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>Magister Scientiae - MSc / The Sea Point contact, Cape Town, South Africa, exposes the contact between the Neoproterozoic Malmesbury Group metasedimentary rocks of the Pan-African Saldania belt and the intrusive S-type Peninsula Granite of the Neoproterozoic-Paleozoic Cape Granite Suite (CGS). The exposure outcrops over an area of approximately 170 m × 60 m with the northern end of the exposure being characterized by the country rock–microgranite intrusive contact. Heading further south, the outcrop transitions to the main contact zone, which is a predominantly gradational zone marked by sheets of compositionally variable granitic injections (collectively referred to as hybrid granite phases) concordant to the country rock structure, before reaching the main pluton area comprising the voluminous coarse-grained porphyritic granite. Using a combined study incorporating field, structural, geochemical, isotopic and U-Pb geochronological data, the intrusive contact is investigated to determine the construction history of the pluton and delineate possible emplacement mechanisms. The granitic phases, which vary from fine-grained leucocratic, medium-grained porphyritic to coarse-grained porphyritic, are peraluminous, magnesian to ferroan, and alkali-calcic. Based on the linear trends between the whole-rock major and trace element content of the granites vs. maficity (molar Fe + Mg), their initial Sr ratios and εNd(t) values, the granites of the study area are consistent with the currently proposed petrogenetic model for the CGS (e.g. Stevens et al., 2007; Villaros et al., 2009a; Harris & Vogeli, 2010); i.e., they are crustally derived and their chemical variability is controlled primarily by peritectic assemblage entrainment. The fractional crystallization of K-feldspar is identified as the primary mechanism for the local geochemical variability of the granites. The fractionation of K-feldspar as a mechanism of variability was evaluated using binary log-log diagrams of Ba, Sr and Eu and is interpreted to have taken place at levels close to the emplacement site after source entrainment processes. Although there is outcrop evidence, particularly in the main contact zone, to suggest that local assimilation and filter pressing took place, this was not reflected by the whole-rock and isotope geochemistry of the granites. This suggests that these processes are very localized and will need further rigorous testing to ascertain the extent to which they caused variability. Outcrop evidence for assimilation includes gradational country rock-granite contacts and the ductile behaviour of the country rock, whereas the occurrence of K-feldspar megacrysts embedded in the country rock at the main contact zone suggests melt accumulation and escape consistent with the filter pressing mechanism. In the case of the latter, the melt fraction of the granite was easily mobilized and driven out compared to the crystal fraction (K-feldspars) during the emplacement of the granites. Field relationships and the structural interpretation of the Malmesbury Group country rocks and the granites reveal that: (1) the various granites are late syn-tectonic and (2) were emplaced as incrementally assembled, repeated pulses of inclined granitic sheets more or less normal (i.e. at high angles) to the regional NE-SW shortening (D1) of the Malmesbury forearc during the Saldanian orogeny. Given the lack of a controlling shear zone in facilitating granite emplacement in the study area, the pre-existing planar anisotropies (bedding planes and foliations) in the country rock provided preferential pathways for magma emplacement and propagation during deformation. This implies that the tensile strength normal and parallel to the bedding and foliation anisotropy of the country rock was larger than the regional differential stress (σ1 – σ3, with σ1 ≥ σ2 ≥ σ3), allowing for magma emplacement relative to shortening. Sheet propagation is interpreted to have occurred through the balance of the following conditions: (1) density contrasts between host rocks and magmas, (2) the pressure differential along the subvertical fractures/sheets, and (3) the melt pressure equalling the lithostatic pressure to keep the magma pathways open and being sufficiently high such that it exceeds the sum of σ1 and the tensile strength of the rock parallel to σ1. The crystallization ages of the dated granite samples are identical within error and vary between 538.7 ± 3.6 Ma and 542.7 ± 2.9 Ma. They, therefore, cannot prove which granite phase intruded first and which one proceeded and so forth. Field relationships, however, suggests that the microgranites were first to intrude given their fine-grained nature and the localized chilled contacts they show with the country rock. The various coarser-grained and porphyritic phases were next to intrude, with their coarse grain-sizes and lack of chilled margins with the country rock suggesting that the time interval between their successive emplacements was not too long; this prevented the country rock from completely cooling down between each magma batch. Magma stoping and the ductile flow of the host material (owing to highly viscous magma flow) to accommodate granite emplacement are interpreted to be secondary emplacement processes.

