Master of Science

Two studies were initiated in the Virginia southern Piedmont to assess characterization, classification, and productivity of soils mapped as Cecil-Pacolet (clayey, kaolinitic, thermic Typic Hapludults). Effects of erosion on Ap and Bt soil properties and soybean grain yields were studied in Pittsylvania and Lunenburg counties. Relationships between soil properties, soybean yields, and erosion classes were not observed until the soils became severely eroded. Water contents at -10kPa and -1500kPa increased as clay content increased but plant available water remained at 0.09 m³ m⁻³ across erosion classes. Available phosphorus (P) decreased with severity of erosion and was significantly correlated with soybean yield. The highest grain yields were on slightly and moderately eroded soils and were attributed to available P levels above 18 mg P kg⁻¹ critical level for optimum crop production. Low yields on the severely eroded sites corresponded to available P below 18 mg kg⁻¹. A second study on composition and variability of the Cecil-Pacolet map unit in Appomattox County showed large variation in soil properties and taxonomic classes. Variability is attributed to intrusions of mafic materials in the map unit. Variability was extreme within delineated soil bodies and was reflected in taxonomic classification in which up to six taxa can occur within the same delineation. Cecil and Pacolet soils comprise 62 percent of the map unit. Similar soils comprise 70 percent of the map unit and dissimilar soils make up the remaining 30 percent. The map unit is named Pacolet-Cecil and dissimilar soils are included in the mapping unit description. / Master of Science

Distributions of larval fishes in the Winfield Pool, Kanawha River, West Virginia, were determined by sampling two sites with bongo and push nets. Cyprinids, clupeids, and <i>Aplodinotus grunniens</i> dominated collections. Main channel densities were a fraction of the densities along the shoreline, indicating the importance of the shoreline as a nursery. Diel trends in abundance were evident for several taxa, but were likely caused by diel changes in gear avoidance and distribution of larvae. Vertical trends in abundance were apparent for several taxa at the deeper and more lentic sampling site (lower pool). <i>Aplodinotus grunniens</i> were generally more abundant near the bottom, especially during daylight. Cyprinids were more abundant near the bottom in mid-June, but displayed no vertical trends on other sampling dates. Clupeids were more abundant at middepth or surface during daylight, while equally dispersed or near the bottom at night. Vertical trends were not evident at the shallower and more lotic site (upper pool) except for <i>Aplodinotus grunniens</i>, which displayed the same preference for the bottom, as at the lower site. / Master of Science

This paper's objective is to determine the best approaches for clean-up of an underground oil leak using cost-benefit analysis. The background aspects of the leak, including a description and history of the oil plume, aspects of the site, and applicable Federal and local regulations, are discussed. Several remediation methods are chosen for examination. The costs associated with each method are estimated. An analysis of the area's property value data using the hedonic approach to benefits estimation is also conducted. Costs of the clean-up of the oil plume are compared to the benefits. It was determined that the amount of estimated benefits from restoration programs is $7.6 million. Based on this information and the cost data, the microbial fence / hydraulic containment method and the enhanced groundwater extraction / hydraulic containment method should be considered as remediation approaches. / Master of Arts

In the coalfields of Southwest Virginia, Iongwall technology accounts for an increasing proportion of underground coal mine production. lt is a highly productive, capital intensive method that provides a degree of mine safety greater than conventional methods. However, subsidence caused by Iongwall mining has been blamed for, among other things, damaging wells, springs, and streams above the mines. Surface landowners whose water supplies are affected by Iongwall mines may negotiate with mining companies for compensation, or they can seek redress in the courts. At the same time, the U.S. Surface Mine Control and Reclamation Act (SMCRA) provides a framework for regulation of the environmental effects of coal mining, including hydrologic effects. The Department of Mines, Minerals, and Energy, Division of Mined Land Reclamation (DMLR) is responsible for implementation of Virginia’s primacy program under SMCRA. This research has assessed the potential of Iongwall mining to damage the groundwater and surface water resources In Southwest Virginia; and examined whether existing laws and regulations, as implemented, provide an adequate and appropriate level of protection to both water property rights and the environment. Methods included review of published and ongoing literature on effects of underground coal mining on hydrologic systems and methods of mitigation; review of mining permits and complaint investigations on file at DMLR; review of court case decisions involving mining effects on groundwater and surface water; review of regulatory documents from other states active in Iongwall mining and the Federal Office of Surface Mining (OSM); and interviews with coal company personnel, DMLR and OSM officials, researchers, and regulatory officials in other states. Review of both DMLR complaint investigations and published reports of numerous hydrologic investigations indicate that longwall mining is likely to alter the hydrologic regime in the vicinity of the mine. The knowledge base for regulation of hydrologic impacts has been inadequate but is being improved in Virginia. Both DMLR and some coal companies recognize the need for more and better data, and are taking steps to develop the requisite data and models. Regulatory personnel in Ohio, Pennsylvania, West Virginia, and Kentucky have expressed recognition of similar data deficiencies in their states. At least one state, Ohio, has dealt with the problem of water rights by enacting legislation that assigns liability for replacing damaged water supplies to the mining companies. West Virginia, through its regulatory program, also requires water replacement. Recommendations are offered that have as their main objective the reduction of uncertainty about the effects of longwall mining and about compensation of surface owners for damage to water supplies. / Master of Urban and Regional Planning / incomplete_metadata

