A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy. Johannesburg, 2016. / Gold mining of the Witwatersrand Basin reefs has been responsible for the rise of Johannesburg as an economic centre of South Africa. While mining provided a base for business and infrastructure development for the region, it has also generated social and environmental problems for the country. Tailings storage facilities (TSFs), a common sighting around Johannesburg and across the entire basin, have been built to contain the processed waste following extraction of gold from the pyrite containing quartzite ore. When the fine grained waste is exposed to atmospheric conditions, oxidation of remnant sulphides occurs resulting in acidic, metal rich and sulphate rich plumes that enter the environment through surface and groundwater systems. This thesis sought to better understand the release, transport, dispersal and fate of metals emanating from TSFs and their remnant footprints on the Witwatersrand. These metals included aluminium, copper, chromium, iron, manganese, nickel and uranium and are known to be toxic to humans depending on their concentration and speciation. Traditionally, analytical methods have been employed in studies focussing on the characterisation of some of these processes in the region. While these studies have generally conducted quantitative assessment of the extent of pollution, little comprehensive interrogation and fingerprinting of the processes that are influential in determining the potential risk posed by metals has been done. This has largely been due to the shortcomings of analytical methods to determine these. To this end, this research has employed geochemical modelling to complement the traditional analytical methods. The approach to study the release of metals from TSFs involved assessment of the partitioning of metals within tailings and their potential release using batch and sequential extraction methods. Processes of metal release within the tailings were simulated through geochemical modelling (using the PHREEQC and Geochemist’s Workbench codes). The simulations were based on the percolation of rainwater through these layers and the changes in its chemistry along the path. The potential seepage of this plume along the path was then correlated to observed efflorescent mineral crusts that are temporary sinks for metals and are a common feature in the vicinity of the tailings and water bodies such as ponds and streams. The potential impact of the mineral crusts on the water chemistry of receiving water systems following their dissolution was assessed using forward geochemical modelling. The transport of the metals in groundwater was also studied. This involved simulations of the transition in chemistry of a plume from a TSF along an aquifer of known composition. This was based on a 1-D reactive transport model constructed using information from sequential extraction work on the aquifer rock (to identify the key minerals to consider) and site data (mainly flow rates) from previous studies. The processes occurring in the removal of metals from acid mine drainage (AMD) through a permanent sink in the form of a pump-and-treat plant in the Central Goldfield of the basin were simulated using PHREEQC. The findings from the research showed that two different plumes were produced from an abandoned TSF as a result of rainwater percolation, notably a plume produced from the dissolution of secondary salts formed in the oxidised layer and a sulphuric acid rich plume in the unoxidised layer. These differences were apparent in the geochemical composition of the mineral crusts collected on the walls of tailings dumps and from a pond into which the plumes were draining. On dissolution, mineral crusts were found to produce acidic solutions with crusts containing predominantly Fe producing pH values below 3. The simulated dissolution of various types of mineral crusts gave insight into the impact of minerals present in the smallest amount. This showed that the bulk mineralogy as determined by analytical techniques such as PXRD and remote sensing could not be used with confidence to deduce the impact of the mineral crusts on receiving water bodies. The characteristics of surface plumes released from tailings TSF were compared to other water systems in the area around Soweto, with complementary interpretation conducted using chemometric methods. From principal component analysis (PCA), surface water systems were found to form distinct groups largely influenced by mineral solubility, alkalinity and dissolved oxygen content. The 1-D reactive transport simulations involved acidic, metal and sulphate rich water ingressing the aquifer (below the TSF). Several scenarios were modelled including simulations with different dolomite contents; allowing for surface complexation and the presence of cation exchange surfaces. At a point 500 m from the water ingress in the dolomite rich aquifer, Fe and Mn were largely precipitated out (as confirmed by sequential extraction results on the aquifer rock) while the sulphate concentration was reduced by almost half. On the other hand, Ca concentrations were conservative largely because of continuous dissolution of dolomite and precipitation of gypsum along the flow path. The simulations of the high density sludge treatment plant involved forward modelling of the treatment process with the sludge responsible for the removal of trace metals from the incoming acid mine drainage. The model can be of use for cost and process optimisation at the facility. This research has had notable outputs in the form of publications; models on metal release, transport and attenuation; and models on pump-and-treat processes. These will form an important repository of information and for benchmarking any further studies related to AMD. / MT2016

