Although more than a hundred papers dealing with the agglomeration problem in combustion and gasification of biomass can be found in the literature, very few studies focusing on the bed particle layer formation process in fluidized bed combustion (FBC) and fluidized bed gasification (FBG) can be found. With increased knowledge of the bed particle layer formation process — i.e. the main route behind bed agglomeration and bed material deposition in wood combustion/gasification — suitable combinations of fuel/bed material and/or bed material management measures can be suggested. This would not only aim to reduce the risk of ash related operational problems but also to enhance the catalytic activity of the bed material (e.g. for tar removal in gasification). The present investigation was therefore undertaken to determine the layer formation process on and within typical bed materials (i.e. quartz and olivine) and for a potentially interesting new bed material, K-feldspar. Bed material samples were collected from four different combustion and two different gasification appliances: two bubbling fluidized beds (BFB) (5 kWth/30 MWth), two full-scale circulating fluidized beds (CFB) (90/122 MWth), and two dual fluidized bed gasifiers (DFB) (8/15 MWth). Scanning electron microscopy/energy-dispersive spectroscopy (SEM/EDS) and X-ray diffraction (XRD) were used to explore layer morphology and elemental composition and to gain information about crystalline phases of the layers. Phase diagrams and thermodynamic equilibrium calculations (TECs) were used to interpret the melting behavior of the layers and the melt fragments in deposits. In addition, a diffusion model was used to interpret the layer growth process. For quartz bed particles taken from BFB, the younger particles (< around 1 day) had only one thin layer, but for particles older than 3 days, the layer consisted of inner and outer layers. In addition to the inner and outer layers, a K-rich inner-inner layer was found for bed particles taken from CFB and DFB. No outer layers were found for quartz bed particles taken from DFB. The thin/absence of an outer layer could have resulted from the more significant attrition between particles in CFB and DFB. Reduced availability of Ca and a risk of layer breakage from the particle lead to the formation of the inner-inner layer. Similar elemental compositions of the layers upon the quartz bed particles taken from different fluidized bed techniques were found. The inner-inner layers are dominated by Si, K and Ca (excluding O), and the outer layers are rich in Ca, Si and Mg, which seem to resemble more closely the fuel ash composition. The inner layers, mainly consisted of Si and Ca, were found to have higher concentrations of Ca for older particles. The layer thickness increases with particle age, but the growth rate decreases. Melt was estimated to exist in the inner layer for younger particles (< around 1 day) and in the inner-inner layer. The existence of partially melted inner-inner layers, in particles from CFB and DFB, points towards higher risk of bed agglomeration in these techniques compared to BFB. Based on the experimental results, thermodynamic equilibrium calculations, and diffusion model analyses, a layer formation process on quartz bed particle was suggested: the layer formation is initiated by reaction of gaseous K compounds with quartz to form K-rich silicate melt, which prompts the diffusion of Ca2+. The gradual incorporation of Ca into the melt followed by the precipitation of Ca-silicates, e.g. Ca2SiO4, will result in the continuous inner layer growth. However, because of increasing concentration of Ca and release of K from the inner layer, the melt disappears in the inner layer and the layer formation process gradually becomes Ca diffusion controlled. The diffusion resistance increases with increasing thickness of a more Ca-rich layer, resulting in a decreasing layer growth rate. Crack layers with similar compositions dominated by Si, K and Ca were observed in relatively old quartz bed particles. A melt was predicted to exist in the crack layer according to thermodynamic equilibrium calculations. The crack layers found in quartz particles from BFB and CFB connect with the cracks in the inner layer, whereas for bed samples collected from DFB, the crack layers were found along existing cracks in the quartz particle. The different morphologies may indicate different routes of formation for crack layers in bed particles from different fluidized bed technologies. For quartz particles from BFB and CFB, crack formation through the inner layer down to the interface between the inner layer and the core of quartz bed particle initiates the cracks in the quartz bed particle. This allows for diffusion of gaseous alkali compounds to react with quartz in the bed particle core, thereby forming crack layers. The reaction is accelerated with bridge formation between crack layers. This may later lead to the breakdown of the bed particle into smaller alkali-silicate-rich fragments. For K-feldspar bed particles from BFB and CFB, only one layer was found for particles with an age of 1 day. For bed particles with ages older than 3 days, two layers including a homogenous inner layer containing cracks and a more particle-rich outer layer can be distinguished. Compared to bed particles from BFB with similar ages, the outer layer is thinner for bed particles from CFB. The inner layer is dominated by Ca, Si and Al (excluding O), whereas the outer layer is dominated by Ca, Si and Mg. The average concentration of Ca in the