Vid vattenrening produceras slam som restprodukt. Slam innehåller en stor mängd ämnen, såsom metaller, medicinrester och olika näringsämnen. I Sverige produceras flera hundra tusen ton årligen. Innehållet måste hanteras, men hur görs det idag och hur kommer det att hanteras i framtiden. Vanligast idag är att återvinna fosfor och kväve genom att sprida slam som gödning inom jord och skogsbruk. Däremot metaller som finns i slam utvinns inte idag, även om det vore värdefullt ur miljösynpunkt.  Denna litteraturstudie beskriver hur slamhantering ser ut idag, med fokus på Sverige. Därefter beskrivs forskningsläge och möjlig framtida utveckling i hantering. Slamhantering är problematisk ur flera aspekter. Slamhantering behöver hantera följande svårigheter: En logistisk aspekt är de stora volymer som behöver hanteras och att de produceras på många olika platser.Forskning på konsekvenser av slamspridning är relativt liten. Det gäller den påverkan som medicinrester, tungmetaller och andra ämnen utgör.Vilka utvinningsbara ämnen ska prioriteras, eftersom metoder för utvinning ställer maximerad utvinning av gödning i motsats till maximerad utvinning av metaller. / When purifying water, sludge is produced as a residual product. Sludge contains lots of different substances, such as metals, medical waste and different nutrients. In Sweden there is many hundred thousands of tons of sludge produced annually. The content must be managed, but how is it handled today and how will it be managed in the future. Commonly today phosphorus and nitrogen recycles by spreading sludge as fertiliser in agriculture and forestry. Metals in sludge is not recycled, even if it would be positive from an environmental point of view. This literature study describes how sludge treatment is today with a focus in Sweden. Then it describes the current state of research and possible future development in management. Sludge handling is problematic from many different aspects. Sludge treatment must have to address these challanges: One logistic aspect is that there are great volumes that needs to be handled and that it is produced in many different places. The research in consequences of sludge spreading is a relatively small base. That goes for the influence of medical waste, heavy metals, and other substances in sludge. What recyclable substances needs to be prioritised, since the methods of extraction puts the maximal extraction of fertiliser against the maximised extractions of metals

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No / Modelling of wastewater temperatures along a sewer pipe using energy balance equations and assuming steady-state conditions was achieved. Modelling error was calculated, by comparing the predicted temperature drop to measured ones in three combined sewers, and was found to have an overall root mean squared error of 0.37 K. Downstream measured wastewater temperature was plotted against modelled values; their line gradients were found to be within the range of 0.9995-1.0012. The ultimate aim of the modelling is to assess the viability of recovering heat from sewer pipes. This is done by evaluating an appropriate location for a heat exchanger within a sewer network that can recover heat without impacting negatively on the downstream wastewater treatment plant (WWTP). Long sewers may prove to be more viable for heat recovery, as heat lost can be reclaimed before wastewater reaching the WWTP.

The process of allocating necessary resources like clean water, fuel/energy and food have resulted in an unsustainable use of natural resources causing problems with Soil erosion, soil fertility, desertification, deforestation, eutrophication and global warming. The purpose of this study was to gain information on the functional design of a waste management system enabling the organic components of domestic waste to be processed as useful resources while at the same time allow them to be re-circulated. The main part of this study was carried out at the Kendu SDA Hospital in the Rachyonyo district in western Kenya. For the case of this study two main objectives where chosen. The first was to develop a principal technological solution using three classed “appropriate technologies” found suitable for the purpose namely biogas, ecological water treatment systems and slow sand filtration. The second was to further analyse each included technology to further develop their potential to fit the concept. Results from the pilot facilities where then to be retrieved from the actual component selection and construction process itself, with performance analysis left for future studies. The main purpose of the biogas system study has been to evaluate the original ideas of overall concept, details, materials and construction methods. The 1 m3 biogas system has improved significantly during the development process and is today not far from an implementation, i.e. construction on a slightly larger scale. The biogas system developed during the project has proven to have potential for digestion of both latrine and kitchen waste. Using the two as fuel for the process does not only remove a problem – it grants several benefits. The ecological waste water treatment system main objective was to design and construct a pilot SSF-wetland. Results show that the construction process for smaller scaled SSF systems is simple and does not require trained personnel or specialized equipment and that significant cost reduction can be made by using locally available materials. The slow sand filtration sub system concept is called PT SCX and though still in the stage of development proved to have great potential concerning both efficiency and sustainability. The PT SCX comprises the advantages of slow sand filtration with further development of individual system solutions. It was adapted to enable both integration to the IWESS solution and stand alone installations purifying even highly turbid surface water sources to drinking water quality. The result from the study confirms the suitability of the three included technologies, ecological waste water treatment, biogas and slow sand filtration to work in an integrated system called IWESS- Integrated Water Energy and Sanitation Solution. The combined subsystems can together with source separated sewage offer full resource recovery enabling recirculation of both nutrients and water. In addition the system can be designed as a net producer of renewable and emission free energy.

