[pt] Um estudo experimental em modelos reduzidos do duto PE-3, construído na Baía de Guanabara em 2003, é descrito neste trabalho. O duto PE-3 tem diâmetro externo de 457,2 mm e a sua principal característica é a sua geometria em ziguezague. Este duto transporta óleo combustível à temperatura de 80ºC da Refinaria de Duque de Caxias aos terminais de navios na Ilha D´Água. O presente estudo foi realizado em modelos reduzidos com semelhança física, e teve como objetivo avaliar experimentalmente o comportamento do modelo variando-se o ângulo de ziguezague e o comprimento do duto. Os modelos foram submetidos à variação de temperatura, pressão interna e condições de apoio lateral e longitudinal, simulando as condições reais de trabalho do protótipo. Para cada comprimento (12, 16 e 18 metros) e ângulo de ziguezague (5º, 10º e 15º) foram realizados ensaios com o modelo sem reação lateral do solo, com reação lateral simulando 1 metro de enterramento no protótipo, com reação lateral simulando 1 metro de enterramento e vão central livre, e com imperfeição horizontal. Foram realizados ainda 2 ensaios com um duto reto para efeito de comparação com o modelo zig-zag. Os resultados mostraram que a geometria em ziguezague minimiza os esforços gerados pela expansão térmica do duto. / [en] An experimental study on reduced scale models of the PE-3 pipeline, built in Guanabara Bay in 2003, is described in this work. The main characteristic of the PE-3 pipeline is the zig-zag geometry. This pipeline has an external diameter of 18 and is used to transport heavy heated oil from the Duque de Caxias refinary to a shipping terminal. The present study was carried out in reduced models with physic similitude, and the objective is to evaluate experimentally the behavior of the model, varying the zig-zag angle and the length of the pipeline. The models were submitted to temperature variation, internal pressure and different conditions of lateral and longitudinal support, simulating the real working conditions of the prototype. For each length (12m, 16m and 18m) and zig-zag angle (5°, 10° and 15°) tests were carried out with the model without lateral reaction of the soil, with lateral reaction simulating 1 meter of buried prototype, with lateral reaction simulating 1 meter of buried prototype and central free span, and with horizontal imperfection. Two straight pipeline tests were carried out in order to compare with the zig-zag model. The results showed that the zig-zag geometry minimizes the effects caused by the thermal expansion of the pipeline.