Previous studies have identified water meter inaccuracy at low flow rates as a significant source of non-revenue flow for water systems; however a lack of available data makes it difficult to include low flow accuracy degradation in meter replacement plans. This thesis examines results from an extensive accuracy test program carried out at the Utah Water Research Laboratory on small water meters over a wide range of flow rates and at various levels of throughput. The study compares expected apparent losses of different types of water meters based on a flow profile and expected daily use for the State of California. By including an average composite charging rate, use of the method developed in this study can determine the meter replacement payback period for different meter types. The analysis contained in this document is intended as a guide to assist utility managers when developing meter replacement plans.

Northern Utah Valley is one of the fastest growing areas of Utah and has increasing needs for domestic, industrial, and agricultural water. To meet these needs, groundwater and surface water systems must be understood to maximize their use. Chemical studies of the sediment mineralogy and related water-chemistry give insight to the movement of the water. There are three major aquifers present in the valley: shallow Pleistocene; deep Pleistocene; and Tertiary. They are composed of sands and gravels and are separated by confining layers (aquitards) composed mostly of clay. Along the flanks of the bordering mountains there are undifferentiated aquifers which act as conduits supplying water for aquifers in the valley. Sediment samples from aquifers and confining layers were obtained by rotary and cable-tool drilling. X-ray diffraction analyses showed that the aquifers are mainly composed of quartz, calcite, and dolomite, whereas the con fining layers contain illite and montmorillonite with some kaolinite, quart z and calcite. One hundred nine water samples were collected in this study from s ur face water, spring water, undifferentiated aquifer water, shallow Pleistocene aquifer water, deep Pleistocene aquifer water and Tertiary aquifer water. Results show that the ground water system has several geochemical cells in each aquifer, due to diverse areas of recharge. Three major water types can be identified in different areas of the shallow Pleistocene aquifer, three in different areas of the Tertiary aquifer, and four in different areas of the deep Pleistocene aquifer. The differences in these water types are related to the composition of the mountain recharge areas and positions of faults within the valleys. The aquifer composition exerts relatively little influence on the chemistry of the ground water. Mountains of predominantly carbonate rocks produce recharge waters rich in calcium and bicarbonate. Mountains of predominantly granitic rocks produce recharge water low in mineral content. Valley sediments near major faults produce highly mineralized waters.

