by 9.9 %. Effect of different level of these two additives on mechanical, thermal, physical properties and processability of the composite runs were studied. Addition of 4 wt-% LiCl was found to decrease the melting point from 222 °C to 191 °C, to increase modulus by 14 % in comparison to Nylon-6/wheat straw (15 wt-%). However, it decreased the processability and strength by 12.7 %.
Plasticizer was investigated to easing processability and decreasing the degradation by reducing the residence time in the extruder, it does not affect the melting point of Nylon-6. The addition of 4 wt-% of plasticizer (N-BBSA) increased modulus and strength only by 2.6 % and 3 %, respectively, in comparison to Nylon-6/wheat straw (15 wt-%) composites. The results of mechanical properties were used as a benchmark for comparisons among samples with different formulations (levels of additives) to find out levels of LiCl and N-BBSA for the best mechanical properties. It was found that samples with 2 wt-% LiCl and 2 wt-% of N-BBSA had 29.3 % higher tensile modulus than neat Nylon-6, while its strength was almost same as neat Nylon-6 and 6.3 % higher than Nylon-6/WS (15 wt-%). These results were used to correlate the mechanical properties as a function of percentage of salt and plasticizer in the formulation.
Differential scanning calorimetry (DSC) was used to evaluate the percentage of crystallinity and the melting point of the thermoplastic phase and thermal gravimetric analysis (TGA) was used to measure the thermal stability of different formulation. The kinetics of crystallization and degradation were evaluated using results from DSC and TGA, respectively. The activation energy for thermal degradation and the percentage of crystallinity of the thermoplastic composites were correlated to mechanical properties using linear regression. It was found that fiber degradation had a significant effect on strength but the effects of percentage of crystallinity on composites strength were insignificant. On the other hand, the percentage of crystallinity affects stiffness and impact strength. The ductility was a function of both crystallinity and thermal stability.
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Bubbling Fluidized Bed Gasification of Biomass and Refuse Derived FuelRobinson, Travis January 2015 (has links)
In Canadian remote northern communities most electricity is generated by burning diesel fuel. However, because it is expensive to import fuel into remote communities the cost of electricity is very high. Waste management is also difficult in remote northern communities. The goal of this thesis was to investigate the co-gasification of refuse waste materials and biomass as a means of reducing solid waste volumes while also using locally available materials for power generation.
As part of this research, thermo-gravimetric analysis (TGA) was investigated as a potential means of characterizing refuse derived fuels (RDF). Laboratory sample preparation of RDF for TGA had not been thoroughly considered. Laboratory sample preparation is important since RDF is very heterogeneous compared to other solid fuels and since TGA typically requires a very small sample size. A TGA method was applied to a variety of materials prepared from a commercially available RDF using a variety of procedures. The repeatability of the experimental results was related to the sample preparation methods. Cryogenic ball milling was found to be an appropriate means of preparing RDF samples for TGA. Applicability of the TGA method to the determination of the renewable content of RDF was considered.
Air-blown auto-thermal gasification experiments using materials representative of waste and biomass were performed at 725°C, 800°C, and 875°C, using a 0.15 m internal diameter bubbling fluidized bed gasifier located at NRCan CametENERGY in Ottawa, Ontario. Commercially prepared RDF and PET scrap were used to represent waste materials. Commercially produced hardwood pellets were used to represent biomass. The co-gasification of hardwood pellets and commercially produced RDF indicated that each fuel make a contribution to the results which is proportional to its fraction in the feed mixture. Inclusion of the RDF in the fuel mixture led to bed agglomeration at the 875°C temperature condition. Higher temperatures were found to provide better conversion of the fuel to gas, and the limitation which inclusion of RDF places on the operating temperature of the gasifier negatively affects conversion of biomass.