<p>The process of allocating necessary resources like clean water, fuel/energy and food have resulted in an unsustainable use of natural resources causing problems with Soil erosion, soil fertility, desertification, deforestation, eutrophication and global warming. The purpose of this study was to gain information on the functional design of a waste management system enabling the organic components of domestic waste to be processed as useful resources while at the same time allow them to be re-circulated. The main part of this study was carried out at the Kendu SDA Hospital in the Rachyonyo district in western Kenya. For the case of this study two main objectives where chosen. The first was to develop a principal technological solution using three classed “appropriate technologies” found suitable for the purpose namely biogas, ecological water treatment systems and slow sand filtration. The second was to further analyse each included technology to further develop their potential to fit the concept. Results from the pilot facilities where then to be retrieved from the actual component selection and construction process itself, with performance analysis left for future studies.</p><p>The main purpose of the biogas system study has been to evaluate the original ideas of overall concept, details, materials and construction methods. The 1 m3 biogas system has improved significantly during the development process and is today not far from an implementation, i.e. construction on a slightly larger scale. The biogas system developed during the project has proven to have potential for digestion of both latrine and kitchen waste. Using the two as fuel for the process does not only remove a problem – it grants several benefits.</p><p>The ecological waste water treatment system main objective was to design and construct a pilot SSF-wetland. Results show that the construction process for smaller scaled SSF systems is simple and does not require trained personnel or specialized equipment and that significant cost reduction can be made by using locally available materials.</p><p>The slow sand filtration sub system concept is called PT SCX and though still in the stage of development proved to have great potential concerning both efficiency and sustainability. The PT SCX comprises the advantages of slow sand filtration with further development of individual system solutions. It was adapted to enable both integration to the IWESS solution and stand alone installations purifying even highly turbid surface water sources to drinking water quality.</p><p>The result from the study confirms the suitability of the three included technologies, ecological waste water treatment, biogas and slow sand filtration to work in an integrated system called IWESS- Integrated Water Energy and Sanitation Solution. The combined subsystems can together with source separated sewage offer full resource recovery enabling recirculation of both nutrients and water. In addition the system can be designed as a net producer of renewable and emission free energy.</p>

Synthetic musk compounds are artificial organic substances commonly used as fragrant constituents of personal care products as parfums, cosmetics, detergents, in-house cleaning and washing agents. Given their large area of applications and their ability to be persistent, they leaked into all parts of ecosystem, especially aquatic one. There have been a big focus on studiyng these compounds, their properties and fate in the different parts of ecosystems in the last years. The aim of master's thesis was carry out the determination of five representatives (habanolide, exaltolide, ambrettolide, musk MC4 and ethylene brassylate) of macrocyclic musk compounds in waste water samples from influent and effluent of three water treatment plants (WWTP Brno-Modřice, WWTP Lednice and WWTP Mikulov). One of the main tasks was to perform a method optimisation for the determination of selected musk compounds in waste water and evaluation and interpretation of the results. Solid phase microextraction (SPME) technique was used for the extraction of analytes, consequently gas chromatography-mass spectrometry was used for analysis of selected analytes. Following evaluation the removal efficiency of musk compounds in the waste water treatment plant was assessed.