Inland salt lakes of the arid and semi-arid zones of Western Australia are unique systems. An unpredictable rainfall pattern and a transient water regime ensure these lakes remain dry for much of the year. Lake Yindarlgooda in the Eastern Goldfields of Western Australia is a typical inland salt lake that has been subjected to additional stresses. This thesis is the outcome of investigations conducted on the lake from 2001 to 2003. Emphasis is on the limnology and biota of the lake, including an adjacent wetland, and impacts on the aquatic ecosystems caused predominantly by mining. Lake Yindarlgooda is a large, shallow hypersaline lake situated on the Yindarlgooda Palaeoriver. It is sodium chloride dominated and has naturally high background levels of nickel. Sites impacted by the leaching of hypersaline decant water from a leach residue storage facility (LRSF) were differentiated from control sites using multivariate statistics. Salinity was found to be a major determinant in the structure of the biological communities in the lake systems. / Different biotic communities with low taxonomic diversity were recorded in Lake Yindarlgooda and Swan Refuge, a nearby hyposaline clay pan. The benthic microbial communities were dominated by halotolerant diatoms, notably Amphora coffeaeformis, Navicula incertata and Hantzschia baltica. Variation in the diatom assemblages between the playa sites and the clay pan were noted, influenced by habitat type and salinity. Within Lake Yindarlgooda, the diatom assemblages in the control and impact sites were found to be similar. A narrow salinity spectrum dictated the taxa present. Many of the benthic diatoms collected during the dry phase were encysted, having entered dormancy. The invertebrate fauna in Lake Yindarlgooda and Swan Refuge belonged to the Crustacea. A larger percentage of hyposaline invertebrate taxa were recorded from Swan Refuge, while those in Lake Yindarlgooda were typically halotolerant species. The Ostracoda showed the greatest diversity and their abundance was higher in the southern control sites while the Anostracan, Parartemia sp., dominated the northern impact sites of the playa. / The riparian zone of Lake Yindarlgooda supported a diverse plant community, dominated by the Chenopodiaceae. The marginal vegetation communities along the shores of Lake Yindarlgooda were found to be similar, indicating habitat homeogeneity. Within the riparian zone both biological and physical soil crusts occupied large areas not inhabited by vascular plants. The biological soil crust identified was composed of an association between the filamentous cyanobacterium Microcoleus sp. and a moss species (Musci). Both biological and physical soil crusts were found to have functional roles in stabilising the surrounding low dunes. The soil crusts in the northern control sites were badly degraded as a result of trampling by livestock, while those in the southern control sites were protected and were intact. Only one Parartemia species was found to inhabit Lake Yindarlgooda, Parartemia n. sp. d. It was collected in salinities ranging from 50 to 140 g L-1. The population appeared to be oviparous, recruitment mostly from resting eggs. The male to female ratios varied between sites, as did the number of juveniles compared to the adults. The northern impact sites had a more mature Parartemia population than the southern control sites and appeared to have undergone a second recruitment. Examination of the surface sediment found a well established Parartemia “egg bank” in the northern impact sites with egg numbers much higher than in the southern control sites. / The ultrastructure of the Parartemia resting egg was identical to that of Artemia. Differences in the external features and internal structure of the resting egg of Parartemia n sp. d and Parartemia n. sp g from Lake Miranda, another saline lake, were identified. This study showed morphological variation of the egg within Parartemia, a finding not previously recorded. Rehydration trials on the Parartemia egg bank indicated that the increase in sediment salinity from the LRSF had a negative effect on the hatching of the resting eggs. In salinities above 60 mS cm-1 hatching was less successful. The conditions provided in the trials were similar to those in Lake Yindarlgooda. The hatching technique was repeated on sediment from Lake Miranda with similar results. These trials were considered a valuable monitoring tool in the assessment of impacts on the biota of temporary lakes in the absence of water. This study demonstrated that in the absence of water the egg and spore/seed bank can be used as a proxy for monitoring temporary lakes. It was also found to be valuable in understanding the distribution and diversity of the biotic communities in Lake Yindarlgooda. This study provides the first integrated reference information on a Western Australian inland salt lake against which any future impact may be assessed.

Diss. Linköping : Univ., 2004. / Härtill 6 uppsatser.

Cooling water systems are used to remove excess heat from a chemical process to the atmosphere. The primary components of these systems are the cooling tower and the heat exchanger network. There is a strong interaction between these individual components, thus their performances are interrelated. Most published research in this area has focused mainly on optimization of the individual components i.e. optimization of heat exchanger network or optimization of the cooling towers. This approach does not optimize the cooling water system as a whole. Previous research work in which a holistic approach was used is limited to cooling water systems with single cooling water source. This work presents a technique for integrated optimization of complex cooling water systems. The system under consideration consists of multiple cooling towers each supplying a set of heat exchangers. A superstructural approach is employed to explore all possible combinations between the heat exchangers and the cooling towers. The cooling water reuse opportunities within the heat exchanger networks are also explored. A detailed mathematical model consisting of the cooling towers and the heat exchanger networks model is developed. Two practical scenarios are considered and the mathematical formulations for Case I and II yield nonlinear programing (NLP) and mixed integer nonlinear programming (MINLP) structure respectively. Although the reuse/recycle philosophy offers a good debottlenecking opportunity, the topology of the associated cooling water network is more complex, hence prone to higher pressure drop than the conventional parallel design. This is due to an increased network pressure drop associated with additional reuse/recycle streams. Therefore, it is essential to consider pressure drop during the synthesis of cooling water networks where the reuse/recycle philosophy is employed. The on-going research in this area is only limited to cooling water networks consisting of a single cooling water source. The common technique used is mathematical optimization using either superstructural or non superstructural approach. This work further presents a mathematical technique for pressure drop optimization in cooling water systems consisting of multiple cooling towers. The proposed technique is based on the Critical Path Algorithm and the superstructural approach. The Critical Path Algorithm is used to select the cooling water network with minimum pressure drop whilst the superstructural approach allows for cooling water reuse. The technique which was previously used in a cooling water network with single source is modified and applied in a cooling water network with multiple sources. The mathematical formulation is developed considering two cases. Both cases yield mixed integer nonlinear programming (MINLP) models. The cooling tower model is also used to predict the exit condition of the cooling tower given the inlet conditions from the cooling water network model. The results show up to 29% decrease in total circulating cooling water flowrate when the cooling water system is debottlenecked without considering pressure drop. Consequently, the overall cooling towers effectiveness was improved by up to 5%. When considering pressure drop the results showed up to 26% decrease in total circulating water flowrate. / Thesis (PhD)--University of Pretoria, 2013. / gm2013 / Chemical Engineering / unrestricted