inner layer increases with bed particle age. Increasing layer thickness with decreasing growth rate was found, similar to that on quartz particles. For particles from DFB, the inner layer is also mainly consisted of Ca and Si, but cracks in the inner layer were not found. For all the particles, the Ca/Si molar ratio in the layer decreases towards the bed particle core and the change of concentration is more significant at the bed particle core/layer interface. The overall inner layer growth is resultant from the gradual incorporation of Ca into the layer. For olivine bed particles from DFB, the younger bed particles (< around 24 h) have only one layer, but after 24 h, an inner layer and an outer layer appear. Furthermore, for bed particles older than 180 h, the inner layer is separated into a distinguishable Ca-rich and Mg-rich zone. Two kinds of cracks in the inner layer either perpendicular or parallel to the particle surface were observed. Compared to the younger bed particles, the Ca concentration in the layer of older particles is much higher. A detailed mechanism for layer formation on olivine particles in fluidized bed gasification (most likely also applicable to combustion) based on the interaction between woody biomass ash and olivine has been proposed. The proposed mechanism is based on a solid-solid substitution reaction. However, a possible enabling step in the form of a Ca2+ transport via melts may occur. Ca2+ is incorporated into the crystal structure of olivine by replacing either Fe2+ or Mg2+. This substitution occurs via intermediate states where Ca-Mg silicates, such as CaMgSiO4, are formed. Mg2+ released from the crystal structure most likely forms MgO, which can be found in a distinguishable zone between the main particle layers. Due to a difference in the bond lengths between Mg/Fe and incorporated Ca2+ with their respective neighboring oxygen atoms, the crystal structure shifts, resulting in formation of cracks. The dominating elements in the inner layers are similar for each kind of bed material from BFB, CFB, and DFB, indicating limited effects of atmosphere on the inner layer formation. The initiation of layer formation differs depending on the bed material, but increasing Ca concentration in the inner layer with time for all bed materials indicates that the layer growth resulted from the incorporation of Ca into the layer. Compared to quartz, K-feldspar and olivine are more promising bed materials in wood combustion/gasification, especially in CFB and DFB techniques, from the perspective of mitigating bed agglomeration and bed material deposit build-up.

<p>U doktorskoj disertaciji vr&scaron;eno je istraživanje mogućnosti konverzije energije<br />različitih vrsta drvne biomase procesom pirolize. Ispitivanu drvnu biomasu<br />predstavljale su strugotina hrasta, bukve, tre&scaron;nje, oraha, jele, lipe, kao i<br />me&scaron;avina navedenih vrsta. Dobijeni eksperimentalni rezultati ukazuju da<br />prinos gasa, tečne i čvrste faze tokom odvijanja procesa pirolize zavise od<br />reakcionog vremena, temperature i brzine zagrevanja.</p> / <p>Doctoral dissertation investigates possibilities for energy conversion of<br />different woody biomass types through pyrolysis process. Investigated woody<br />biomass included oak, beech, cherry, walnut, fir, lime wood chips and their<br />mixture. Obtained experimental results imply that gas, liquid and solid phase<br />yields during pyrolysis process depend on reaction time, temperature and<br />heating rate.</p>

Both transportation costs and market values of woody biomass are strongly linked to the amount of moisture in the woody biomass. Therefore, managing moisture in the woody biomass well can lead to significant advantages in the woody biomass energy business. In this study, two prediction models were developed to estimate moisture content for Douglas-fir (Pseudotsuga menziesii (Mirb.) Franco) and hybrid poplar (Populus spp.) woody biomass. Experimental data for the Douglas-fir model were collected over four different seasons at two different in-forest study sites in Oregon (Corvallis and Butte Falls) between December 2010 and December 2011. Three woody biomass bundles consisting of 3-meter length logs (30 to 385 mm diameter) were built each season at each study site; a total of 24 Douglas-fir bundles (1,316 to 3,621 kg weight) were built over the period. Experimental data for the hybrid poplar model were collected in two drying trials at two off-forest study sites in Oregon (Clatskanie and Boardman) between April 2011 and January 2012. Two types of woody bundles consisting of 3-meter length logs were built each trial: small (28 to 128 mm diameter, 2,268 to 5,389 kg weight) and large (75 to 230 mm diameter, 3,901 to 7,013 kg weight). A total of eight hybrid poplar bundles were built over the period. These data were used to develop linear mixed effects multiple regression models for predicting the moisture content of Douglas-fir and hybrid poplar biomass, respectively. The major factors considered in this study for predicting woody biomass moisture content change were cumulative precipitation, evapotranspiration (ET₀), and biomass piece size. The Food and Agriculture Organization (FAO) Penman-Monteith method, which requires temperature, solar radiation, wind, and relative humidity data, was used to calculate ET₀. The developed models can be easily applied to any location where historic weather data are available to calculate estimated air-drying times for Douglas-fir and hybrid poplar biomass at any time of the year. Oregon has been split into nine climate zones. Use of the model was demonstrated for four climate zones, two in which air-drying data were collected, and two in which it was not collected. Considerable differences in predicted drying times were observed between the four climate zones. / Graduation date: 2013