<p>In the pilot plant at Hammarby Sjöstad, Sjöstadsverket, several new methods are tested in order to achieve a good use of resources. When a new technique is considered it is often the performance of the technique itself, under given conditions, that is evaluated. However, in order to evaluate the overall function the whole picture is needed. With a system analysis it becomes possible to make a comparison where all the positive aspects are put up against the negative ones, for the technique itself as well as its requirements. In this way the influence that minor components have on an entire system can be considered.</p><p>This report presents a system analysis of an anaerobic membrane reactor (MBR) with a VSEP-membrane (Vibratory Shear Enhanced Process). The MBR is tested at the research treatment plant at Hammarby Sjöstad. In the analysis presented two different treatment techniques treating two different types of wastewaters are compared. The considered techniques are conventional (represented by an active sludge process) and the MBRtechnique. The waters treated are a mixed wastewater and wastewater from a separating system where closet water is separated from greywater and mixed with food waste from waste disposers.</p><p>The system analysis has been carried out with the URWARE (URban WAter REsearch) system analysis tool. A new URWARE-model that describes the anaerobic reactor and the VSEP membrane was created in order to generate the system structures needed for the analysis. The model consists of two submodels, which as the other URWARE-models are mass-flow, steady-state models based on yearly average-values. The model was tested and calibrated from the test-results at the Hammarby Sjöstad pilot plant. In the study the systems are compared considering energy, exergy and recirculation of nutrients.</p><p>The VSEP-technique has some advantages compared to the conventional system as it ensures that a large part of the nutritional content in the wastewater can be retained. The advantage is more obvious with the separated system, where food waste is mixed with closet water. Also the global warming potential of the new technique is lower. However, conventional treatment is better from an exergy-perspective. This is mostly due to the high energy consumption as a result of the reversed osmosis (RO) required for post treatment.</p> / <p>I försöksanläggningen vid Hammarby Sjöstad, Sjöstadsverket undersöks flera olika metoder för att uppnå största möjliga resursutnyttjande. När en ny teknik utprovas är det i allmänhet funktionen hos den givna metoden under givna förutsättningar som undersöks. För att få ett helhetsperspektiv krävs emellertid att den sätts in i sitt sammanhang. En systemanalys gör det möjligt att få en bild av alla för- och nackdelar, såväl av tekniken i sig som av de förutsättningar den kräver. Även effekter som små delar har på ett helt system kan då belysas och dess betydelse för helheten fastställas.</p><p>Föreliggande studie möjliggör en systemanalytisk utvärdering av en anaerob membranbioreaktor (MBR) kopplad till ett VSEP-membran (Vibratory Shear Enhanced Process) som är under utprovning vid Sjöstadsverket. Studien jämför två vattenreningstekniker för behandling av två olika typer av avloppsvatten. Dels rör det sig om konventionell teknik (aktiv slam-rening liknande den behandlingsmetod som används idag), dels den nya MBRtekniken. De vatten som behandlas är blandat avloppsvatten respektive sorterat klosettvatten blandat med matavfall från avfallskvarnar.</p><p>Systemanalysen har utförts med hjälp av systemanalysverktyget URWARE (URban WAter REsearch). För att kunna bygga upp önskade systemstrukturer har en ny modell för att beskriva den anaeroba reaktorn och VSEP-membranet skapats inom ramen för detta examensarbete. Modellen består av två delmodeller, som liksom övriga modeller i URWARE är substansflödesmodeller där beräkningar är baserade på årsmedelvärden. Modellen har utprovats och kalibrerats mot mätresultat från pilotförsöken vid Sjöstadsverket. I studien jämförs systemen med avseende på energi, exergi och återföring av närsalter.</p><p>Utifrån systemanalysen konstateras att MBR-tekniken ger vissa fördelar gentemot konventionell teknik då en stor del av näringsinnehållet från avloppsvattnet kan fångas upp. Detta gäller speciellt då tekniken används i kombination med ett separerat avloppssystem där matavfall blandas med klosettvatten. Även växthuspotential för den nya tekniken är lägre totalt sett. Ur exergisynpunkt är konventionell teknik emellertid mer fördelaktig. Till stor del beror detta på hög energiförbrukning pga. den efterbehandling med omvänd osmos (RO) som systemet i dess nuvarande utformning kräver.</p>