Results obtained with RDF suggested that utilization of mixed waste for a thermal conversion process located in a Canadian remote northern community is probably not a viable option. It was then decided to target plastic waste in particular. Plastic could be source-separated, collected, and gasified alongside biomass. Polyethylene terephthalate (PET), which is often used for food and beverage containers, was chosen to represent plastic. Initially, attempts were made to co-gasify mixtures of PET pellets and hardwood pellets. These attempts failed due to the formation of coke above the bed. To alleviate these problems hardwood-PET composite pellets were manufactured and these were gasified at 725°C, 800°C, and 875°C. Inclusion of PET in the pellets dramatically increased the amount of tar produced during gasification.
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Removal of selected chlorinated phenolic compounds from water sources in Vaal Triangle using HPLC, Macadamia nutshell activated carbon and solid phase extractionMachedi, Sechaba 12 1900 (has links)
M. Tech (Department of Chemistry, Faculty of Applied and Computer Sciences) Vaal University of Technology. / In this study, analytical method for determining the chlorinated phenols in water was developed using High Performance Liquid Chromatography. The following four compounds which are 2, 4, 6- Trichlorophenol (2, 4, 6 TCP), 3-chlorophenol (3CP), 2, 4- Dichlorophenol (2, 4 DCP) and 4-chloro-3-methylphenol (4C3MP) were identified and
quantified with a High Performance Liquid Chromatography (HPLC). The validation parameters tested were,: linearity, trueness, precision, detection limit of quantitation, sensitivity, specificity, selectivity. The linear calibration ranges of five standard solution from 1-10 ppm. The linearity ranges between 0.9298-0.9813. The activated carbon based on the waste macadamia nutshell activated carbon (MAC) was investigated for its potential uses as an adsorbent for chlorinated phenols removal and compared with grafted macadamia nutshell activated carbon (GMAC). The adsorbent was characterized with Fourier transform infrared spectrophotometer (FTIR), scanning electron microscope (SEM) and thermo gravimetric analysis (TGA). The parameters such as pH, temperature, contact time, concentration and adsorbent were investigated by adsorption technique. The strata C18E has been used before for the same reason and therefore the research was based on mimic the functional group of solid phase extraction (SPE) into macadamia activated carbon (MAC). The functional groups in SPE C18E are benzene and octadecyl. MAC was grafted with strata C18E functional groups to compare its potential with the SPE. The pseudo-first-order and pseudo-second-order kinetic models were applied to verify the experimental data. The pseudo-second order exhibited the best fit for the kinetic studies for MAC adsorption. Chemical removal of chlorinated phenols from wastewater is necessary to reduce harmful products on the environment and human health. Chlorinated phenols have been previously listed as some of the highest priority contaminants and as well as mainly important capability carcinogenic toxins released from chemical plants. Their availability in water supplies was perceived by their bad taste and smell. The acceptable chlorinated phenols concentration in portable water is 1 (mg/l) base on the approval of world health organization. The permanent checking of chlorinated phenols in environmental samples has a greater significance and stresses highly effectiveness, common selectively and great sensitively methods. The maximum uptake of Phenol using weighed mass of MAC was found to be 78 % and for GMAC was 84% for both 2,4,6TCP. t=250 min, pH=5, Co=1mg/l, T = 25 oC and m = 0.3 g/l were the optimum condition for Phenol-MAC system and GMAC system. Over all analysis of equilibrium model analysis indicates the fitness of Langmuir isotherm model to Phenol MAC adsorption system, suggesting a monolayer adsorption of phenol on the surface of MAC. Phenol adsorption capacity of MAC was found to be decreasing with increase in temperature suggesting that the adsorption process was exothermic in nature, which was further supported by the negative values of change in enthalpy. Characterization of MAC and GMAC confirmed the mesoporous texture, highly carbonaceous nature and a higher effective surface area of 912 m2/g. The highest phenol uptake capacity of GMAC was found to be 8.0049 mg/g. The optimal conditions for various process parameters are t = 250 min, pH=5, Co=1mg/l, T = 25 oC and m = 0.3 g/l were the optimum condition for Phenol-GMAC system. Like Phenol-MAC system, the kinetics studies confirmed that Phenol-GMAC adsorption system can be described by pseudo- second-order kinetics model. Equilibrium model analysis indicates the fitness of Langmuir isotherm model to Phenol-MAC adsorption system, suggesting a monolayer adsorption of phenol on the surface of GMAC. Phenol adsorption capacity of GMAC was found to be decreasing with increase in temperature suggesting that the adsorption process was exothermic in nature, which was further supported by the negative values of change in enthalpy. The negative values of Gibb’s free energy suggested that adsorption of phenol onto GMAC was a spontaneous process.