Woody biomass transportation costs and market values/costs are strongly correlated with the woody biomass moisture content. Properly managing moisture content can potentially lead to economic and environmental advantages in biomass energy markets. Good management requires accurate moisture content measurements. Therefore, availability of accurate, precise, reliable, and efficient tools to assess woody biomass moisture content is essential. In this study, six different tools (Fibre-Gen HM200, IML Hammer, Humimeter BLW, Timbermaster, Humimeter HM1 and Wile Bio Meter) were evaluated. The six tools employed three different measurement technologies; acoustic, conductance, and capacitance. Woody biomass samples were collected over one season (summer 2011) at three different locations in western Oregon (Corvallis, Dallas, and Clatskanie) for three softwood species and three hardwood species: Douglas-fir (Pseudotsuga menziesii (Mirb.) Franco), Ponderosa pine (Pinus ponderosa L.), western hemlock (Tsuga heterophylla (Raf.) Sarg.), hybrid poplar (Populus spp.), Madrone (Arbutus spp.), and Garryana Oak (Quercus garryana Dougl. ex Hook). Twenty 3-meter long log (20 to 400mm diameter) specimens were collected per species; 18 specimens were divided into two different treatments (open vs. covered), and the two remaining specimens were chipped. In addition, approximately 100 kilograms per species of hogfuel (limbs and tops) were collected and chipped. Moisture content measurements of logs, chips, and hogfuel were made regularly over a four month period. These data was used to develop multiple linear regression models for assessing the moisture content of the six species using the six tools. The major factors considered in the regression models were species (6), treatment (2), and tools (6). The data were also used to estimate the sample size needed for each tool. The best tool from each technology type was identified. The results generated from this study show that (1) none of the tools are accurate without calibration for different species, (2) the best model/tool combination could only explain about 80% of the variability in measurements, (3) further product development is required in some cases to ensure that the tools are robust for industrial application, and (4) there is a wide range in efficiency of the tools (i.e., 50 minute tool efficiency range). The Fibre-Gen HM200 and Wile Bio Meter were the most accurate, precise and efficient tools tested. The cost of transporting woody biomass from the forest to woody biomass plants is "optimized" when the moisture content drops to approximately 30% (wet basis). Validation of the models developed for three of the tools tested (Fibre-Gen HM200, Humimeter BLW and the Wile Bio Meter) indicates that the tools are accurate below 35% MC (wet basis). This suggests they could be used for making threshold transportation decisions, i.e., determining when to haul. / Graduation date: 2013

As an alternative renewable source for bioenergy, forest biomass has recently drawn more attention from the U.S. government and the general public. Woody biomass policies have been adopted to encourage the new bioenergy industry. A variety of state policy incentives attempt to create a desirable legal climate and lure new firms, imposing two important questions regarding state government policies and the sustainable use of forest resources. This dissertation sheds some light on these questions. The first paper constructs a woody biomass policy index through scoring each statute and weighting different categories of policies from the vantage point of renewable energy investment. It analyzes the disparity in the strength of state government incentives in the woody biomass utilization. The second paper employs a conditional logit model (CLM) to explore the effects of woody biomass policies on the siting decisions of new bioenergy projects. In addition, significant state attributes influencing the births of new bioenergy firms are identified such as resource availability, business tax climate, delivered pulpwood price, and the average wage rate. The third paper uses the Sub-Regional Timber Supply (SRTS) model to examine the regional aggregate forest biomass feedstock potential in Tennessee and to predict the impacts of additional pulpwood demand on the regional roundwood market through 2030. The fourth paper includes the benefits of thinning and logging residues in a dynamic optimization model to analyze how bioenergy policies will impact forest stock, harvest levels, optimal rotation, and silvicultural effort. The results may have substantial implications regarding woody biomass policies, the creation of a new bioenergy industry, and sustainable forest resource management. A lucrative state woody biomass policy support and tax climate can attract new bioenergy businesses. States endowed with abundant forest resources may choose to provide strong tax incentives to spur the birth of new plants. However, overuse of forest biomass can impact roundwood markets and traditional wood processing industries. How government incentives will affect the sustainability of natural resources can be diverse. These findings offer constructive insights in the enactment and implementation of new woody biomass legislation.

