<p dir="ltr">Vapor Compression Systems (VCS) are the most common air conditioning technology. However, the VCS process is energy inefficient due to overcooling and reheating. Liquid Desiccant air conditioning (LDAC) is a potentially more energy-efficient air conditioning technology. LDAC removes vapor in the air using the liquid desiccant’s high-water affinity and controls temperature using an additional cooling device. Additionally, LDAC typically requires heating to regenerate the diluted Liquid Desiccant (LD) for repeated use after absorbing moisture.</p><p dir="ltr">Earlier types of the LDAC systems operated at a relative high concentration and temperature during the dehumidification process, resulting in an increased heat source temperatures required for regeneration, which substantially diminished the energy efficiency advantages of LDAC systems. In the past two decades, researchers have explored a new LDAC system configuration that integrates an LDAC system with a heat pump (HP). The HP can deliver sensible cooling to lower the LD operating temperature and cool the process air. Simultaneously, it provides heating at the condenser side to facilitate the regeneration process. Subsequently, membrane-based dehumidifiers were introduced to separate the LD and airflow using a membrane that permits the passage of water vapor. This approach prevents direct contact, which otherwise would result in LD droplet carryover, addressing concerns related to health and the corrosion of air ducts. An internally cooled membrane-based dehumidifier with enhanced performance garners significant attention, as it essentially functions as a three-stream heat exchanger that facilitates both heat and mass transfer processes. Because of the intricate characteristics of the three-stream heat and mass exchanger, the finite difference models used to analyze the internally cooled membrane dehumidifier is highly detailed and comprehensive. These models are well-suited for assisting in the device’s design but are not suitable for system-level simulations. The lack of simple models for internally cooled membrane-based dehumidifiers limits the evaluation of energy performance at the system level. The limitation becomes particularly pronounced when a HP is integrated, as the model hinders our comprehension of the interactions between the HP and LDAC under the transient operating conditions.</p><p dir="ltr">The thesis research aims to bridge the gaps related to system configuration design, limitations of existing dehumidifier models, and the analysis and assessment of transient system level performance. A model of the internally cooled membrane-based dehumidifier, based on artificial neural networks, was created using data generated through the utilization of a published and detailed finite element dehumidifier model. The resulting model was validated by testing it with out-of-sample data and comparing its results with the validated finite difference model. An LDAC system setup using the internally cooled dehumidifier was established in Modelica using the artificial neural network model created. Furthermore, models of a VCS and an LDAC based on adiabatic dehumidifier were also developed to facilitate performance comparison. The different systems underwent simulation for an entire cooling season spanning from May to September. The internally cooled dehumidifier-based system exhibited superior energy performance, achieving seasonal energy performance levels up to 104% and 34% higher than the VCS and adiabatic dehumidifier systems, respectively. The improved performance in comparison to the VCS is due to the higher temperature operation of the HP. The improvement in comparison to the adiabatic dehumidifier system is due to the improved capacity of the internally cooled dehumidifier to deal with the absorption heat released during dehumidification. Depending on the geographical location, the internally cooled dehumidifier system displayed enhanced performance in the applications characterized by moderate sensible cooling, while its efficiency was relatively lower in arid and hot regions. Additionally, the results demonstrated that the adiabatic system performed similarly to the internally cooled dehumidifier system in locations with high sensible and latent cooling loads.</p><p dir="ltr">This work introduces a pioneering data-driven model for internally cooled membrane liquid desiccant dehumidifiers, representing a significant advancement in the field. The model's computational efficiency and accuracy address the challenges posed by sophisticated and computationally expensive physical models, providing a valuable tool for simulating such devices. The creation of the simple ANN-based dehumidifier model opens the possibility for simulation of internally cooled devices as part of dehumidification systems, whereas as of today its study has been mostly limited to single devices simulations. In the study, a model-based comparison of system performance between an HP-coupled internally cooled dehumidifier-liquid desiccant air conditioning system and HP-coupled adiabatic LDAC, as well as Vapor Compression Systems, elucidates the optimal operational configuration and rationale. Furthermore, a climate sensitivity analysis of system simulations guides researchers toward focusing on the development of HP-coupled internally cooled/heated liquid desiccant systems, particularly in climates that offer the greatest potential for energy savings compared to commonly used vapor compression systems. This comprehensive exploration enhances our understanding and paves the way for more efficient and effective developments in liquid desiccant-based dehumidification technologies.</p>

Heat pumps are a vital part of each building for their role in keeping the space conditioned for the occupant. This study focuses on developing a model for the ground-source heat pump at the Zero Energy lab at the University of North Texas, and finding the minimum data required for generating the model. The literature includes many models with different approaches to determine the performance of the heat pump. Each method has its pros and cons. In this research the equation-fit method was used to generate a model based on the data collected from the field. Two experiments were conducted for the cooling mode: the first one at the beginning of the season and the second one at the peak of the season to cover all the operation conditions. The same procedure was followed for the heating mode. The models generated based on the collected data were validated against the experiment data. The error of the models was within ±10%. The study showed that the error could be reduced by 20% to 42% when using the field data to generate the model instead of the manufacturer’s catalog data. Also it was found that the minimum period to generate the cooling mode model was two days and two hours from each experiment, while for the heating mode it was four days and two hours from each experiment.

La tesis que a continuación se presenta surge como una respuesta práctica al problema medioambiental relacionado con el empleo de sustancias sintéticas como fluidos de trabajo en muchos de los equipos de climatización comercializados en la actualidad. Con su desarrollo se busca dar alternativas a la creciente demanda de sistemas de climatización eficientes que contribuyan a la optimización de los recursos energéticos. Uno de los objetivos planteados en el desarrollo de la tesis ha sido el diseñar y evaluar experimentalmente el comportamiento de diferentes prototipos experimentales de bombas de calor, particularmente de tipo agua-agua con el uso del propano como refrigerante. La caracterización de los prototipos se llevó a cabo realizando diferentes estudios de carga con la finalidad de determinar la mínima cantidad de propano en cada sistema para obtener las máximas prestaciones en cuanto a COP y capacidad. Los estudios han mostrado que los elementos principales, como el compresor o los intercambiadores de calor presentan mayores rendimientos con el uso del propano en comparación a algunos refrigerantes sintéticos como el R407C. Esto se debe en gran medida a las excelentes propiedades termodinámicas y de transporte del propano, así como a la evolución que este refrigerante tiene a través de los componentes del sistema. En cuanto a la carga óptima de propano, se han obtenido cargas de refrigerante próximas a los 500 gramos, que han permitido obtener coeficientes de operación elevados bajo condiciones de trabajo típicas de calefacción y refrigeración, así como capacidades específicas de refrigeración entre 25 y 33 Wattios por gramo de propano. / Martínez Galván, IO. (2008). Estudio experimental de optimización de una bomba de calor agua-agua empleando propano como fluido de trabajo [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/3344 / Palancia