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Levantamento e estudo das ocorrências de grafita do Distrito Grafitífero Aracoiába-Baturité, CE / Survey and study of graphite occurrences in the Aracoiába-Baturité graphite bearing District, CEPaulo Roberto Pizarro Fragomeni 23 March 2011 (has links)
O Distrito Grafitífero Aracoiába-Baturité apresenta depósitos do tipo gnaisse grafitoso (minério disseminado) e veio (minério maciço) com diferentes origens genéticas e com características físicas e ambientes geológicos de formação próprios. O minério tipo gnaisse grafitoso é de origem sedimentar, singenético, com teores de 1,5 a 8% de C, que se distribuem ao longo de duas extensas faixas paralelas, hospedadas na Subunidade Baturité, que constitui um importante metalotecto regional. A associação de grafita metamórfica disseminada em metassedimentos da Sequência Acarápe constitui um geoindicador de antiga bacia sedimentar neoproterozóica e, também, pode ser considerado como zona de geosutura resultante do subsequente fechamento de um oceano primitivo. As rochas desta subunidade correspondem na paleogeografia da Sequência Acarápe aos fácies de sopé de talude e de planície abissal. O minério tipo veio (fluido depositado) é epigenético e, com teores entre 20% e 70% de C, forma corpos tabulares e bolsões, controlados em escala local por estruturas de alívio (falhas, fraturas, zonas de contato, eixos de dobras etc.) que permitiram a percolação de soluções penumatolíticas relacionadas ao corpo plutônico de Pedra Aguda. As variações dos valores das relações entre isótopos estáveis de carbono (δ13C) na grafita do minério disseminado são de -26,72 a -23,52 e do minério maciço de -27,03 a -20,83, revelando sinal de atividades biológicas (bioassinaturas) e permitem afirmar que a grafita das amostras acima são derivadas de matéria orgânica. Foram apresentados os principais guias de prospecção para grafita e testados os seguintes métodos geofísicos: Eletro-Resistividade; GPR - Ground Penetrating Radar; Magnetometria; VLF (Very Low Frequency); e Polarização Induzida Espectral (IPS) / Resistividade (ER). A conjugação dos métodos de Polarização Induzida Espectral (IPS) e Eletro Resistividade (ER) foi o que demonstrou a melhor eficiência. Com relação à determinação do teor de carbono por termogravimetria (ATG), que é o método mais utilizado para este elemento. Verificou-se, que as faixas de queima atribuídas ao carbono no minério do Distrito de Aracoiába-Baturité (340 a 570C e de 570 a 1050C) eram diferentes das faixas do minério de Minas Gerais (350C a 650C e 650C a 1.050C). Esta constatação indica a necessidade de se determinar previamente as faixas de temperatura para cada região pesquisada. / The Aracoiába-Baturité Graphite-bearing District has graphitic gneiss deposits (disseminated ore) and vein (solid ore) with different genetic origins and their own physical characteristics
and geological environments. The graphite gneiss ore is of sedimentary, syngenetic origin, with 1.5% to 8% C content, which is distributed along two long parallel belts, hosted in the
Baturité Sub-unit, which consists of a major regional metallotect. The association of metamorphic graphite disseminated in metasediments of the Acarápe Sequence consists of a geoindicator of an old Neo-Proterozoic sedimentary basin and also can be considered a geosuture
zone, the result of the subsequent closing of a primitive ocean. The rocks of this subunit correspond in the paleogeography of the Acarápe Sequence to the facies of the bottom of a slope and of an abyssal plain. The vein ore (deposited fluid) is epigenetic and, with C contents of between 20% and 70%, forms tabular bodies and pockets, controlled on a local scale by relief structures (faults, fractures, contact zones, fold axes, etc.), which allowed