Land use pattern and plans influence future urban development. More desired urban forms can be created through land use decisions and policing power. Unfortunately, land use data is rarely analyzed, and researchers rely on a few historical, morphological studies for any information on land use change. Historical, morphological studies show that cities, and sections of cities, face different developmental problems at various points In time; for example, out-migration, poor quality housing, competition among employment sectors and lack of undeveloped land. How these problems are addressed depends on the current state of planning. Well-organized and up-dated plans address current and future growth, and foster or hinder specific kinds of growth. In Roanoke, Virginia, a bounded city with limited vacant land, redevelopment has become an essential element of growth. A case study of Roanoke examined the transformation of Roanoke's zoning ordinance from 1966 to 1987 when Roanoke was emerging from development into redevelopment. Publications by Roanoke City Government, rezoning request notices for the city from 1978 to 1991 and rezoning request files from 1982 to 1991 and publications on five neighborhoods were used to examine the (1) differences between the 1966 and 1987 zoning ordinances, (2) application of the 1966 zoning ordinance, (3) application of the 1987 zoning ordinance, and (4) application of conditional zoning. The data showed that zoning affected the land use pattern by fostering or hindering specific land use categories. The 1966 ordinance's large minimum lot sizes hindered the application of residential zoning categories by stopping small scale, inner city developments. The 1966 ordinance fostered the expansion of commercial and industrial zoning categories through an absence of lot size requirements. The 1987 zoning ordinance decreased the minimum lot size in several residential categories and added lot width, area and yardage requirements to commercial and industrial zoning categories. This ordinance preserved old. inner city structures through techniques, including historic districts. By addressing different developmental stages within the city, the ordinance encouraged infill development in inner city areas and planned unit developments in peripheral locations. Conditional zoning influenced the land use pattern by limiting changes. Land usage limitations give planners more control over land use changes that occur outside of the traditional rezoning process. Time limitations result in an automatic reversion of zoning if construction does not begin within the specified time. The zoning decision-makers used discretion in implementing zoning. Such decisions are important to planning and influence the types of land use changes approved. / Master of Science

The fact that when lime is added to clayey soils same very beneficial results are produced dates back into the remote past. It is not a new development, In the United States lime has been in use since l923. The objective of this study was to determine the effect of increasing soaking time of soil-lime mixtures on the strength, swell potential, and degree of saturation. In order to ascertain the exact composition of clay minerals, X-ray diffraction analysis was run on the soil sample. The analysis showed that the clayey soil contained a large amount of water with a greater percentage of halloysite minerals. The soil, it was concluded, was poorly crystalline and was found to be midway between montmorillonite and kaolinite group. / Master of Science

Motorboat activity can adversely effect the water quality of a reservoir. The potential impacts of motorboat activity on the Occoquan Reservoir's water and sediments were evaluated. Thirty-one sites, both marina and nonmarina, along the reservoir were selected. Sediment and water samples were collected in 1990, during peak boating activity, and in October, during low boating activity. The objectives of this research were to determine the concentrations of polyaromatic hydrocarbons (PAHs) in water and sediment samples and to determine if their presence was related to boating activity. The presence of other non-PAH organics was also determined. Contours of total PAH concentrations, boxplots and ANOVA analyses between marina and nonmarina sites were generated from gathered data in order to meet these objectives. PAHs were present in the water during peak boating activity and not detected during low boating activity, while PAHS were detected in the sediments during both sampling periods. The aqueous and sediment PAH concentrations were at or below the method detection limits. The PAH ratios of unalkylated PAHs confirmed PAH contamination to be of a combustion source. Boating was shown to be a PAH source to the water column, during peak boating activity, throughout the entire Occoquan Reservoir. An ANOVA between marina and nonmarina sites for the aqueous total PAH concentrations did not show a significant difference in June. This implied that boating did not cause any localized impacts to the water column and that there was another PAH source. There was a significant difference for total PAH concentrations between the marina and nonmarina sites for the sediment samples in June, showing localized impacts at marina areas due to boating activity. PAH profiles showed urban runoff as another major contributor to the PAH concentration in the water and sediments. The urbanization of Hooes Run and the hydrology of the reservoir caused urban runoff to impact localized areas. Finally, atmospheric deposition was also a source of PAHs to the sediments throughout the entire reservoir. Non-PAH organics found in a few of the water and sediment samples were the pesticides atrazine and p,p'-DDD, alkyl phosphates, alcohols and C₈ to C₁₂ hydrocarbons. / Master of Science