Although more than a hundred papers dealing with the agglomeration problem in combustion and gasification of biomass can be found in the literature, very few studies focusing on the bed particle layer formation process in fluidized bed combustion (FBC) and fluidized bed gasification (FBG) can be found. With increased knowledge of the bed particle layer formation process — i.e. the main route behind bed agglomeration and bed material deposition in wood combustion/gasification — suitable combinations of fuel/bed material and/or bed material management measures can be suggested. This would not only aim to reduce the risk of ash related operational problems but also to enhance the catalytic activity of the bed material (e.g. for tar removal in gasification). The present investigation was therefore undertaken to determine the layer formation process on and within typical bed materials (i.e. quartz and olivine) and for a potentially interesting new bed material, K-feldspar. Bed material samples were collected from four different combustion and two different gasification appliances: two bubbling fluidized beds (BFB) (5 kWth/30 MWth), two full-scale circulating fluidized beds (CFB) (90/122 MWth), and two dual fluidized bed gasifiers (DFB) (8/15 MWth). Scanning electron microscopy/energy-dispersive spectroscopy (SEM/EDS) and X-ray diffraction (XRD) were used to explore layer morphology and elemental composition and to gain information about crystalline phases of the layers. Phase diagrams and thermodynamic equilibrium calculations (TECs) were used to interpret the melting behavior of the layers and the melt fragments in deposits. In addition, a diffusion model was used to interpret the layer growth process. For quartz bed particles taken from BFB, the younger particles (< around 1 day) had only one thin layer, but for particles older than 3 days, the layer consisted of inner and outer layers. In addition to the inner and outer layers, a K-rich inner-inner layer was found for bed particles taken from CFB and DFB. No outer layers were found for quartz bed particles taken from DFB. The thin/absence of an outer layer could have resulted from the more significant attrition between particles in CFB and DFB. Reduced availability of Ca and a risk of layer breakage from the particle lead to the formation of the inner-inner layer. Similar elemental compositions of the layers upon the quartz bed particles taken from different fluidized bed techniques were found. The inner-inner layers are dominated by Si, K and Ca (excluding O), and the outer layers are rich in Ca, Si and Mg, which seem to resemble more closely the fuel ash composition. The inner layers, mainly consisted of Si and Ca, were found to have higher concentrations of Ca for older particles. The layer thickness increases with particle age, but the growth rate decreases. Melt was estimated to exist in the inner layer for younger particles (< around 1 day) and in the inner-inner layer. The existence of partially melted inner-inner layers, in particles from CFB and DFB, points towards higher risk of bed agglomeration in these techniques compared to BFB. Based on the experimental results, thermodynamic equilibrium calculations, and diffusion model analyses, a layer formation process on quartz bed particle was suggested: the layer formation is initiated by reaction of gaseous K compounds with quartz to form K-rich silicate melt, which prompts the diffusion of Ca2+. The gradual incorporation of Ca into the melt followed by the precipitation of Ca-silicates, e.g. Ca2SiO4, will result in the continuous inner layer growth. However, because of increasing concentration of Ca and release of K from the inner layer, the melt disappears in the inner layer and the layer formation process gradually becomes Ca diffusion controlled. The diffusion resistance increases with increasing thickness of a more Ca-rich layer, resulting in a decreasing layer growth rate. Crack layers with similar compositions dominated by Si, K and Ca were observed in relatively old quartz bed particles. A melt was predicted to exist in the crack layer according to thermodynamic equilibrium calculations. The crack layers found in quartz particles from BFB and CFB connect with the cracks in the inner layer, whereas for bed samples collected from DFB, the crack layers were found along existing cracks in the quartz particle. The different morphologies may indicate different routes of formation for crack layers