The City of Saskatoon is challenged with large quantities of wood wastes such as demolition wastes, construction wastes, and elm tree trims. It has also been recently found that some of the elm trees in Saskatoon might have been infected with the Dutch elm disease, hence, this would lead to the cutting down of trees. The cutting of the affected elm trees will definitely increase the quantities of wood wastes in Saskatoon. The City of Saskatoon might therefore develop the initiative to develop more landfills, as all wood wastes are usually deposited into the landfills. Landfills are usually not environmental friendly, hence, no one wants a landfill in his backyard. Furthermore, the concerns about climate change is also a pressing issue around the world as individual countries most especially the industrialised countries are looking for means to reduce their carbon foot prints. The two issues discussed above have therefore developed the initiatives for renewable energy sources as an alternative to the burning of fossil fuel to produce energy. One of the common alternatives to burning of fossil fuel is the biomass fuel specifically the woody biomass fuel (wood chips). This project is therefore developed as one of the initiatives to evaluate the feasibility of wood chips as an energy source in Saskatoon.

The southern pine beetle (SPB) poses a significant threat to pine forests of the southeastern US. Pre-commercial thinning (PCT) is a commonly used silvicultural practice to mitigate and prevent SPB spread in young southern pine stands. Typically, PCT represents an added management cost to landowners and thinned material is not utilized for forest products. Increased demand for woody biomass energy may provide landowners and harvesting contractors an opportunity to utilize PCT residues as a woody biomass energy feedstock, which may wholly or partially offset PCT costs. However, little information is available regarding harvestable biomass quantities in PCT stands and few studies have assessed harvesting productivity and costs in very young pine stands. To develop estimates of biomass abundance in PCT candidate stands, loblolly pine (Pinus taeda) stands aging 5 to 12-years old, and enrolled in the Virginia Department of Forestry Pine Bark Beetle Prevention Program (VDOF PBBPP), were inventoried across the Piedmont and Coastal Plain regions of Virginia. To attain productivity and cost estimates of utilizing small-diameter stems for woody biomass energy, a biomass harvesting case study was then conducted on a 15-year old loblolly pine stand. Results of the inventory and case study indicate that stands at the upper age limit for the PCT program may contain harvestable quantities of biomass (39.63 green tons/acre), although high harvesting costs ($23.46/green ton) relative to regional delivered biomass prices may limit the economic feasibility of utilizing PCT biomass for energy. / Master of Science

In the continental United States, mean surface air temperature is expected to increase by up to 5°C within 100 years. With hotter temperatures, leaf budbreak is expected to occur earlier in forests, and leaf area is expected to increase in locations where temperature is limiting. The response of plant photosynthesis to hotter temperatures is less certain; plant productivity could increase or decrease. Past studies have found intraspecific variation in the responses of forest tree productivity, phenology, canopy leaf area, and leaf isoprene emission to warming, which all influence carbon uptake and yield for agricultural tree species; it is therefore important to understand not only how hot climates affect carbon uptake and biomass production between different tree species, but also in different genotypes of the same species. We conducted a common garden study at the Biosphere 2 research center near Oracle, AZ, USA. We created a hybrid poplar plantation of 168 trees, which were planted as cuttings in January 2013. The trees used in this study are comprised of 5 distinct genotypes of Populus deltoides × trichocarpa from a range of average annual air temperatures. We measured photosynthetic capacity, leaf phenological timing, canopy leaf area and aboveground woody biomass in 2014 growing season, and leaf isoprene emission in the 2015 growing season. We observed a strong effect of genotype on aboveground woody biomass increment, implying strong local adaptation to the home range and limited phenotypic plasticity in terms of physiological and biometric responses to high temperature environments. Our study suggests that genotypes from hotter home ranges are able to maintain photosynthetic capacity and canopy leaf area late into the growing season, despite high temperatures, and thus produce more aboveground woody biomass. This study may have implications for agricultural management—as temperatures warm where managers currently grow hybrid poplar for agricultural or other purposes, the genotypes from those home ranges would likely have reduced yield; managers could investigate the use of genotypes from home ranges with higher average temperatures to replace the vulnerable local varieties.

