No description available.

The term diesel particulate matter (DPM) is used to refer to the solid phase of diesel exhaust, which is mainly composed of elemental carbon and organic carbon. DPM is generally in the nano-size range (i.e., 10-1,000 nm). Occupational exposure is a health concern, with effects ranging from minor eye and respiratory system irritation to major cardiovascular and pulmonary diseases. Significant progress has been made in reducing DPM emissions by improving fuels, engines and after-treatment technologies. However, the mining industry, in particular, remains challenged to curb exposures in some operations where relatively many diesel engines are working in confined environments with relatively low airflow. Basic theory and a limited amount of prior research reported in the literature suggest that water sprays may be able to scavenge airborne DPM. The goals of the work presented in this thesis were to build an appropriate laboratory set up and to test the efficacy of micron-scale water (or fog) droplets to remove DPM from an air stream. The general experimental approach was to direct diesel exhaust through a chamber where fog drops are generated, and to measure DPM up- and down-stream of the treatment. Initially, fundamental experiments were conducted to explore the effect of the fog drops on the removal of (electrically neutralized) DPM from a dry exhaust stream. Compared to no treatment (i.e., control) and with the use of a diffusion dryer downstream of the fog treatment, the fog improved DPM removal by about 57% by mass and 45% by number density (versus no treatment). Without the use of the diffusion dryer, improvement in DPM removal was about 19% by mass. Analysis of the results suggests that a likely mechanism for the DPM removal in this experimental system is thermal coagulation between DPM and fog droplets, followed by gravitational settling and/or impaction of the droplets with system components. Further tests using raw exhaust (i.e., neither dried nor neutralized) having a higher DPM number density; shorter residence times; additional fogging devices; and no diffusion dryer downstream of the fog treatment were also carried out. These yielded an average overall improvement in DPM mass removal of about 45% attributed to the fog treatment (versus no treatment). The significant increase in DPM removal in these tests compared to the initial test (i.e., 19% removal by mass) cannot be fully explained by differences in residence time or DPM and fog droplet densities. Increased humidity in the system (due to the undried exhaust) may have allowed for a larger mean droplet size, and therefore might explain more rapid settling of DPM-laden droplets. Another possible contributing factor is ambient surface charge of the DPM, which might perhaps result in more efficient attachment between DPM and fog drops and/or increased deposition loses in the system. / Master of Science