This research investigated using a life cycle environmental and economic approach to evaluate IX technology for small potable water systems, allowing for the identification and development of process and design improvements that reduce environmental impacts and costs. The main goals were to evaluate conventional IX in terms of life cycle environmental and economic sustainability, develop a method for improving designs of IX systems from a environmental and economic sustainability standpoint, evaluate potential design improvements, and make the research findings accessible to water professionals through user-friendly tools and frameworks that take into account their feedback. This research provides an understanding, from the perspective of life cycle environmental impacts and costs, of the tradeoffs between various reactor designs of IX, the effects of scale, key contributors to impact and cost, design trends that improve sustainability, and how combined cation anion exchange compares to conventional IX. Furthermore, tools were developed that can be used to identify design choices that improve sustainability of IX systems. These tools were made into a user-friendly format to better bridge the gap between research and practice.

Water is a scarce and unevenly distributed national resource and it is, therefore, important to reduce water consumption in paper mills. Closure of water systems for reuse, however, directly and indirectly results in an increase in the numbers and types of microorganisms resulting in poor runnability, lower production rates and increased safety hazards. The aim of this study was to investigate the microbiology of paper-mill water systems in South Africa to aid in closure of water systems whilst controlling microbial fouling. Different environmental parameters monitored at paper mills were reviewed together with microbial enumeration techniques employed by industry and characterisation and identification methods to study bacteria. Various environmental and process parameters could play an important role in the number and type of microorganisms in a paper-mill water system. The highest correlation between an environmental parameter and biological activity was found for oxidation-reduction potential and the numbers of culturable aerobic bacteria. Other environmental parameters that significantly influenced microbial numbers were temperature, dissolved oxygen, dissolved solids, chemical oxygen demand, nitrogen, phosphorous, specific water consumption, pulp furnish, biocide class and retention time. The characterisation and identification of problematic bacteria in paper mills could enable better control since the correct biocides could be applied to minimise microbiologically associated problems. Prevalent bacteria that were isolated from the water systems of 14 paper machines were typed into 35 distinct groups using ERIC-PCR and PCR-RFLP and identified with sequence analysis. Eleven of the 35 types were identified to species level, 20 types were identified to genus level and the remaining four types were identified to family level. It was found that the majority of bacteria belonged to the genera Acinetobacter and Pseudomonas that contain well-known slime-forming bacterial species. Traditional methods employed to investigate bacteria in industrial water systems often do not accurately represent the composition and diversity of bacterial communities. DGGE analysis could provide a powerful tool for monitoring bacterial diversity, since it is able to discriminate between identical sizes of PCR-amplified DNA fragments that differ in their sequence content. The use of DGGE to monitor changes in microbial populations could improve control of microbial fouling, but more analyses would be needed to validate the results of the present study. / Dissertation (MSc (Microbiology))--University of Pretoria, 2008. / Microbiology and Plant Pathology / unrestricted