京都大学 / 新制・課程博士 / 博士(エネルギー科学) / 甲第24922号 / エネ博第464号 / 新制||エネ||87(附属図書館) / 京都大学大学院エネルギー科学研究科エネルギー社会・環境科学専攻 / (主査)教授 河本 晴雄, 教授 亀田 貴之, 准教授 南 英治 / 学位規則第4条第1項該当 / Doctor of Energy Science / Kyoto University / DFAM

Pressurised entrained-flow gasification (PEFG) of woody biomass has the potential to produce high purity syngas for the production of vital chemicals, e.g., biofuels. However, ash-related issues such as reactor blockages and refractory corrosion need to be addressed before this potential can be realised from a technical perspective. These undesirable consequences can be brought about by slag formation involving inorganic ash-forming elements and the chemical transformations that they undergo during fuel conversion. The objective of this study was to elucidate the ash transformations of the major ash-forming elements and the slag formation process. A pilot-scale PEFG reactor was used as the basis of the study, gasifying different woody biomass-based fuels including wood, bark, and a bark/peat mixture. Different ash fractions were collected and chemically analysed. Reactor slags had elemental distributions differing from that of the fuel ash, indicating the occurrence of fractionation of ash material during fuel conversion. Fly ash particles from a bark campaign were also heterogeneous with particles exhibiting differing compositions and physical properties; e.g., molten and crystalline formations. Si was consistently enriched in the reactor slags compared to other major ash-forming elements, while analyses of other ash fractions indicated that K was likely volatilised to a significant extent. In terms of slag behaviour, near-wall temperatures of approximately 1050-1200 °C inside the reactor were insufficient to form flowing ash slag for continuous extraction of ash material during firing the woody biomass fuels alone. However, fuel blending of a bark fuel with a silica-rich peat changed the chemical composition of the reactor slags and bulk slag flow behaviour was evident. Thermochemical equilibrium calculations supported the importance of Si in melt formation and in lowering solidus and liquidus temperatures of Ca-rich slag compositions that are typical from clean wood and bark. Viscosity estimations also showed the impact that solids have upon slag flow behaviour and corresponded qualitatively to the experimental observations. Corrosion of reactor refractory was observed. The mullite-based refractory of the reactor formed a slag with the fuel ash slag, which caused the former to flux away. Reactor blockages were also resultant because of the high viscosity of this slag near the outlet.  A preliminary study into the corrosion of different refractories was also carried out, based on firing a bark/peat mixture.  Alumina-rich refractories consisting of corundum, hibonite, mullite, and andalusite tended to form anorthite and exhibited varying degrees of degradation. Infiltration of slag was evident for all the samples and was a severe mode of degradation for some refractories. For fused-cast periclase and spinel-based refractories, slag infiltration was limited to voids and no extensive signs of refractory dissolution were found. This is also supported by a thermochemical equilibrium calculations mimicking slag infiltration that incorporated viscosity estimations. The findings from this thesis contribute towards the development of woody biomass PEFG by highlighting issues concerning ash fractionation, slag behaviours and ash\slash refractory interaction that should be investigated further.

京都大学 / 0048 / 新制・課程博士 / 博士(エネルギー科学) / 甲第21885号 / エネ博第386号 / 新制||エネ||75(附属図書館) / 京都大学大学院エネルギー科学研究科エネルギー基礎科学専攻 / (主査)教授 片平 正人, 教授 森井 孝, 教授 木下 正弘 / 学位規則第4条第1項該当 / Doctor of Energy Science / Kyoto University / DGAM

While the southeastern United States, including the state of Mississippi, has a strong natural resource base, woody biomass is not fully utilized to produce bioenergy in this region. This study intended to explore opportunities, issues, and the economic potential of wood-based bioenergy in the state of Mississippi. Realizing the importance of private forest landowner decisions in sustaining a bioenergy feedstock supply, one aim of this study was to understand their choices for preferred harvesting methods of supplying woody biomass for wood-based bioenergy industries. Study results indicated that landowners were interested in optimizing revenue from woody biomass utilization while minimizing damage to the surrounding environment and facilitating less site preparation. Similarly, by administering a survey instrument, total and unused volumes of residues in primary and secondary mill operations were also estimated. Availability of woody residue was higher in the primary wood processing industry. Similarly, the likelihood of getting feedstock would be higher if a wood-based bioenergy generating facility could be located near a larger, year round operational forest product industry. This study further accounted for the potential direct, indirect, and induced economic impacts of a state wood-based bioenergy industry. Three potential wood-based bioenergy industries namely wood-pellet, bio-oil and methanol-based gasoline facilities were considered for an economic analysis. Study results revealed that operation of a wood-pellet industry would contribute 82 full- and part-time jobs to the economy with $12 million worth of economic output to the Mississippi economy. Likewise, the operation of a bio-oil industry would generate 165 new full- and part-time jobs and provide an economic output of $17 million. Also, $96 million in economic output and 795 full- and part-time more jobs would be added by establishing a methanol-based gasoline industry. Clearly, these impacts are substantial and are likely to draw the attention of policy makers and investors towards wood-based bioenergy in Mississippi.