in bed particles from different fluidized bed technologies. For quartz particles from BFB and CFB, crack formation through the inner layer down to the interface between the inner layer and the core of quartz bed particle initiates the cracks in the quartz bed particle. This allows for diffusion of gaseous alkali compounds to react with quartz in the bed particle core, thereby forming crack layers. The reaction is accelerated with bridge formation between crack layers. This may later lead to the breakdown of the bed particle into smaller alkali-silicate-rich fragments. For K-feldspar bed particles from BFB and CFB, only one layer was found for particles with an age of 1 day. For bed particles with ages older than 3 days, two layers including a homogenous inner layer containing cracks and a more particle-rich outer layer can be distinguished. Compared to bed particles from BFB with similar ages, the outer layer is thinner for bed particles from CFB. The inner layer is dominated by Ca, Si and Al (excluding O), whereas the outer layer is dominated by Ca, Si and Mg. The average concentration of Ca in the inner layer increases with bed particle age. Increasing layer thickness with decreasing growth rate was found, similar to that on quartz particles. For particles from DFB, the inner layer is also mainly consisted of Ca and Si, but cracks in the inner layer were not found. For all the particles, the Ca/Si molar ratio in the layer decreases towards the bed particle core and the change of concentration is more significant at the bed particle core/layer interface. The overall inner layer growth is resultant from the gradual incorporation of Ca into the layer. For olivine bed particles from DFB, the younger bed particles (< around 24 h) have only one layer, but after 24 h, an inner layer and an outer layer appear. Furthermore, for bed particles older than 180 h, the inner layer is separated into a distinguishable Ca-rich and Mg-rich zone. Two kinds of cracks in the inner layer either perpendicular or parallel to the particle surface were observed. Compared to the younger bed particles, the Ca concentration in the layer of older particles is much higher. A detailed mechanism for layer formation on olivine particles in fluidized bed gasification (most likely also applicable to combustion) based on the interaction between woody biomass ash and olivine has been proposed. The proposed mechanism is based on a solid-solid substitution reaction. However, a possible enabling step in the form of a Ca2+ transport via melts may occur. Ca2+ is incorporated into the crystal structure of olivine by replacing either Fe2+ or Mg2+. This substitution occurs via intermediate states where Ca-Mg silicates, such as CaMgSiO4, are formed. Mg2+ released from the crystal structure most likely forms MgO, which can be found in a distinguishable zone between the main particle layers. Due to a difference in the bond lengths between Mg/Fe and incorporated Ca2+ with their respective neighboring oxygen atoms, the crystal structure shifts, resulting in formation of cracks. The dominating elements in the inner layers are similar for each kind of bed material from BFB, CFB, and DFB, indicating limited effects of atmosphere on the inner layer formation. The initiation of layer formation differs depending on the bed material, but increasing Ca concentration in the inner layer with time for all bed materials indicates that the layer growth resulted from the incorporation of Ca into the layer. Compared to quartz, K-feldspar and olivine are more promising bed materials in wood combustion/gasification, especially in CFB and DFB techniques, from the perspective of mitigating bed agglomeration and bed material deposit build-up.

Unidades litológicas, em particular arenitos, muitas vezes, carecem de um posicionamento cronoestratigráfico preciso. Como os arenitos são importantes rochas-reservatório de hidrocarbonetos e aquíferos, a falta de exatidão nestas informações dificulta a exploração destes bens minerais. A datação relativa de rochas sedimentares pode ser obtida por análise do conteúdo fossilífero ou por correlação estratigráfica. Entretanto, em algumas rochas sedimentares, esta análise não é possível ou tem um caráter duvidoso. Este é o caso da Formação Marizal (Bacia do Recôncavo) que apresenta um histórico controverso sobre a real idade deposicional. A Formação Marizal é um arenito flúvio-eólico cuja idade é discutível e, por isso, sua posição