abstract: De facto potable reuse (DFR) occurs when surface water sources at drinking water treatment plants (DWTPs) contain treated effluents from upstream wastewater treatment plants (WWTPs). Contaminants of emerging concerns (CECs) originate from treated effluents (e.g., unregulated disinfection by-products, pathogenic microorganisms as Cryptosporidium oocyst, Giardia cyst, and Norovirus) can be present in surface water and pose human health risks linked to CECs. Previously developed De facto Reuse Incidence in our Nations Consumable Supply (DRINCS) model predicted DFR for the national largest DWTPs that serve >10,000 people (N = 2,056 SW intakes at 1,210 DWTPs). The dissertation aims to quantify DFR at all surface water intakes for smaller DWTPs serving ≤10,000 people across the United States and develop a programmed ArcGIS tool for proximity analysis between upstream WWTPs and DWTPs. The tested hypothesis is whether DWTPs serving ≤10,000 people are more likely to be impacted by DFR than larger systems serving > 10,000 people.The original DRINCS model was expanded to include all smaller DWTPs (N = 6,045 SW intakes at 3,984 DWTPs) in the U.S. First, results for Texas predicted that two-thirds of all SW intakes were impacted by at least one WWTP upstream. The level of DFR at SW intakes in Texas ranged between 1% to 20% under average flow and exceeded 90% during mild droughts. Smaller DWTPs in Texas had a higher frequency of DFR than larger systems while < 10% of these DWTPs employed advanced technology (AT) capable of removing CECs. Second, nationally over 40% of surface water intakes at all DWTPs were impacted by DFR under average flow (2,917 of 6,826). Smaller DWTPs had a higher frequency (1,504 and 1,413, respectively) of being impacted by upstream WWTP discharges than larger DWTPs. Third, the difference in DFR levels at smaller versus larger DWTPs was statistically unclear (t-test, p = 0.274). Smaller communities could have high risks to CECs as they rely on surface water from lower-order streams impacted by DFR. Furthermore, smaller DWTPs lack more than twice as advanced unit processes as larger DWTPs with 52.1% and 23%, respectively. DFR levels for DWTPs serving > 10,000 people were statistically higher on mid-size order streams (3, 5, and 8) than those for smaller DWTPs. Finally, DWTPs serving > 10,000 people could pose risks to a population impacted by DFR > 1% as 40 times as those served by smaller DWTPs with 71 million and 1.7 million people, respectively. The total exposed population to risks of CECs served by DWTPs impacted by upstream WWTP discharges (DFR >10%) was estimated at 12.3 million people in the United States. Future studies can use DRINCS results to conduct an epidemiological risk assessment for impacted communities and identify communities that would benefit from advanced technology to remove CECs. / Dissertation/Thesis / Doctoral Dissertation Civil, Environmental and Sustainable Engineering 2020

Yes / There is a need for an inexpensive, reliable and fast monitoring tool to detect contaminants in a short time, for quick mitigation of pollution sources and site remediation, and for characterization of natural dissolved organic matter (DOM). Fluorescence spectroscopy has proven to be an excellent technique in quantifying aquatic DOM, from autochthonous, allochthonous or anthropogenic sources. This paper reviews the advances in in situ fluorescence measurements of DOM and pollutants in various water environments. Studies have demonstrated, using high temporal-frequency DOM fluorescence data, that marine autochthonous production of DOM is highly complex and that the allochthonous input of DOM from freshwater to marine water can be predicted. Furthermore, river measurement studies found a delayed fluorescence response of DOM following precipitation compared to turbidity and discharge, with various lags, depending on season, site and input of dissolved organic carbon (DOC) concentration. In addition, research has shown that blue light fluorescence (λemission = 430–500 nm) can be a good proxy for DOC, in environments with terrestrial inputs, and ultraviolet fluorescence (λemission = UVA–320–400 nm) for biochemical oxygen demand, and also E. coli in environments with sanitation issues. The correction of raw fluorescence data improves the relationship between fluorescence intensity and these parameters. This review also presents the specific steps and parameters that must be considered before and during in situ fluorescence measurement session for a harmonized qualitative and quantitative protocol. Finally, the strengths and weaknesses of the research on in situ fluorescence are identified. / Authors, E.M. Carstea and C.L. Popa, acknowledge the support of the Ministry of Research and Innovation, CNCS-UEFISCDI, project number PN-III-P1-1.1-TE-2016-0646, within PNCDI III, project number 18N/2019, under the Core Program OPTRONICA VI, project number 19PFE/17.10.2018 and project number 152/2016, SMIS 108109.