The Altiplano-Puna Volcanic Complex in the Central Andes is one of the youngest large silicic volcanic fields (LSVFs) in the world, erupting over 13,000 km³ of material during multiple supereruptions from 11 to 1 Ma. Understanding the timescales over which magma is stored in the crust prior to eruption is crucial to understanding the development of LSVFs such as the APVC. The residence time of a magma is defined as the time between magma formation and its eruption. While the eruption age of a volcanic system is generally well constrained through ⁴⁰Ar/³⁹Ar dating of sanidine and biotite crystals, determining the time of magma formation offers a bigger challenge. U-Pb dating of zircon—an early crystallizing, ubiquitous phase in silicic systems—is a commonly used method for determining the timing of magma formation. U-Pb zircon ages were collected for 16 ignimbrites representing the temporal and spatial distribution of the APVC. Zircon crystallization histories show significant overlap between eruptive centers of similar age separated by as much as 200 km. Ignimbrites erupted from the same multicyclic caldera show little relationship. This suggests that ignimbrites may share a deeper, regional source. Timescales of zircon crystallization for individual ignimbrites range from ~400 ka to more than 1 Ma, with little correlation with age or erupted volume. Ignimbrites with longer crystallization timescales frequently exhibit a stepped age distribution and highly variable U contents, suggesting that these ignimbrites likely formed in a very crystalline, low melt fraction environment while ignimbrites with short crystallization times and constrained U concentrations crystallized in high melt fraction systems. Zircon crystallization histories record periods of continuous zircon crystallization in the APVC that extend over 1.5-2 Ma pulses and correlate well with eruptive pulses recognized by previous studies. Overall, zircon crystallization histories of the magmas feeding ignimbrite eruptions in the APVC record long timescales of magmatic activity from a shared regional source, likely the Altiplano-Puna Magma Body currently detectable underlying the APVC. / Graduation date: 2012

Four multicyclic complex calderas and smaller ignimbrite shields located within the Altiplano Puna Volcanic Complex of the Central Andes (APVC) erupted 13000 km�� of magma within the last 11 Ma. One of the largest and most complex of these is the Cerro Guacha Caldera. Ar-Ar age determinations and paleomagnetic directions suggest that the Cerro Guacha Caldera was formed by two major eruptions, caldera collapse, resurgence cycles and several smaller eruptions. Two major ignimbrites (> 600 km��) are found with ������Ar-�����Ar from biotites and sanidines of 5.65 �� 0.01Ma for the 1300 km�� (magma volume) Guacha ignimbrite and 3.49 �� 0.01Ma for the 800 km�� Tara Ignimbrite. The last major eruption occurred on the western flank producing the 1.72 �� 0.02 Ma Puripica Chico Ignimbrite with a volume of approximately 10 km��. Characteristic remanent magnetization data (ChRM) for these ignimbrites show that the Guacha has reverse polarity, while the Tara is normally polarized and the magnetic fingerprints have allowed their current full extents to be identified. A conspicuous lineament of volcanic structures in the eastern part of the caldera, bordering a caldera moat, filled out welded ignimbrites and sedimentary lacustrine sequences suggest an earlier 60x40 km outer collapse associated with the Guacha explosive episode. A central graben formed on the Guacha welded ignimbrite is related to a first episode of resurgence. Evidence of a second 30 x15 km inner collapse includes offset of welded Guacha ignimbrites and alignment of lava domes associated with the Tara ignimbrite. A second resurgence episode is suggested by the presence of an uplifted central block consisting primarily of welded Tara ignimbrite. As a whole the three ignimbrites (Guacha, Tara and Puripica Chico) share the same petrological and geochemical characteristics: high-K series, compositional ranges from dacite to rhyolite, with andesitic members present as lavas (for the Guacha and Puripica Chico Ignimbrites) and as pumices (for the Tara Ignimbrite). Highest silica content is found in the Chajnantor dome. Rayleigh modeling for Ba, Rb and Sr suggests at least 60% of crystal fractionation to account for the compositional variation between the Guacha andesite and the Chajnantor dome. Dy/Hb ratio increases with time from the Guacha andesite to the Negreal andesite suggesting stabilization of garnet owing to crustal thickening. Fe-Ti exchange geothermometry for the Tara Ignimbrite yielded log fO��� values ranging from -13.06 to -13.38 and temperatures of 714�� to 801��C. Amphibole geobarometry yielded pressures ranging from 150 to 180 MPa equivalent to 5.3 and 6.4 km depth respectively for the Tara Ignimbrite; the pressures range between 133 to 242 MPa, equivalent to 5.0 to 9.2 km depth for the Guacha Ignimbrite. The zircon saturation method yielded saturation temperatures of 716�� and 705��C for the Guacha and Chajnantor dome respectively and 784��C for the Tara Ignimbrite. The zircon crystallization range for the magmas of the Cerro Guacha Caldera is 1.25 Ma for the Guacha Ignimbrite; 1.09 Ma for the Puripica Chico Ignimbrite and 0.95 Ma for the Tara Ignimbrite. Recycling of antecrystic zircons within the caldera magmas is continuos through time. / Graduation date: 2012