na coluna estratigráfica (aproximadamente Albiniano/Aptiniano), ainda é questionável. Em algumas amostras são encontrados overgrowths de K-feldspatos e nos quais é possível aplicar a técnica de datação 40Ar-39Ar visando obter idades que possam ser relacionadas com processos ocorrentes nestes arenitos (em geral, deposição e/ou diagênese). Entre os minerais pesados existentes nas amostras da Formação Marizal, foram encontrados grãos de zircões. A datação U-Pb de zircões detríticos pode fornecer informações sobre a proveniência desta unidade. Assim, zircões da Formação Marizal foram analisados visando complementar as informações sobre esta unidade, permitindo uma melhor interpretação. Os overgrowths de K-feldspatos indicaram valor de 159.89 ± 23.96 Ma e, para o núcleo detrítico, 432.57 ± 11.89 Ma. O valor médio obtido em torno de 160 Ma, considerando-se que todos os cuidados analíticos e de seleção de amostra foram considerados, é mais antigo do que o esperado. Assim, este valor foi interpretado como indicativo de que o overgrowth teria sido desenvolvido numa rocha fonte sedimentar sendo posteriormente transportado. Esta idade pode ser relacionada a fase pré rifte da Bacia do Recôncavo. O valor confirma ideias existentes de remobilização do substrato da bacia durante a fase rifte. Como tem sido discutido, overgrowths de K-feldspato são estáveis e possíveis de serem transportados por pequenas distâncias, o que corrobora a interpretação acima. Já o valor obtido para o núcleo mostra a contribuição do Paleoprotrozóico adjacente à bacia, retrabalhado no Brasiliano. Em relação ao zircão, a idade do núcleo detrítico de 432,53± 6,54 Ma pode ser associada com a cobertura sedimentar do Paleoproterozóico retrabalhada no ciclo Brasiliano, também observada nos valores U-Pb definidos para os zircões. Em relação ao zircão, os dados indicam ausência aparente de fontes arqueanas. Os resultados mostram duas fontes principais para a sedimentação: uma Rhyaciana (Paleoproterozóico onde ± 53 % dos grãos são “Transamazônicos”) e outra Neoproterozóica-Cambriana (30% dos zircões são “Brasilianos”). / Sandstones represent the most important reservoir rocks and aquifers in many sedimentary basins. It is necessary to have a precise chronostratigraphic position in order to provide a better explotation of water or hydrocarbons. Traditionally, the relative dating of sedimentary units is obtained with fossil content or stratigraphic correlation. But in many sedimentary rocks these analyses are not possible and sometimes have a dubious interpretation. This is the case of the Marizal Formation (Recôncavo Basin) where many questions arise when the age of the unit is questioned. The Marizal Formation is a fluvio-eolic sandstone which has been associated with an Albian/Aptian age in the stratigraphic column, although very discussible. Samples of sandstones of Marizal Formation present an important diagenetic overgrowths around K-feldspar detrital cores and they are suitable to 40Ar-39Ar dating concerning the identification of processes in the sandstones (as diagenesis or depositional ages). Among the heavy mineral suite in the Marizal Formation, zircon grains are identified. The U-Pb dating of detrital zircons can provide information about the provenance of the unit allowing better interpretation to the Marizal Formation. The overgrowths of K-feldspar indicated a value of 159.89 ± 23.96 Ma and to the detrital core, 432.57 ± 11.89 Ma. The mean value obtained around 160 Ma, considering that all care and analytical sample selection were considered, is older than expected. So, this was interpreted as indicating that the overgrowth, have been developed in a sedimentary source rock being transported latter to the depositional site. This age may be related to pre-rift stage of the Recôncavo Basin. The value confirms previous ideas of remobilization of the substrate during the rift basin stage. As has been extensively discussed, overgrowths of K-feldspars are stable and can be transported by small distances, which corroborates the above interpretation. The value obtained to the detrital core can be associated with a Paleoproterozoic sedimentary cover reworked in the Brazilian cycle. For zircon U-Pb dating, the data indicate no apparent Archean sources. The results show two main sources for sedimentation: a Rhyacian (Paleoproterozoic where ± 53% of the grains are "Transamazonian") and another Neoproterozoic-Cambrian (30% of zircon are "Brazilian").