The interaction of a liquid drop with a solid surface is being actively studied to understand practically encountered scenarios such as the impact of fuel spray droplets onto the walls of engine combustion chamber, the formation of thermal barrier coating on the surfaces of turbine blades, the process of ink-jet printing, etc. The surface topography of solid surface is one of the major parameters influencing the dynamics of drop-surface interaction process. Understanding the precise role of surface topography features such as micro asperities and grooves on the spreading and receding processes of impacting liquid drops is crucial for the improvement in abovementioned applications. Recent developments in the fabrication of micro- and nano-structures on solid surfaces provide fabulous opportunities to investigate the role of single/multiple micro asperities and grooves on the dynamics of impacting drops. The thesis deals with an experimental work on the impact of water drops on stainless steel surfaces comprising unidirectional parallel grooves. A group of six target grooved surfaces covering a wide range of surface wettability were considered. The target surfaces were prepared using the techniques of photolithography, electro discharge machining, and laser machining. Scanning electron microscope and optical surface profilometer were used to characterize the groove texture geometrical parameters of the target grooved surfaces. The experiments of drop impact were carried out in an experimental apparatus consisting of a liquid drop generator, a substrate table, and a digital video imaging system. Free-falling distilled water drops released from a certain height were allowed to impact normally on the target surfaces. The image sequences of drop impact dynamics were constructed from the images captured using the digital video imaging system. Majority of the drop impact experiments were captured using a high speed video camera operating with frame speed ranging from 3000 to 10000 fps. For the target grooved surfaces, the impact dynamics was analyzed for the impacting drop liquid oriented both in the direction perpendicular to the grooves ( ) and in the direction parallel to the grooves (||) via independent test runs. The captured digital frames were used to deduce the temporal variation of impacting drop parameters such as drop contact diameter, drop contact angle, and drop height at the center of impacting drop with the aid of image processing software. The impacting drops were characterized in terms of Weber number, We expressed in terms of drop impact velocity and drop diameter measured just before the start of impact process. The study covered We ranging from 1.8 to 170. In general, the groove texture on the solid surface influences the drop impact process for all We examined in the study. The effect is more pronounced for the receding of impacting drops. For high We drops, the groove texture enhances the perturbations seen at the periphery of spreading lamella. The study showed quantitatively that the drop impact process on a target grooved surface comprising unidirectional parallel grooves develops a non-axisymmetric drop flow on the grooved surface exhibiting different spreading and receding processes of impacting drop liquid in the directions perpendicular ( ) and parallel (||) to the grooves. The maximum spreading diameter reached immediately after the completion of early inertia-dominated spreading in is less than that obtained in || due to the loss of drop kinetic energy caused by the pinned motion of drop liquid in . The non- axisymmetric drop flow on the target grooved surface develops a difference between the frequencies of contact angle oscillation of impacting drop liquid in  and ||. The frequency difference in contact angle oscillation causes the beating phenomenon in the temporal variation of the contact angle anisotropy, Δθ and drop height at the center of impacting drop, Z. For a given target grooved surface, the experimental measurements suggested that the beat frequency is almost independent of We. The temporal variation of Δθ and Z do not show the traces of beating phenomenon for the impact of high We drops. Owing to the non-axisymmetric drop flow, the final equilibrium drop shape is eccentric for the impact of low We drops and approaches a circular shape for the impact of high We drops. The role of groove texture geometrical parameters is seen in the drop impact process via the surface wettability especially for the impact of low We drops. Larger surface roughness factor makes the target grooved surface to exhibit hydrophobic characteristics.

Dynamic behavior of impacting water drops on superhydrophobic solid surfaces provides important details on the stability/durability of such solid surfaces. Multi-scale surface roughness combined with a layer of low energy chemical is an essential surface modification process followed to create superhydrophobic capabilities on solid surfaces. The present work aims at studying the effect of low energy surface coating on droplet impact dynamics by carrying out experiments of water drop impacts on rough solid surfaces with and without chemical modification. A group of six aluminium alloy (Al6061) surfaces (three pairs) are prepared. Roughness, characterized in terms mean surface roughness, Ra, is introduced to these metallic surfaces using sand-paper polishing, electric discharge machining (EDM), and chemical based surface etching process. Low energy surface layer is laid on the rough surfaces by coating NeverWet hydrophobic solution, octadecyl-trichloro-silane (OTS), and perfluorodecyltricholorosilane (FAS-17). The impact dynamics of water drops is analyzed by capturing high speed videos for a range of drop Weber number from 1 to 570 and the salient features of drop impact process on the coated rough surfaces are compared with the corresponding uncoated rough surfaces. A one-to-one comparison on the spreading, fingering, receding, and final equilibrium of impacting drops on the coated and uncoated target surfaces is presented. Upon coating NeverWet, the original surface features of the base aluminium surface are completely covered by the hydrophobic coating material resulting in a fresh top surface layer. The outcomes as well as the bounce-off characteristics of impacting water drops on the coated surface are comparable to those observed on lotus leaf. The surface morphology features of rough aluminium surfaces coated with OTS and FAS-17 are comparable to those of the corresponding uncoated surfaces. The quantitative measurements on primary spreading and maximum spread factor of impacting drops are largely unaffected by the presence of low energy chemical coating. The dominant effect of surface coating is seen on the receding of impacting drops and hence the final drop configuration. This behavior is more prominently seen on EDM fabricated rough surface (larger Ra) combined with OTS coating than that on etching based rough surface (smaller Ra) combined with FAS-17 coating highlighting the dependence of coating effect with roughness features.