seepage of pneumatolithic solutions relating to the plutonic body of Pedra Aguda. The variations in the values of the ratios between stable carbon isotopes (δ13C) in the graphite of the disseminated ore are -26.72 to -23.52 and of the solid ore -27.03 to -20.83, showing a sign of biological activities (biosignatures), and it can be said that the graphite of the above samples is derived from organic matter. The main prospecting guides for graphite were presented and the following geophysical methods tested: Electro-resistivity (ER);
Ground Penetrating Radar (GPR); Magnetometry; Very Low Frequency (VLF); and Spectral Induced Polarization (SIP) / Electro-resistivity (ER). It was found that the combination of the Spectral Induced Polarization (SIP) and Electro-resistivity (ER) methods proved the most efficient. In relation to determining the carbon content using thermogravimetry (TG), which is the most commonly used method for this element, it was found that the bands of burning attributed to the carbon in the ore in the Aracoiába-Baturité District (340 to 570C and from 570oC to 1050C) were different from the bands of the ore in Minas Gerais (350C to 650C and 650C to 1050C). This finding suggests the need to determine beforehand the temperature ranges for each region studied.
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Fused Arenes-Based Molecular and Polymeric Materials for Organic Field Effect TransistorsIrugulapati, Harista 01 May 2013 (has links)
In the past decade, tremendous progress has been made in organic field effecttransistors. Fused oligothiophenes and anthracene molecules are fascinatingmacromolecules having unique optoelectronic properties. These compounds are successfully employed as active components in optoelectronic devices including field effect transistors. Our goal is to design and synthesize conjugated molecular materials, which are highly functionalized through structural modifications in order to enhance their electronic, photonic, and morphological properties. The main desire is to synthesize novel organic fused-arenes having efficient charge carrier mobilities, as well as to optimize optical properties for organic field effect transistors (OFETs). Novel series of fused arene molecules of 9,10-di(thiophen-3-yl)anthracene (1), trans-2,5-(dianthracene-9- vinyl)thiophene (2), trans-5,5’-(dianthracene-9-yl)vinyl)- 2,2’-bithiophene (3), 5,5’-di(2 thiophene)-2,2’-bithiophene (4) , 9,10-(divinyl)anthracene core with 1- phenylcarboxypyrene (6) and polymers of poly(anthracene-co-bithiophene) (5) and poly(anthracene) (7) have been synthesized as promising materials for organic field effect transistors (OFETs). These compounds were confirmed and characterized by 1H-NMR, FT-IR, and elemental analysis. Their optical, thermal, and electronic properties were investigated using UV-Vis and photoluminescence spectroscopy, and thermogravimetric analysis respectively. Future studies will focus on evaluating OFETs performance of these material.
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Estudo e desenvolvimento de conjuntos membrana-eletrodos (MEA) para célula a combustível de eletrólito polimérico condutor de prótons (PEMFC) com eletrocatalisadores à base de paládio / Study and development of membrane electrode assemblies for proton exchange membrane fuel cell (PEMFC) with palladium based catalystsBONIFACIO, RAFAEL N. 09 October 2014 (has links)
Made available in DSpace on 2014-10-09T12:42:20Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T13:59:42Z (GMT). No. of bitstreams: 0 / Tese (Doutoramento) / IPEN/T / Instituto de Pesquisas Energeticas e Nucleares - IPEN-CNEN/SP
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