Unidades litológicas, em particular arenitos, muitas vezes, carecem de um posicionamento cronoestratigráfico preciso. Como os arenitos são importantes rochas-reservatório de hidrocarbonetos e aquíferos, a falta de exatidão nestas informações dificulta a exploração destes bens minerais. A datação relativa de rochas sedimentares pode ser obtida por análise do conteúdo fossilífero ou por correlação estratigráfica. Entretanto, em algumas rochas sedimentares, esta análise não é possível ou tem um caráter duvidoso. Este é o caso da Formação Marizal (Bacia do Recôncavo) que apresenta um histórico controverso sobre a real idade deposicional. A Formação Marizal é um arenito flúvio-eólico cuja idade é discutível e, por isso, sua posição na coluna estratigráfica (aproximadamente Albiniano/Aptiniano), ainda é questionável. Em algumas amostras são encontrados overgrowths de K-feldspatos e nos quais é possível aplicar a técnica de datação 40Ar-39Ar visando obter idades que possam ser relacionadas com processos ocorrentes nestes arenitos (em geral, deposição e/ou diagênese). Entre os minerais pesados existentes nas amostras da Formação Marizal, foram encontrados grãos de zircões. A datação U-Pb de zircões detríticos pode fornecer informações sobre a proveniência desta unidade. Assim, zircões da Formação Marizal foram analisados visando complementar as informações sobre esta unidade, permitindo uma melhor interpretação. Os overgrowths de K-feldspatos indicaram valor de 159.89 ± 23.96 Ma e, para o núcleo detrítico, 432.57 ± 11.89 Ma. O valor médio obtido em torno de 160 Ma, considerando-se que todos os cuidados analíticos e de seleção de amostra foram considerados, é mais antigo do que o esperado. Assim, este valor foi interpretado como indicativo de que o overgrowth teria sido desenvolvido numa rocha fonte sedimentar sendo posteriormente transportado. Esta idade pode ser relacionada a fase pré rifte da Bacia do Recôncavo. O valor confirma ideias existentes de remobilização do substrato da bacia durante a fase rifte. Como tem sido discutido, overgrowths de K-feldspato são estáveis e possíveis de serem transportados por pequenas distâncias, o que corrobora a interpretação acima. Já o valor obtido para o núcleo mostra a contribuição do Paleoprotrozóico adjacente à bacia, retrabalhado no Brasiliano. Em relação ao zircão, a idade do núcleo detrítico de 432,53± 6,54 Ma pode ser associada com a cobertura sedimentar do Paleoproterozóico retrabalhada no ciclo Brasiliano, também observada nos valores U-Pb definidos para os zircões. Em relação ao zircão, os dados indicam ausência aparente de fontes arqueanas. Os resultados mostram duas fontes principais para a sedimentação: uma Rhyaciana (Paleoproterozóico onde ± 53 % dos grãos são “Transamazônicos”) e outra Neoproterozóica-Cambriana (30% dos zircões são “Brasilianos”). / Sandstones represent the most important reservoir rocks and aquifers in many sedimentary basins. It is necessary to have a precise chronostratigraphic position in order to provide a better explotation of water or hydrocarbons. Traditionally, the relative dating of sedimentary units is obtained with fossil content or stratigraphic correlation. But in many sedimentary rocks these analyses are not possible and sometimes have a dubious interpretation. This is the case of the Marizal Formation (Recôncavo Basin) where many questions arise when the age of the unit is questioned. The Marizal Formation is a fluvio-eolic sandstone which has been associated with an Albian/Aptian age in the stratigraphic column, although very discussible. Samples of sandstones of Marizal Formation present an important diagenetic overgrowths around K-feldspar detrital cores and they are suitable to 40Ar-39Ar dating concerning the identification of processes in the sandstones (as diagenesis or depositional ages). Among the heavy mineral suite in the Marizal Formation, zircon grains are identified. The U-Pb dating of detrital zircons can provide information about the provenance of the unit allowing better interpretation to the Marizal Formation. The overgrowths of K-feldspar indicated a value of 159.89 ± 23.96 Ma and to the detrital core, 432.57 ± 11.89 Ma. The mean value obtained around 160 Ma, considering that all care and analytical sample selection were considered, is older than expected. So, this was interpreted as indicating that the overgrowth, have been developed in a sedimentary source rock being transported latter to the depositional site. This age may be related to pre-rift stage of the Recôncavo Basin. The value confirms previous ideas of remobilization of the substrate during the rift basin stage. As has been extensively discussed, overgrowths of K-feldspars are stable and can be transported by small distances, which corroborates the above interpretation. The value obtained to the detrital core can be associated with a Paleoproterozoic sedimentary cover reworked in the Brazilian cycle. For zircon U-Pb dating, the data indicate no apparent Archean sources. The results show two main sources for sedimentation: a Rhyacian (Paleoproterozoic where ± 53% of the grains are "Transamazonian") and another Neoproterozoic-Cambrian (30% of zircon are "Brazilian").

