Thesis (Ph. D.)--Hong Kong University of Science and Technology, 2002. / Includes bibliographical references (leaves 155-160). Also available in electronic version. Access restricted to campus users.

Thesis (M. Phil.)--Hong Kong University of Science and Technology, 2003. / Includes bibliographical references (leaves 94-98). Also available in electronic version. Access restricted to campus users.

Thesis (Ph. D.)--Lehigh University, 2003. / Includes vita. Includes bibliographical references (leaves 198-205).

published_or_final_version / Orthopaedics and Traumatology / Master / Master of Philosophy

Vacuum Arc Remelting (VAR) is a secondary process used for homogenization of high-melting-point and oxygen-sensitive materials such as superalloys and titanium alloys. The VAR process is carried out with the aim of melting a large consumable electrode in such a way that the resulting ingot has improved homogeneity. The Specialty Metals Processing Consortium (SMPC) has spent the past 20 years developing technology to improve control over the final ingot remelting and solidification processes to alleviate conditions that lead to the formation of inclusions and segregation. Channel segregates are concentration defects arising during the solidification of large-diameter solute-rich alloys. As manufacturers for turbine engines and generators call for larger ingots, it becomes more difficult to produce them without these defects. If, however, liquid pool depth can be controlled precisely to stabilize the solidification zone in the ingot, we could, in principle, produce larger ingots that are defect free. A problem arises because measurements obtained from the VAR furnace do not give enough information to accurately estimate the liquid pool shape in dynamic melting situations. Also, the solidification process in VAR is extremely complex due to the multiple physical domains present and a high-fidelity model is required to give an accurate description of the dynamic process. The Basic Axisymmetric Remelting (BAR) code was initially developed by Lee Bertram at Sandia National Laboratories as a high-fidelity multi-energy model to describe ingot casting in this system. In this work we present a new strategy to improve the accuracy of the estimates used in the control system. This strategy consists of implementing BAR as a new set of measurements to be used by the estimator. This new strategy was used in tests jointly sponsored by SMPC and Los Alamos National Laboratory (LANL) in February 2011 using a laboratory-scale furnace and alloy 718 electrodes. / text

The high temperature fatigue crack growth behaviour of the newly developed, metastable titanium-based alloy, TIMETAL 21S, was investigated in an inert and an oxidizing environment. The investigation adopted a two pronged approached, namely, to initially establish the pure microstructural behaviour under oxidizing and inert environments at various elevated temperatures, and consequently, to establish the environmental effects on the fatigue crack growth behaviour in the various environments at high temperature. The effect of the oxidizing environment on the metastable alloy and on the mechanical and chemical events occurring at the fatigue crack were studied by using optical and scanning electron microscopy, including ED X analysis, x-ray diffraction, and Auger Electron Spectroscopy (AES) . For the microstructural investigation, the TIMETAL 21S samples were exposed for 5 hours to a pure argon and argon + 20% O2 environment at 300°C to 750°C in increments of 50°C. The results showed that in the oxidizing environment a more homogeneous nucleation of the alpha phase had occurred at higher temperatures and that the oxide Ti02, in addition to the alpha case, had predominantly formed on the exposed surfaces. AES analysis showed that dissolution of the oxygen into the alloy occurred even at low temperatures. An LEFM approach was used to investigate fatigue crack growth rate (FCGR) of C(T) specimens at 375°C, 450°C, 550°C and 620°C in the argon and argon + 20% oxygen environment. The crack growth rates were monitored using load-line compliance and the beachmarking method - a method by which beach marks were impressed on the fracture surface to track the progressing crack. The results showed that the crack growth rates were lower in the oxidizing environment and was influenced by a synergistic effect of the temperature, stress intensity at the crack tip and the environment. In addition to the phenomena of crack tip shielding (a process whereby the effective crack tip driving force experienced at the crack tip was locally reduced), other mechanisms such as slip character modification and secondary cracking ahead of the crack tip, leading to crack tip blunting and branching, had to be incorporated to fully explain the crack growth behaviour. The tests conducted in the inert environment effectively excluded the effect of oxygen on the crack growth behaviour and substantiated that various mechanisms ultimately determined the FCGR in TIMETAL 21S at elevated temperatures. / Thesis (M.Sc.Eng.)-University of Natal, Durban, 1995.

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Thesis (M.S.)--University of Missouri--Rolla, 2007. / Vita. The entire thesis text is included in file. Title from title screen of thesis/dissertation PDF file (viewed November 29, 2007) Includes bibliographical references.