Hypoxia occurs when the dissolved oxygen concentrations in water fall below 2 mg/L, and negative impacts to flora and fauna can result. In this study, sediment core and water column measurements were collected and processed through several laboratory and field methods to better understand the biogeochemistry of Weeks Bay (WB), AL. Results show that salinity, temperature, and dissolved oxygen fluctuate on a diurnal cycle. Results also show a significant difference in water column and sediments between different years and sites. The western side of WB was found to more likely to go hypoxic than other portions. Conclusions of this research include that major differences in the water column are shown during a diurnal cycle, but sediments appear to be less dynamic. The implications of this work include WB hypoxia tendency is heterogeneous over space and time. However the sediments, although important, indicate that the pelagic and benthic components are decoupled.

Methylmercury (MeHg) production is magnified in the natural environment by geochemical influxes and an active sulfate reducing bacteria community. It has been found that the presence of sulfides, excess nutrients, and the type of depositional environment (normal marine or euxinic) greatly influences MeHg production and degree of pyritization (DOP). The aim of this research is to investigate a possible connection between MeHg accumulation and the DOP in Weeks Bay sediment. Collected sediment samples have confirmed a significant presence of total reduced sulfides, inorganic mercury, reactive iron, and total organic carbon. Pyritization results indicate a normal marine environment and, of the three measured elements (S, Fe, and C,) carbon and sulfur are the dominant limiting factors to the DOP in Weeks Bay. Current geochemical and pH/redox conditions favor MeHg and pyrite production. The quantified pyrite greatly exceeds that of MeHg indicating DOP inhibits MeHg precipitation.

Sediment is a major impairment in many streams and rivers in the drainage basins along the northern Gulf of Mexico. The use of geospatial technologies improves assessment and decision making for the management of environmental resources and conditions for coastal watersheds. This research focuses on the development of a conceptual qualitative model enhanced with expert input for the assessment of soil erosion potential in coastal watersheds. The conceptual model is built upon five layers (slope, precipitation, soil brightness or exposure, Kactor, and stream density) like those in a standard numerical soil loss model such as the Revised Universal Soil Loss Equation (RUSLE). The conceptual model produced a continuous surface to index erosion potential. Pearson’s correlation coefficient was used to identify variable sensitivity. The model was most sensitive to Kactor variable, followed by soil brightness, stream density, and slope. The model was not sensitive to the precipitation variable due to the lack of variability across the watershed. Expert input was added to the conceptual model for erosion potential with the Analytical Hierarchy Process (AHP). The AHP is used to value the importance of criteria, providing a quantitative weight for the qualitative data. The expert input increased the overall importance of topographic features and this increased cell counts in the upper erosion potential classes. The AHP weights were altered in 1% increments ranging from plus to minus 20% producing 201 unique runs. A quartile analysis of the runs was used to define areas of model agreement. The quartile analysis allowed for the application of an analysis mask to identify areas of increased erosion potential for improved management related decisions. The conceptual and AHP erosion potential output data, including watershed management priority rankings, were published as web mapping services for story map development as a transition to a decision support system. The limits of the story map to allow user interactions with model output rendered an unacceptable platform for decision support. The story map does offer an alternative to static reports and could serve to improve dissemination of spatial data as well as technical reports and plans like a watershed management plan.

This study compares suspended sediment and land use/land cover in the watershed of Weeks Bay, Alabama. Using Landsat thematic mapper imagery, potential high and low erosion sites were determined based on the increase in urban development form 2002 to 2005. In situ sediment sampling was used to test the hypothesis that the high erosion potential sites have larger amounts of suspended sediments. Additionally, sampling was performed along the Fish and Magnolia rivers to establish a background total suspended sediment level. The background study established an average total suspended sediment concentration of 18.71 mg/L for the Fish River and 17.47 mg/L for the Magnolia River, which are higher than previous studies. The results of the comparison between suspended sediments and land use/land cover proved to be more complex than expected due to variation in precipitation, to the 30 m satellite resolution, and to the criteria for classifying urban land use.

Thesis (M.S.) -- Mississippi State University. Department of Geosciences. / Title from title screen. Includes bibliographical references.

Thesis (M.S.)--Mississippi State University. Department of Geosciences. / Title from title screen. Includes bibliographical references.