Soputan volcano is one of the few basaltic volcanoes among 127 active volcanoes in Indonesia. It is part of the Sempu-Soputan volcanic complex located south of Tondano Caldera, North Sulawesi and commonly produces both explosive eruptions with VEI 2-3 and effusive lava dome and flow eruptions. Over the last two decades, Soputan had thirteen eruptions, the most recent in 2016. Most eruptions started explosively, followed by dome growth and in some cases pyroclastic flows. Our study focuses on understanding the magmatic system of Soputan and what processes are responsible for its highly explosive eruptions, which are typically uncommon for a basaltic magma composition. Our study includes tephra samples predating the 1911 eruptions, lava flow samples from the 2015 eruption, and ash from a 2015 fallout deposit. Our whole rock major and trace element composition are virtually identical to lava flow and select pyroclastic deposit compositions of Kushendratno et al. (2012) for the 1911-1912 and 1991-2007 eruptions. Bulk rocks contain 49 to 51 wt.% SiO2, whereas 2015 ash samples are slightly more silicic with 53 wt.% SiO2, consistent with segregation of groundmass from phenocrysts in the eruption cloud. Mantle normalized incompatible trace elements indicate strongly depleted HFSE (High Field Strength Elements) and REE (Rare Earth Elements) signatures but with spikes at Pb and Sr and mild enrichment of Rb and Ba. In comparison of data of this study with what was reported by Kushendratno et al. (2012), Fo68-79 olivine-hosted melt inclusions range from basaltic (48-52 wt.% SiO2) to basaltic andesite (54-55 wt.%) as compared to 54 - 65 wt.% SiO2 glass in Fo68-74 olivines. The compositional range of melt inclusions is consistent with 50% fractionation of multiple minerals including observed phenocrysts of olivine, plagioclase, pyroxene and oxides. Compositional trends with an inflection point likely reflect a change in the crystallizing assemblage, where early crystallization includes clinopyroxene and plagioclase, while later crystallization is dominated by plagioclase. New volatile concentration data from melt inclusions (S max. 0.35 wt.%, Cl max. 0.17%, H2O max. 5.2 wt.% from FTIR analyses) are higher than previously reported from younger samples (S max. ~0.07 wt.%, Cl max. 0.2%, H2O max. ~1 wt.%). H2O is relatively constant (~1-4 wt.%) for individual tephra samples (data by FTIR and water by difference method). Our inclusion data suggest that more volatile-rich magmas exist at depth and this is consistent with a model whereby recharge of deep, volatile-rich magmas into a more degassed and crystal-rich magma initiates a new, highly explosive eruption.

Surface manifestations of hydrothermal fluids such as fumaroles and hot springs provide valuable information about the level of activity of a volcano during quiescent period. Geochemical study of gas and spring waters is useful to elaborate geochemical model for magmatic-hydrothermal system. Furthermore, temporal geochemical monitoring of these fluids with time provides a better understanding in processes occurring inside the volcano and can be useful to detect any changes in the activity of the magmatic-hydrothermal system. This thesis investigates two hydrothermal systems at Kelud and Papandayan volcanoes that are located at Java Island in Indonesia. Kelud is considered as one of the most dangerous volcanoes of Java because of its frequent eruptions. After the last eruption that occurred in 1990, a new lake rapidly filled the crater of Kelud volcano. Water samples collected since 1993 are near neutral Na-K chloride fluids and are typical of aged hydrothermal system where the acidity has been completely neutralized by fluid-rock interaction and where the emission of acid magmatic gases has stopped. Two sudden increases in lake temperature in 1996 and 2001 were accompanied by rapid changes in lake water compositions and suggest the existence of two hydrothermal systems feeding the lake: a shallow hydrothermal system dominated by Ca-Mg sulfate waters and a deepest aquifer with neutral alkali chloride waters. From 2001 to 2005, measurements of CO2 emitted by the surface of the lake were performed by using the accumulation chamber method modified in order to work at the surface of a crater lake. Two statistical methods were used to process data: the graphical statistical and stochastic simulation methods. The results of graphical statistical approach showed that two different degassing processes are acting at the lake surface: one corresponding to CO2 fluxes resulting from rising bubbles and the other corresponding to equilibrium diffusion of dissolved CO2 at the water-air surface. Total CO2 emission rate estimated by stochastic simulation ranges from 105 t/day for 2001 to 32 t/day for 2005. Thermal energy released by the lake was also estimated by using an energy balance model with a new constraint using the CO2 flux. The thermal flux decreased from 200 MW (2001) to 100 MW (2002) and then remained stable. Correlation between the chemical data of waters, the fluxes of CO2 and energy show that a constant decrease in the level of activity of the volcano since 1993 occurred although the lake temperature has been stable since 2003. Since the last magmatic eruption that occurred in 1772, phreatic eruptions occur on Papandayan volcano with the last one in 2002. The volcanic material ejected during this eruption is essentially made of altered rocks from within the hydrothermal system. The interaction of acid waters with the host rocks corresponds to an advanced argilic alteration. The chemical compositions of waters from Papandayan volcano and Kelud lake waters are contrasting. Indeed, the spring waters sampled since 1994 are acid sulfate-chloride waters and acid sulfate waters. The chemical and isotopic analyses of gases and waters suggest a significant magmatic contribution in SO2, HCl and HF to the hydrothermal system. The chemical composition of waters sampled after the 2002 eruption have provided information about origin of this eruption. Decrease in chloride concentration and in delta 34S of dissolved sulfates showed that the magmatic contribution in these fluids are less important and that the waters are likely to be formed by the condensation of steam (H2O, H2S) rising from a boiling aquifer.<p><p> / Doctorat en sciences, Spécialisation géologie / info:eu-repo/semantics/nonPublished