Thesis (M.S.)--West Virginia University, 1999. / Title from document title page. Document formatted into pages; contains ix, 129 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 114-120).

M. Tech (Department of Chemistry, Faculty of Applied and Computer Sciences) Vaal University of Technology. / The presence of tires in open fields, households and landfills is a great threat to the wellbeing of the ecosystem around them. Tire creates an ideal breeding ground for disease carrying vermins and their possible ignition threatens the surrounding air quality due to the harmful gases produced during combustion. Pyrolysis of tires produces four valuable products namely; char, steel, tire pyrolytic oil (TPO) and noncondensable gases. TPO has been reported to have similar properties to commercial diesel fuel. The biggest challenge faced by TPO to be used directly in combustion engines is the available sulfur content of about 1.0% wt. Considering the stringent regulations globally for allowable sulfur content in liquid fuels, TPO therefore, requires deep desulfurization before commercialization. In this study, different desulfurization techniques were applied to reduce the sulfur content in TPO. A novel study on combination of adsorptive and air-assisted oxidative desulfurization (AAOD) was developed for desulfurization of TPO. Different carbon materials were employed as catalyst and/or adsorbent for the AAOD system. The effect of operating conditions; catalyst/adsorbent dosage, H2O2/HCOOH ratio, reaction time, temperature and air flowrate were studied. Oxidation equilibrium was reached at 80 °C for both commercial activated carbon (CAC) and activated tire char (ATC) at a reaction time of 50 min. With a total oil recovery of more than 90% and the initial sulfur content of 7767.7 ppmw, the presence of air at a flow rate of 60 l/hr increased oxidation from 59.2% to 64.2% and 47.4% to 53% for CAC and ATC, respectively. The use π-complexation sorbent was also applied to study the selectivity of such sorbents to organosulfur compounds (OSC) found in liquid fuels. The π-complexationbased adsorbent was obtained by ion exchanging Y-zeolite with Cu+ cation using liquid phase ion exchange (LPIE). Batch adsorption experiments were carried out in borosilicate beakers filled with modified Cu(I)-Y zeolite for both TPO and synthesized model fuels. For model fuels (MF), the selectivity for adsorption of sulfur compounds followed the order dibenzothiophene (DBT)> benzothiophene (BT)> Thiophene.

Thesis (MBA)--Stellenbosch University, 2012. / Tyre waste from end-of-life tyres (ELTs), sometimes erroneously defined as a type of waste, in fact represents a renewable energy resource that is highly competitive as replacement fuel to coal in the form of tyre-derived fuel (TDF) or useable as rubber crumb in other products. In this research study, the main utilisation options considered were based on rubber crumbing through ambient and cryogenic processing. Pyrolysis, the so-called ‘holy grail’ of tyre technologies, rubberised asphalt products, TDF options and various other product options from tyre crumb as basis were considered. Although pyrolysis technology is highly commendable and environmentally friendly, it is still a process with too many variants and presents an unstable economic model that is not attractive to entrepreneurs. Rubberised asphalt depends on policy decisions from local and national authorities supporting initial higher spending and allowances on budgets to acquire future savings from the longevity in the product. The policy requirements and the instability that politically-inspired decisions carry with them are contributing to the unattractiveness of this solution to the entrepreneurial fraternity. Through government requiring a certain percentage of asphalt pavements to contain rubber (like in the United States of America (USA)), rubberised asphalt could be a very useful and viable option to produce. In the USA, the Environmental Protection Agency (EPA) recently avoided the return to coal in industrial kilns currently using TDF based on its beneficial carbon dioxide (CO2) emission and cost structures by defining TDF as Reasonably Available Control Technology (RACT) to existing coal-burning industrial kilns. In South Africa, the usage of TDF should be of interest to Eskom and the cement industry. TDF (produced from end-of-life tyres), defined as a renewable energy resource due to its proven biomass component and with its high calorific value, presents higher energy output values in comparison to coal and furthermore presents the industry with lower input costs per ton and reduces the CO2 emission factor. Entrepreneurial intervention involving Eskom and/or the cement industry in South Africa with the utilisation of end-of-life tyres as renewable energy resource is an overdue business opportunity. With more than ten million tyres per year available in South Africa and a stockpile of more than fifty million waste tyres, sustainability of TDF supplies is a reality. TDF is much cheaper per ton than coal and emits approximately 20 percent less CO2 and/or CO2e than low-grade coal to produce the same electricity output. From all the information gathered, it is clear that in countries where coal energy is extensively used, TDF utilisation not only reduces the tyre waste issues, but it also serves as an environmentally-friendly renewable energy resource in electricity production and cement kilns; the industry with some of the highest CO2 emission risks. The final chapter of this report presents a schedule representing the choice of tyre processing and disposal methods ranked by environmental preference and defining the priorities linked to process and product choice.