Thesis (Ph. D.)--University of Washington, 2005. / Vita. Includes bibliographical references (p. 95-98).

The FIRST program (Far Infrared Spectroscopy in the Troposphere) was created as an Instrument Incubator Program (IIP) by NASA Langley to demonstrate improved technology readiness levels (TRLs) for two technologies needed in the design of new imaging Fourier transform spectrometers (IFTS). The IIP IFTS was developed at the Space Dynamics Laboratory and flown to an altitude of 103,000 feet on an instrumented NASA balloon payload. The sensor collected approximately 15,000 interferograms during its 6-hour flight. Fourier transforms (FFT) produced acceptable results except for noise equivalent temperature differences (NETD) that were five times higher than goal and inconclusive transforms at seven strong absorption features. An alternate transform technique, maximum likelihood estimation (MLE), was implemented to improve spectral estimations at the absorptions and to improve the NETD for the sensor. Iterative expectation-maximization (EM) algorithms provide numerical solutions for the MLE. Four combinatorial forms of the EM algorithm were developed. Forms of the EM algorithm were developed to optimize amplitude estimations as a function of assumed noise distributions. 'Direct' and 'indirect' EM forms were developed to process the asymmetrical interferograms recorded by the FIRST sensor. The direct method extends the standard even (cosine) EM algorithm to simultaneously transform both the sine and cosine components of the interferogram. The indirect method, uses Fourier and inverse Fourier transforms as pre-processors to convert the measured asymmetrical interferograms to even (cosine) interferograms. Using the indirect Gaussian EM form improved the measured NETD by approximately twenty percent between 100 and 700 wavenumbers. For wavenumbers less than 100 or greater than 700, the improvement increased to a factor of at least two out to 1500 wavenumbers. The indirect Gaussian produced inconclusive results in the areas of high absorption because of large bias errors introduced by the FFT/IFFT pre-processing. The indirect method was found to be inadequate for estimating spectra at the deep absorptions. The direct EM method, on the other hand, has the potential to produce improved amplitude estimations at the absorptions since there are no inherent biases in the algorithm's initial conditions at a cost in computer resources and execution times that are four times those needed for the indirect method.

We derive tropospheric column BrO during the ARCTAS and ARCPAC field campaigns in spring 2008 using retrievals of total column BrO from the satellite UV nadir sensors OMI and GOME-2 using a radiative transfer model and stratospheric column BrO from a photochemical simulation. We conduct a comprehensive comparison of satellite-derived tropospheric BrO column to aircraft in-situ observations of BrO and related species. The aircraft profiles reveal that tropospheric BrO, when present during April 2008, was distributed over a broad range of altitudes rather than being confined to the planetary boundary layer (PBL). Perturbations to the total column resulting from tropospheric BrO are the same magnitude as perturbations due to longitudinal variations in the stratospheric component, so proper accounting of the stratospheric signal is essential for accurate determination of satellite-derived tropospheric BrO. We find reasonably good agreement between satellite-derived tropospheric BrO and columns found using aircraft in-situ BrO profiles, particularly when satellite radiances were obtained over bright surfaces (albedo >0.7), for solar zenith angle <80 degree and clear sky conditions. The rapid activation of BrO due to surface processes (the bromine explosion) is apparent in both the OMI and GOME-2 based tropospheric columns. The wide orbital swath of OMI allows examination of the evolution of tropospheric BrO on about hourly time intervals near the pole. Low surface pressure, strong wind, and high PBL height are associated with an observed BrO activation event, supporting the notion of bromine activation by high winds over snow. We also provide monthly climatological maps of free tropospheric BrO volume mixing ratio (VMR) derived using the so-called cloud slicing technique. In this approach, the derived slope of the total column BrO versus cloud pressure is proportional to free tropospheric BrO VMR. Estimated BrO VMR shows a minimum in the tropics and greater values at higher latitudes in both hemispheres. High tropospheric BrO VMR at high latitudes in spring could be influenced by near-surface bromine activation.

Thesis (Ed.D.)--Teachers College, Columbia University, 1995. / Typescript; issued also on microfilm. Sponsor: Warren E. Yasso. Dissertation Committee: O. Roger Anderson. Includes bibliographical references (leaves 95-109).

Thesis (Ph. D.)--University of Washington, 2004. / Vita. Includes bibliographical references (leaves 196-214).

This thesis describes the refinements, modifications and additions to a prototype Very High Frequency (VHF) Boundary Layer (BL) Spaced Antenna (SA) radar initially installed at the University of Adelaide's Buckland Park field site in 1997. Previous radar observations of the lowest few kilometres of the atmosphere, in particular the Atmospheric Boundary Layer, have used Ultra-High Frequency (UHF) radars. Unlike VHF radars, UHF radars are extremely sensitive to hydro-meteors and have difficulty in distinguishing clear-air echoes from precipitation returns. The advantages and requirements of using a VHF radar to observe the lowest heights is discussed in conjunction with some of the limitations. The successful operation of the system over long periods has enabled in-depth investigation of the performance of the system in a variety of conditions and locations. Observations were made from as low as 300m and as high as 8 km, dependent upon conditions. Comparisons between the radar and alternative wind measuring devices were carried out and examined. The antenna system of the radar is a critical component which was analysed in depth and subsequently re-designed. Through the use of numerical models and mea- surements, evaluation of different designs was accomplished. Further calibration of the remaining components of the full system has enabled estimations of the absolute received power. Additional parameters which can be derived with a calibrated radar were compared with values obtained by other authors, giving favourable results. Full Correlation Analysis (FCA) is the predominant technique used in this work. A brief discussion of the background theory and parameters which can be measured is described. A simple one-dimensional model was developed and combined with a 'radar backscatter model' to investigate potential sources of errors in the parameters determined using FCA with the VHF Boundary Layer Radar. In particular, underes- timations in the wind velocity were examined. The integration of a Radio Acoustic Sounding System (RASS) to obtain tempera- ture profiles is discussed. The theory of RASS measurements including the limitations and considerations which are required for the VHF BL radar are given. The difficulties encountered trying to implement such a system and the subsequent success using a Stratospheric Tropospheric (ST) Profiler in place of the BL radar is presented. Taken as a whole this thesis shows the success of the VHF BL to obtain mea- surements from as low as 300m. The validation of this prototype radar provides an alternative and, in certain situations, a superior device with which to study the lower troposphere. / Thesis (Ph.D.)--Department of Physics and Mathematical Physics, 2001.