Thesis (MFor)--Stellenbosch University, 2011. / ENGLISH ABSTRACT: This study is aimed at testing the possibility of using woody biomass from three invasive woody vegetation types (Spider Gum, Myrtle and Acacia) for production of bioenergy in the Cape Agulhas Plain. Physical recoverability of the woody biomass was studied by means of a semi-mechanized harvesting system to evaluate potential productivity, operational costs and the estimated yield energy gain. The system consisted of five components: manual harvesting, motor-manual harvesting, extraction, chipping and road transport. Data on the system productivity was obtained using activity sampling and time study techniques. Activity sampling was applied on manual and motor-manual harvesting in order to record harvesting time and standard time study techniques were used to obtain time data for extraction, chipping and road transport operations. Findings revealed benefits associated with the utilisation of invasive woody vegetation as energy feedstock. Therefore, the problem of exotic tree species can be dealt with by transforming them into energy feedstock, thus minimising the effect of invasive plants. At the same time essential biomass energy can be produced, while some of the cost of production could be offset by the benefits accruing from the biomass energy. The Acacia site, characterized by larger mature dense trees, had the highest amount of harvested biomass compared to the rest of the vegetation types (i.e. Myrtle and Spider Gum). The overall system productivity was found to be significantly influenced by a low equipment utilisation rate, estimated at 50%. This resulted in low production rates in general. The low supply rate of material to the chipper by the three-wheeled loader (1.5 – 5.3 oven-dry tonne per production machine hour) was found to be a major constraint in the chipping process, especially when considering that the chipper is potentially capable of chipping 4 – 9.4 ODT PMH-1 at the harvesting sites. This resulted in a significant energy balance of 463 GJ between output and input energy of the system. The overall total supply chain system costs based various road transport distances of species ranged from R 322.77 ODT-1 to R 689.76 ODT-1 with an average of R 509 ODT-1. This was found to be costly compare to the case where high machine utilisation rate and optimal productivity are used (average of R 410 ODT-1), biomass recoverability in this field trial had a higher total system cost due to low productivity, resulting from the low equipment utilisation rate applied. / AFRIKAANSE OPSOMMING: Hierdie studie was gemik daarop om die moontlikheid van die gebruik van houtagtige biomassa, afkomstig van uitheemse plantegroei (Bloekom, Mirte en Akasias) op die Agulhasvlakte vir bio-energie te ondersoek. Potensiële produktiwiteit, bedryfskostes en die geskatte energie opbrengs toename is gebruik, om die fisiese opbrengs van houtagtige biomassa van ʼn semi-gemeganiseerde ontginningstelsel te evalueer. Die stelsel het uit vyf komponente bestaan: Handontginning, motor-handontginning, uitsleep, verspandering en padvervoer. Data oor die stelselproduktiwiteit is uit tydstudie en aktiwiteit steekproewe verkry. Aktiwiteit steekproewe is toegepas op hand- en motorhandontgining om ontginingstyd te verkry, terwyl tydstudie standaardtegnieke gebruik is om tyd data vir uitsleep, verspandering en padvervoer werksaamhede te verkry. Bevindings het die voordele met bettrekking tot die gebruik van uitheemse plantegroei as energiebron bevestig. Die uitdaging rondom die verspreiding van uitheemse plantegroei kan dus aangespreek word deur dit as energiebron te benut. Die produksiekoste vir die toegang tot die bruikbare biomassa kan moontlik voorsien word uit die voordele van die gebruik van die energie wat uit die benutting van die biomassa verkry word. Die groter meer volwasse en digte Akasia opstand het die meeste ontginde biomassa gelewer vergeleke met die ander opstande in die studie (d.i. Mirte en Bloekom). Die stelselproduktiwiteit is beduidend beïnvloed deur die lae toerustinggebruik wat minder as 50% beloop het. Dit het ook laer produksievermoë in die algemeen tot gevolg gehad. In die verspandering werksaamheid blyk die lae invoer tempo (1.5 – 5.3 oonddroog ton per produktiewe masjienuur) van die driewiellaaier die beperking op die proses te wees, veral as in ag geneem word dat die verspandering teen 4-9.4 ODT PMH-1 kan geskied. Die resultaat was ʼn beduidende energie balans van 463 GJ tussen uitset- en invoerenergie van die stelsel. Die totale toevoerketting kostes gegrond op verskeie padvervoer afstande van die spesies was tussen R 322.77 ODT-1 tot R 689.76 ODT-1, met ʼn gemiddelde rondom R 509 ODT-1. Die resultaat is duur gevind in vergeleke met gevalle waar hoë masjiengebruik en optimale produktiwiteit (gemiddeld van R 410 ODT-1), moontlik was. Die biomassaherwinning in die studie het ʼn hoër totale stelselkoste gehad veroorsaak deur lae produktiwiteit, wat verwant is aan die laer toerusting gebruikstempo wat verkry is.

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