Unidades litológicas, em particular arenitos, muitas vezes, carecem de um posicionamento cronoestratigráfico preciso. Como os arenitos são importantes rochas-reservatório de hidrocarbonetos e aquíferos, a falta de exatidão nestas informações dificulta a exploração destes bens minerais. A datação relativa de rochas sedimentares pode ser obtida por análise do conteúdo fossilífero ou por correlação estratigráfica. Entretanto, em algumas rochas sedimentares, esta análise não é possível ou tem um caráter duvidoso. Este é o caso da Formação Marizal (Bacia do Recôncavo) que apresenta um histórico controverso sobre a real idade deposicional. A Formação Marizal é um arenito flúvio-eólico cuja idade é discutível e, por isso, sua posição na coluna estratigráfica (aproximadamente Albiniano/Aptiniano), ainda é questionável. Em algumas amostras são encontrados overgrowths de K-feldspatos e nos quais é possível aplicar a técnica de datação 40Ar-39Ar visando obter idades que possam ser relacionadas com processos ocorrentes nestes arenitos (em geral, deposição e/ou diagênese). Entre os minerais pesados existentes nas amostras da Formação Marizal, foram encontrados grãos de zircões. A datação U-Pb de zircões detríticos pode fornecer informações sobre a proveniência desta unidade. Assim, zircões da Formação Marizal foram analisados visando complementar as informações sobre esta unidade, permitindo uma melhor interpretação. Os overgrowths de K-feldspatos indicaram valor de 159.89 ± 23.96 Ma e, para o núcleo detrítico, 432.57 ± 11.89 Ma. O valor médio obtido em torno de 160 Ma, considerando-se que todos os cuidados analíticos e de seleção de amostra foram considerados, é mais antigo do que o esperado. Assim, este valor foi interpretado como indicativo de que o overgrowth teria sido desenvolvido numa rocha fonte sedimentar sendo posteriormente transportado. Esta idade pode ser relacionada a fase pré rifte da Bacia do Recôncavo. O valor confirma ideias existentes de remobilização do substrato da bacia durante a fase rifte. Como tem sido discutido, overgrowths de K-feldspato são estáveis e possíveis de serem transportados por pequenas distâncias, o que corrobora a interpretação acima. Já o valor obtido para o núcleo mostra a contribuição do Paleoprotrozóico adjacente à bacia, retrabalhado no Brasiliano. Em relação ao zircão, a idade do núcleo detrítico de 432,53± 6,54 Ma pode ser associada com a cobertura sedimentar do Paleoproterozóico retrabalhada no ciclo Brasiliano, também observada nos valores U-Pb definidos para os zircões. Em relação ao zircão, os dados indicam ausência aparente de fontes arqueanas. Os resultados mostram duas fontes principais para a sedimentação: uma Rhyaciana (Paleoproterozóico onde ± 53 % dos grãos são “Transamazônicos”) e outra Neoproterozóica-Cambriana (30% dos zircões são “Brasilianos”). / Sandstones represent the most important reservoir rocks and aquifers in many sedimentary basins. It is necessary to have a precise chronostratigraphic position in order to provide a better explotation of water or hydrocarbons. Traditionally, the relative dating of sedimentary units is obtained with fossil content or stratigraphic correlation. But in many sedimentary rocks these analyses are not possible and sometimes have a dubious interpretation. This is the case of the Marizal Formation (Recôncavo Basin) where many questions arise when the age of the unit is questioned. The Marizal Formation is a fluvio-eolic sandstone which has been associated with an Albian/Aptian age in the stratigraphic column, although very discussible. Samples of sandstones of Marizal Formation present an important diagenetic overgrowths around K-feldspar detrital cores and they are suitable to 40Ar-39Ar dating concerning the identification of processes in the sandstones (as diagenesis or depositional ages). Among the heavy mineral suite in the Marizal Formation, zircon grains are identified. The U-Pb dating of detrital zircons can provide information about the provenance of the unit allowing better interpretation to the Marizal Formation. The overgrowths of K-feldspar indicated a value of 159.89 ± 23.96 Ma and to the detrital core, 432.57 ± 11.89 Ma. The mean value obtained around 160 Ma, considering that all care and analytical sample selection were considered, is older than expected. So, this was interpreted as indicating that the overgrowth, have been developed in a sedimentary source rock being transported latter to the depositional site. This age may be related to pre-rift stage of the Recôncavo Basin. The value confirms previous ideas of remobilization of the substrate during the rift basin stage. As has been extensively discussed, overgrowths of K-feldspars are stable and can be transported by small distances, which corroborates the above interpretation. The value obtained to the detrital core can be associated with a Paleoproterozoic sedimentary cover reworked in the Brazilian cycle. For zircon U-Pb dating, the data indicate no apparent Archean sources. The results show two main sources for sedimentation: a Rhyacian (Paleoproterozoic where ± 53% of the grains are "Transamazonian") and another Neoproterozoic-Cambrian (30% of zircon are "Brazilian").