Hyperparasitism of beneficial parasites of Pieris rapae was studied on Brassica crops in Montgomery County, Virginia. The goal of the study was to determine whether the hyperparasites attacking the larval parasites of P. rapae were capable of eliminating an introduced population of the larval parasite Cotesia rubecula (Marshall) (Hymenoptera: Braconidae). Pieris rapae was found to be active from April to November with possibly six generations per year in this region. It was attacked throughout this period by five generations of the larval parasite Cotesia glomerata (L.) (Hymenoptera: Braconidae). Although P. rapae larvae were twice as numerous on broccoli (var. Premium Crop) than on cabbage (var. Rio Verde), a higher proportion of P. rapae larvae was parasitized by C. glomerata on cabbage, indicating that C. glomerata preferred to forage for P. rapae in cabbage. In spring plantings, up to 36.9% of C. glomerata cocoon masses had been affected by the hyperparasite T. galaetopus (Ratzeburg) (Hymenoptera: (Eulophidae) and 23.3% by the hyperparasite Spiloehaleis torvina Cresson (Hymenoptera: Chalcididae). In the fall, 93.2% and 4.2% of the cocoon masses were affected by T. galaetopus and S. torvina, respectively. Tetrastiehus galaetopus activity was observed from May to November, but it was most active after mid July. Tetrastiehus ga/aetopus had little impact on the gregarious C. glomerata, and even though it could affect >90% of the C. glomerata cocoon masses for extended periods, 500/0 of the cocoons in each mass were unaffected. However, it's high reproductive capacity could adversely affect a solitary host such as C. rubecula. Spilochalcis torvina was observed as early as late May but it was most active during the mid summer months. It's reproductive activity ceased by early October even though hosts were abundant in the month which followed. Four generations were seen between June and October. Spilochalcis torvina's hosts were Cotesia orobenae Forbes (Hymenoptera: Braconidae), C. glomerata, and Plutella xylostella (L.) (Lepidoptera: Plutellidae), but the principal host was C. glomerata. However, the proportion of female S. torvina progenies was <31% from the Cotesia spp. hosts and 70% from P. xylostella hosts. Spilochalcis torvina typically hyperparasitized <4 pupae per Cotesia spp. cocoon mass in the field. In laboratory experiments, S. torvina hyperparasitized an average of <7 C. rubecula pupae daily, and the maximum number hyperparasitized was 12. Due to its apparently low reproductive rate in the laboratory, and its low rate of hyperparasitization on hosts in the field, it is unlikely that S. torvina is a danger to populations of parasites like C. rubecula. / Master of Science

Because the Coastal Plain of southeastern Virginia has not been extensively studied, thirty random samples associated with Blackwater and Nottoway rivers were collected in the spring of 1987 from Surry, Sussex, and Southampton counties. Soil classification as well as mineralogical, chemical, and physical analysis were conducted for all samples. The purposes of this investigation were to: (1)classify the soils in this area, (2) determine the distribution of sand and clay minerals, (3) examine the weathering effect on clay minerals on different position of the landscape for different parent material sources. The soils examined classified as follow: Aquic Hapludults 43% > Typic Hapludults 26.6% > Ultic Hapludalfs 10% > Humic Hapludults 3% = Typic Rhodudlts 3% = Aquic Hapludalfs 3% = Typic Udipsamment 3% = Typic Quartzpsamment 3% = Psammentic Hapludalfs. Qualitative analysis of clay minerals revealed that kaolinite and hydroxy interlayer vermiculite were the dominant clay minerals; that montmorillonite, mica, gibbsite quartz, and vermiculite were of lesser quantities; that chlorite, feldspar and interstratified minerals were of trace amounts. Kaolinite represents about 21-70%, HlV 11-60%, montmorillonite 0-20%, mica 0-16%, gibbsite 0-13%, quartz 1-12%, and vermiculite 0-10%. The presence of these minerals were mainly related to the acid reaction of the soil media, which was essentially attributed to Al and H ions in soil solution. From the past history and geological composition of the Piedmont it is assumed that kaolinitic minerals were transported and sedimented in the Coastal Plain. Hydroxy-interlayer vermiculite minerals was weathering from vermiculite because most of the Al was adsorbed by vermiculite to form HIV. Therfore, gibbsite was not precipitated. Montmorillonite was assumed to have formed from mica minerals. That was substantiated by statistical analysis which showed a high negative correlation between gibbsite and vermiculite (r=0.46, n=30) and between montmorillonite and mica (r=-0.6, n=10). / Master of Science