This thesis mainly deals with the thermal treatment of waste - hazardous waste incineration and energy recovery municipal waste incinerators - their descriptions and analysis of legislative conditions. The flue gas cleaning system energy production in different operating modes is assessed by energy and mass balances. Computational models are developed for this purpose. On this basis, productions of energy from thermal treatment of hazardous and communal waste were compared.

A CO2 emission analysis and system investigation of a direct fuel cell waste energy recovery and power generation system (DFC-ERG) for pressure letdown stations was undertaken. The hybrid system developed by FuelCell Energy Inc. is an integrated turboexpander and a direct internal reforming molten carbonate fuel cell system in a combined circle. At pressure letdown stations, popularly called city gates, the pressure of natural gas transported on long pipelines is reduced by traditional pressure regulating systems. Energy is lost as a result of pressure reduction. Pressure reduction also results in severe cooling of the gas due to the Joule Thompson effect, thus, requiring preheating of the natural gas using traditional gas fired-burners. The thermal energy generated results in the emission of green house gases. The DFC-ERG system is a novel waste energy recovery and green house gas mitigation system that can replace traditional pressure regulating systems on city gates. A DFC-ERG system has been simulated using UniSim Design process simulation software. A case study using data from Utilities Kingston’s city gate at Glenburnie was analysed. The waste energy recovery system was modelled using the design specifications of the FuelCell Energy Inc’s DFC 300 system and turboexpander design characteristics of Cryostar TG120. The Fuel Cell system sizing was based on the required thermal output, electrical power output, available configuration and cost. The predicted performance of the fuel cell system was simulated at a current density of 140mA/cm2, steam to carbon ratio of 3, fuel utilization of 75% and oxygen utilization of 30%. The power output of the turboexpander was found to strongly depend on the high pressure natural gas flowrate, temperature and pressure. The simulated DFC-ERG system was found to reduce CO2 emissions when the electrical power generated by the DFC-ERG system replaced electrical power generated by a coal fired plant. / Thesis (Master, Chemical Engineering) -- Queen's University, 2010-08-31 02:02:11.392

The diploma thesis is focused on the evaluation of small-scale waste to energy plants in the Czech Republic. In the first part, there is a survey of the corresponding literature and general evaluation of the specificities of these plants. The next section analyzes the technical and economic indicators of a specific technology by Microsoft Excel model. Finally, recommendations for small-scale waste to energy plants arising from the model are summarized.

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Dans le but de réduire la consommation en carburant et les émissions de CO2 des moteurs à combustion interne, un des leviers, qui a intéressé diffèrent acteurs dans le secteur automobile, est la récupération de l’énergie thermique disponible dans les gaz d’échappement. Malgré différents technologie ont été investigués dans le passé; les transferts de chaleur qui apparient dans les gaz d’échappement n’ont pas encore étés suffisamment étudiés. Le fait que les échanges de la chaleur apparent dans des conditions pulsatives, notamment due aux conditions de fonctionnement moteur, rende les connaissances acquis jusqu’à présent limités et ne pas exploitables. A l’état actuel on n’est pas capable de pouvoir prédire le transfert thermique convectif des écoulements pulsé. Les travaux de cette thèse s’instaurent dans la continuité de ce besoin, l’objectif principal est donc l’étude expérimentale du transfert thermique convectif des écoulements turbulent pulsés dans un conduit cylindrique. La première partie de ce travail a été consacrée à le dimensionnement d’un moyen d’essais permettant la création d’un écoulement pulsé type moteur; en suite différents méthodes de mesures ont étés développes afin de connaitre les variations instantanés de vitesse et température de l’écoulement. Plusieurs essais ont été reproduits afin de caractériser l’impact de la pulsation sur le transfert de la chaleur. Les résultats expérimentaux ont été analysés avec deux approches différentes: dans un premier temps une approche analytique 1D a permis de mettre en évidence le mécanisme principal responsable de l’amélioration du transfert thermique convectif,ainsi, il a fourni des éléments supplémentaires pour le futur développement de modèles mathématiques plus adaptés à la prédiction des transferts d’énergie. En suite une approche 2D, supporté d’une phase de modélisation numérique, a permis de caractériser le mécanisme de transport radial d’énergie thermique. / Waste Energy Recovery represents a promising way to go further in fuel saving and greenhouse emissions control for Internal Combustion Engine applications. Although several technologies have been investigated in the past few years, the convective heat transfers, playing an important role in the energy exchanges at the engine exhaust, has not receive enough attention. Heat transfers, in such applications, occur in pulsating conditions because of the engine operating conditions, making thus the actual knowledge of the heat transfer phenomena limited and not exploitable. Nowadays there is not any model capable to predict convective heat transfers for pulsating flows. In this context, the present thesis addresses the purpose to study the convective heat transfer phenomena, by an experimental approach, occurring for turbulent pulsating flows in pipes. In the first part of this work, an experimental apparatus has been designed to reproduce an exhaust type pulsating flow in fully managed conditions, as well as, several measurement techniques have been developed to know the instantaneous profiles of air temperature and velocity. Many experiments have been performed in order to characterize the impact of the flow pulsation on the convective heat transfers. In the second part of this work, the experimental results have been analyzed with two different approaches: firstly, with a 1D assumption the time-average convective heat transfers has been computed, and the major mechanism responsible of the heat transfer enhancement has been pointed out. Furthermore, it has been possible to highlight the mathematical term representative of such mechanism, which should be accounted in future to define a more adapted numerical model for the heat transfer prediction. In a second phase with a 2D assumption, and, with an energy and a fluid-mechanic computational phase, the radial transport of thermal energy has been characterized for a pulsating flow.