Beetle-killed trees and woody residues degenerate and may lead to wildfires and uncontrolled CO2 emission. Woody biomass is known as a neutral CO2 solid fuel since it generates the same amount of CO2 that takes from atmosphere during its growing up. Cofiring woody biomass with coal in existing coal power plants is a reasonable solution to reduce the net amount of CO2 emission and decrease the risk of wildfires. However, there are some challenges ranging from providing and handling the woody biomass to the operation of cofiring woody biomass with coal. Co-milling of the fuels and ash deposition on the heat exchanger surfaces during cofiring are among the most critical challenges. A CFD model simulated the behavior of the pulverized particles and evaluate the impact of geometry and operational changes on mill performance. In addition, we measured the ash deposit rate derived from cofiring woody biomass with coal in a pilot combustor (1500 kW) and full-scale furnace. Moreover, we developed a model to predict ash deposit rate during combustion of coal and its blend with a variety of biomass. The post-processing analysis of CFD modelling of co-milling woody biomass with coal shows that the entrained large woody biomass particles exit the pulverizer along with the fine coal particles due to their lower density than that of coal particles. Some simple geometry and operational changes can optimize mill performance by reducing the number of large biomass particles in the product stream. Therefore, it makes the particle size distribution (PSD) of the product stream of co-milling more like that of coal. The collected data set of fly ash particles and ash deposit samples shows that the ash formation and deposit rates were not impacted significantly by cofiring woody biomass with coal. The concentration of alkali metals in the ash aerosol during cofiring was slightly higher than that of coal. Cofiring in pilot scale combustor made a tri-modal PSD of ash aerosol particles; however, the distribution was bimodal in the full-scale boiler. The ash deposit rates during cofiring in 1500 kW combustor were higher (30 to 70%) at locations closer to the burner at short operation times. Our developed model of ash deposit rate investigated two types of stickiness models of fly ash particles to the surface of heat exchanger: melt fraction stickiness model (MFSM) and kinetic energy stickiness model (KESM). The developed model suggested that the MFSM, which is based on the melt fraction of ash and our novel approach to condensation of alkali vapor species, was more accurate in predicting ash deposit rate of a variety of fuel combustion of a 100-kW combustor. The model calculated four mechanisms: inertial impaction, thermophoresis, condensation, and eddy impaction.

During the last century coal extraction has degraded ecosystems in Appalachia, converting forested land into other cover types that have a diminished capacity to naturally progress to later stages of succession. This projects objective was to examine two options for land-use that can assist in returning the reclaimed surface mines to forested cover types, with increased ecosystem services, and a potential for economic gain. This project examined a biomass plantation and an American chestnut trial. In the biomass trial, greatest heights for American sycamore (12.3 m) and black locust (8.0 m) were found in the fertilizer plots. Mean individual tree biomass for American sycamore and black locust was 6.4 Kg and 5.3 Kg, respectively; no significant differences were found among treatments. In the American chestnut trial, experimental wide survival was 47.2% in 2009, dropping to 24.74% in 2017. No significant differences were found by genotype, stock type, or the interaction in 2017. Use of mined land for woody biomass plantations and locales for chestnut restoration shows potential if proper management techniques are followed. Given the vast amounts of land disrupted by mining activities in Appalachia, approaches such as these deserve further attention and additional research.

Bare-root Nuttall oak, Shumard oak, and swamp chestnut oak seedlings were planted on former agricultural fields in Mississippi to evaluate growth and survival following treatment by different combinations of mechanical site preparation and pre-emergent Oust XP® applications. Mechanical treatments included: (1) controls, (2) subsoiling treatment, (3) bedding treatment, and (4) combination plowing. Pre-emergent Oust XP® treatments included: (1) one-year Oust XP® applications and (2) two-year Oust XP® applications. Evaluations and measurements were performed over the course of three years. Results within this dissertation should be considered in the context of high quality former agricultural sites with silt loam soils. Seedling height and GLD increased each growing season. Height and GLD of seedlings were greater in bedded and combination plowed areas compared to control and subsoiled areas. Height and GLD were not different by Oust XP® application. However, seedling survival in two-year Oust XP® application areas was reduced compared to one-year Oust XP® application areas. Nuttall oak seedlings planted in bedded and combination plowed areas exhibited greater stem biomass compared to those planted in control or subsoiled areas. Seedlings planted in two-year Oust XP® areas exhibited greater stem and root biomass compared to those planted in areas receiving the one-year treatment. Better growth and biomass production in bedded and combination plowed areas would promote their use for site preparation on similar sites. While survival was lower in two-year Oust XP® treatment areas compared to one-year treatment areas, the difference would not warrant change in management strategy. Additionally, woody biomass was much greater in two-year Oust XP® areas. Thus, if cost is not prohibitive, treatment with two years of Oust XP® is recommended. The objective of the mixed species study was to establish baseline growth and survival data for mixed Nuttall oak and green ash plantations on former agricultural areas. Height and GLD for both species increased each growing season. Third-year survival was excellent at 96.0 percent. In conclusion, the mixture performed satisfactorily. Growth and survival were excellent, which indicates this mixture would be useful in afforesting similar former agriculture sites.