Thesis (M.A.)--University of Wisconsin--Madison, 1972. / eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.

The structures of two new Werner clathrates have been elucidated by X-ray diffraction. Ni(NCS) 2(c6 Hf) 2(c11ttgN) 2.methyl cello solve is monoclinic with a= 10,648(5), b = 23,005(12), a= 16,294(8).R, S = 98,04(2) 0 , Z = 4 and the space group C2/0 • The guest, methyl cello solve is disordered and lies at a centre of inversion. Ni(NCS) 2(c6 H7 N) 4.p-cymene is tetragonal with a= 17,105(9), b = 17, 105(9), a= 23,837(12).R, Z = 8 and the space group I4 1 fa• The guest, p-cymene is disordered and lies at a centre of inversion. The stoichiometry of the clathrates was investigated by various chemical methods including thermogravimetric analysis, differential thermal analysis, mass spectroscopy and proton nuclear magnetic resonance spectroscopy. Host-guest non-bonded energy relationships using atom-pair potentials are examined. Attempts have been made to estimate the association constants of sore of these computed in solution by proton nuclear magnetic resonance spectroscopy.

Diss.--Philologie I--Mainz--Johannes Gutenberg-Universität, 1994. / Bibliogr. p. 510-573.

Univ., Diss.--Tübingen, 2005. / Literaturverz. S. 344 - 371.

Diss.--Lódz--Univ. / Bibliogr. p. 219-232.

Magisterarbeit--Köln--Universität, 2000. / Filmogr. p. 120-121. Bibliogr. p. 109-119.

Texte remanié de: Dissertation--Hagen--FernUniversität, 2006. / Contient un résumé. Bibliogr. p. [369]-474.

The author's inaugural dissertation, Göttingen, 1925, with certain omissions. / "Literaturverzeichnis": p. [ix]-xii. Includes bibliographical references.

Inaug.--Diss. Westfälische Wilhelms-Universität, Münster. / Bibliography: p. [v]-vi.

Fluorous chemistry has seen a number of advances since its birth in the early 1990s. One of the most attractive characteristics of fluorous solvents is their unique solubility properties depending on temperature. This phenomenon has led to the development of a wide range of catalysts that are modified with fluorous tags and are used in biphasic catalysis and easily recovered. Many fluorous phase transfer catalysts are confined to bringing small ions into fluorous media by using fluorous onium or crown ether vehicles. The most popular method to bring transition metal complexes into fluorous media is quite limited, usually resulting in ligand tuning and thus a change in reactivity at the metal center. This can be circumvented by pairing a cationic transition metal with a highly fluorous anion rendering the neutral species highly fluorophilic. To achieve this goal, we chose to use fluorous BArf₆, [B(3,5-C₆H₃(Rf₆)₂)₄]⁻, as the mode of transport and pair it with classic Werner-type complexes that recently have been shown act as organocatalysts in enantioselective Michael additions. The literature synthesis of Na[B(3,5-C₆H₃(Rf₆)₂)₄] (3) was improved and through salt metathesis two new fluorophilic salts were made. The Werner-type trication [Co(en)₃]³⁺ was solubilized in PFMC (perfluoromethylcyclohexane) to generate [Co(en)₃][B(3,5-C₆H₃(Rf₆)₂)₄]₃ (4). This fluorophilic salt was found to be preferentially soluble in fluorous media with a partition coefficient in PFMC/H₂O of 99.0:1.0 and in PFMC/CH₃C₆H₅ of >99.3:<0.7. Another Werner-type trication, [Co(R,R-chxn)₃]³⁺, was also paired with [B(3,5-C₆H₃(Rf₆)₂)₄]⁻ to afford [Co(R,R-chxn)₃][B(3,5-C₆H₃(Rf₆)₂)₄]₃ (5), whose partition coefficients in PFMC/H₂O and PFMC/CH₃C₆H₅ were the same as 4. Within the scope of Werner-type complexes, this work constitutes a significant stride toward developing a series of compounds that bring the concept of organocatalysis into fluorous media. The new compounds 3-5 show high preferences for the fluorous phase and provide a baseline for future Werner-type salt metathesis with fluorous BArf₆.