The main objective of the thesis is to study artificial wastewater recharge in the area of Řevničov and reassessment of related problems such as groundwater chemical changes, colmatage, and unfavorable legislation in the Czech Republic. Individual chapters describe the experience with the above mentioned topic in the Czech Republic, but classifies it into the global context. The major part of the thesis focuses on the assessment of the qualitative and quantitative impacts of wastewater artificial recharge in the geological environment. These conclusions are drawn from monitoring changes of groundwater quality, which are controlled on the network of monitoring boreholes in the Řevničov experimental catchment. The natural attenuation of geological environment has considerable impact to final composition of contaminated water, which is compared to legal limits of underground and potable water in Czech Republic. In the research area several tracing tests were also applied, with the aim of proving the expected flow of wastewater into monitoring borehole. The obtained data specify the situation in the area of interest, or may serve as a source of information for future studies dealing with similar topics. Powered by TCPDF (www.tcpdf.org)

Le développement industriel et urbain accroit la pollution des eaux au Cameroun. Il faut donc rechercher des méthodes de dépollution peu onéreuses et de mise en oeuvre facile. L'objectif de ce travail était d'éliminer les métaux lourds (Cu2+, Pb2+, Hg2+, Cr3+) des eaux usées, par adsorption sur de l'argile brute ou traité thermiquement. L'argile alluviale prélevée dans la région de l'Extrême Nord du Cameroun est essentiellement composée de smectite (46%), kaolinite (38%), interstratifiés (10%) et quartz (5%). Les formules structurales sont (Si3,42Al0,58)(Al0,87Fe0,96Mg0,17)O10(OH)2(C+)0,75 , pour la smectite et Si2Al1,95Fe0,05O5(OH)4. pour la kaolinite. Les cations de métaux lourds s'adsorbent très rapidement sur l'argile brute ; la température et le pH de la solution influencent peu leur adsorption. L'affinité de l'argile pour Cu2+, et Pb2+ est très forte mais faible pour Hg2+ et Cr3+. Le mécanisme proposé est l'échange cationique et la complexation de surface pour l'adsorption de Cu2+, Pb2+ et Cr3+ et un mécanisme de spéciation pour l'adsorption de Hg2+. Les boulettes obtenues par traitement thermique de l'argile au dessus de 500°C sont stables en solution et montrent une bonne capacité d'adsorption des métaux lourds. Les boulettes sont moins efficaces que l'argile brute, mais leur utilisation, évitant la séparation solide-liquide, après adsorption est plus facile / The industrial and urban development increases the water pollution in Cameroon. It becomes imperative to develop inexpensive and easy to manage remediation methods. This work aimed at eliminating heavy metals (Cu2+, Pb2+, Hg2+, Cr3+) from water by adsorption on raw or heat treated clay. The alluvial clay sampled in the far North of Cameroon mainly contains smectite (46%), kaolinite (38%), interlayers (10%) and quartz (5%). The structural formulas are : (Si3,42Al0,58)(Al0,87Fe0,96Mg0,17)O10(OH)2(C+)0,75 for the smectite and Si2Al1,95Fe0,05O5(OH)4 for the kaolinite. The heavy metals cations fastly adsorb on raw clay, the temperature and the pH have not much influence on their adsorption. The clay affinity in relation to Cu2+, and Pb2+ is very strong whereas it is low for Hg2+, Cr3+. For the adsorption of Cu2+, Pb2+ and Cr3+ the proposed mechanisms are the cation exchange and the complexation while for the Hg2+, a mechanism of speciation is involved. The pellets obtained by thremic treatment of the clay above 500°C are stable in solution and they have a good capacity for heavy metals adsorption. Performances of the pellets are lower than those of raw clay, however, their use is easier since they do not need solid-liquid separation after adsorption