This work has focused on showing the differences among four different NMHC oxidation mechanisms: GT Lurmann, CBIV, RACM, and SAPRC mechanisms. This study was carried out to characterize these mechanisms using both specified NOx/NMHC gas mixtures and observational data from NASAs TRACE-P campaign. The differences among these mechanisms were found to be mainly driven by the use of different kinetic data and the specifics of each oxidation scheme. In the test runs, the differences between mechanisms were shown to be dependent on the levels of NOx and NMHC, as well as the reactivity of NMHC species used. Typically, propane had the smallest impact on all product species, whereas propene had the largest. Differences in the predicted levels of OH and HO2 were much smaller compared to those for CH3O2 and CH2O due to the fact that HOx species were generally less sensitive to the presence of NMHCs. During TRACE-P, which involved flights over only marine areas that were slightly polluted by the inflow of pollutants, the alkanes were the dominant NMHC family. Thus, most of the model runs involved relatively low levels of NMHCs and NOx. Therefore, the levels of OH, HO2, CH3O2, and CH2O predicted by the four mechanisms were not dramatically different. A net O3 increase was found only in areas where the NMHC reactivity was high. Because of the similar O3 destruction rates given by all four mechanisms, the difference in O3 tendency among these mechanisms was mainly determined by the O3 formation rate. A significantly higher (e.g., ~30%) O3 formation was found in the Lurmann mechanism than in CBIV due to the stronger contribution from the NO/RO2 channel in this mechanism. This resulted in a difference in the O3 tendency of a factor of 1.5. A major need in terms of future studies will be that of examining these same four mechanisms with a data set that enfolds observations in more polluted regions.

Tropospheric ozone columns (TCOs) derived from differences between the Dutch-Finnish Aura Ozone Monitoring Instrument (OMI) measurements of the total atmospheric ozone column and the Aura Microwave Limb Sounder (MLS) measurements of stratospheric ozone columns are discussed. Because the measurements by these two instruments are not spatially coincident, interpolation techniques, with emphasis on mapping the stratospheric columns in space and time using the relationships between lower stratospheric ozone and potential vorticity (PV) and geopotential heights (Z), are evaluated at mid-latitudes. It is shown that this PV mapping procedure produces somewhat better agreement in comparisons with ozonesonde measurements, particularly in winter, than does simple linear interpolation of the MLS stratospheric columns or the use of typical coincidence criteria at mid-latitudes. The OMI/MLS derived tropospheric columns are calculated to be 4 Dobson units (DU) smaller than the sonde measured columns at mid-latitudes. Standard deviations between the derived tropospheric columns and those measured by ozonesondes are 9 DU (30%) annually but they are just 6 DU (15%) in summer. Uncertainties in the interpolated MLS stratospheric columns are likely to be the primary cause of these standard deviations. An important advantage of the PV mapping approach is that it works well when MLS data are missing (e.g., when an orbit of measurements is missing). In the comparisons against ozonesonde measurements, it provides up to twice as many comparisons compared to the other techniques. The OMI/MLS derived tropospheric ozone columns have been compared with corresponding columns based on the Tropospheric Emission Spectrometer (TES) measurements, and Regional chEmical trAnsport Model (REAM) simulations. The variability of tropospheric ozone columns has been examined for spring and summer 2005 over North America and the surrounding oceans. Comparisons of monthly mean distributions show good agreements between OMI/MLS tropospheric ozone columns, REAM columns, and TES columns. Two six-day periods in March have been selected to study the periodic TCO enhancements in two regions, around the Baja peninsula (Mexico) and over the West Coast of California. Thirteen-day back trajectories and daily maps of carbon monoxide (CO) and ozone from GEOS-CHEM and OMI/MLS have been used to investigate the influence of cross-Pacific transport. It is concluded that in the first period of the case study, the high ozone concentrations in mid and lower troposphere over the West Coast of California have been under the influence of cross-Pacific transport. Meteorological fields indicate that the high ozone concentrations in the upper troposphere over the West Coast of California and the high TCOs over the Baja peninsula are associated with stratospheric intrusions through a deep Rossby wave breaking event. The correlations between REAM TCOs and surface ozone from Environmental Protection Agency ground network measurements indicate that the TCO enhancement over the West Coast is associated with an increase of surface ozone. The correlations of REAM TCOs with geopotential height, wind fields, and tropopause height during the case study period suggest that TCO enhancement is best characterized in springtime by decreases of geopotential height on the 500 mb surface.

Thesis (Ph. D.)--University of Washington, 2000. / Vita. Includes bibliographical references (p. 130-136).

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