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Thesis (MScEng)--Stellenbosch University, 2013. / ENGLISH ABSTRACT: This thesis is about the design, simulation and measuring of ultra wide band antennas for use in the Square Kilometre Array (SKA). The SKA is a radio astronomy project with one of the aims of detecting hydrogen particles in deep space. Several thousand antennas over a wide band of frequencies are needed to receive the radiation from these particles. This motivates the need for a low-cost ultra wide band antenna with the focus on the low frequency part of the SKA. In this thesis we present two design strategies: The first design strategy is for a printed LPDA on a substrate and design curves are generated. A scale model was built and measurements did not correlate with simulation results. This is due to manufacturing tolerances and assembly of the pyramidal structure. The second design strategy is for a full scale zig-zag antenna and design curves were also generated. The aim here is to produce a low-cost prototype by using brazing rods for the wire structure and mount it on a wooden frame. A full scale model was built and measurements on the roof produced much interference for the radiation pattern, but the reflection coefficient was good. We suggest doing measurements in an interference free environment in order to achieve the needed results. To conclude we suggest using the zig-zag antenna for the SKA. Some issues do however need more attention as the transformer has some losses, the cross polarisation is probably not good enough and the beamwidth does not reach the specification. We demonstrated a low cost prototype and there is the possibility of low-cost large scale manufacturing but this needs to be addressed. This has however not been analysed as many factors for large scale manufacturing are very difficult to predict beforehand and lies outside the scope of this thesis. / AFRIKAANSE OPSOMMING: Hierdie tesis gaan oor die ontwerp, simulasie en opmeting van ultrawyebandantennas vir gebruik in die SKA ("Square Kilometre Array"). Die SKA is ’n radioastronomie projek met die doel om waterstof partikels op te spoor in die ruimte. Duisende antennas wat oor ’n wye band van frekwensies strek is nodig om die energie van die partikels op te vang. Hieruit is daar ’n aanvraag vir lae-koste ultrawyebandantennas met die fokus op die lae frekwensie deel van die SKA. In hierdie tesis word twee ontwerpstrategieë voorgestel: Die eerste ontwerpstrategie is vir ’n gedrukte logaritmies periodiese dipool reeks (LPDR) op ’n substraat tesame met ontwerpskurwes wat gegenereer word. ’n Skaal model is gebou en die gemete resultate stem nie ooreen met die simulasie nie. Dit kan toegeskryf word aan vervaardigingstoleransies en die aanmekaar sit van die piramide struktuur. Die tweede ontwerpstrategie is vir ’n vol skaal sigsag ("zig-zag") antenna met ontwerpskurwes wat ook gegenereer word. Die doel is om ’n lae-koste prototipe te bou deur sweissoldeerdraad te gebruik vir die draadstruktuur en dan op ’n hout raam te plaas. ’n Vol skaal model is gebou en metings op die dak het baie interferensie veroorsaak vir die stralingsveld, maar tog was die weerkaatskoëffisient goed. Ons stel voor om die metings te herhaal in ’n steuringvrye omgewing om sodoende die korrekte resultate te verkry. Om af te sluit stel ons voor om die sigsag antenna vir die SKA te gebruik. Sekere kwessies soos die transformator wat verlieserig is, die kruispolarisasie wat moontlik nie goed genoeg is nie en die bundelwydte wat nie die spesifikasie haal nie moet nog aandag geniet. Ons het ’n lae-koste prototipe gedemonstreer en daar is die moontlikheid om dit op grootskaalse vervaardiging ook goedkoop te doen, maar dit moet nog uigesorteer word. Dit was wel nie geanaliseer nie, siende dat vele faktore ’n rol speel by grootskaalse vervaardiging wat uiters moeilik is om voor die tyd te voorspel en buite die omvang van die tesis lê.

>Magister Scientiae - MSc / A novel monomer (Phenazine-2,3-diimino(pyrrole-2-yl)–PDP) derived from the condensation reaction between 2,3-diaminophenazine and a pyrrole derivative has been synthesized as a hinge molecule in the design of a zig-zag polymer with actuation possibility. The monomer was polymerized chemically and electrochemically to produce the new polymer material – polymerized Phenazine-2,3-diimino(pyrrole-2-yl) PPDP. Two very crucial properties of a good actuator material, relate specifically to its solubility testing and electrical conductivity. The hinged polymer material was studied intensively in terms of its spectroscopy; Fourier Transform Infrared - FTIR, 1H’NMR, thermal properties (Differential Scanning Calorimetry-DSC and Thermogravimetric Analysis-TGA) as well as voltammetry and conductivity. Conductivity was evaluated using three different approaches including; 4 probe measurements, plotting of I/V curves based on potentiostatic measurements and an electrochemical impedance experiment using a dielectric Solartron interface. Electrochemical kinetics of the polymer prepared as a thin film at glassy carbon electrode (GCE) was also done and it was clear that the thin film conductivity was vastly different from the compressed pellet conductivity (thick film). The zig-zag polymer was then further modified by homogeneous inclusion of gold nanoparticles to improve conductivity and solubility, in the thick film arrangement. Conductivity of the thin film was studied by electrochemical impedance spectroscopy with the relative charge transfer values being determined for unmodified and modified polymer systems. The solubility testing of the material plays an important role as it is required for a wide range of experimental applications. The zig-zag polymer showed great promise for applications; in dye sensitized solar cells and free standing interpenetrating polymer network (IPN), solubility testing and electrical conductivity would need to be improved in order to be used in these applications.

Philosophiae Doctor - PhD / A novel monomer (N,N'-Bis-(1H-pyrrol-2-ylmethylene)-benzene-1,2-diamine-BPPD) was derived from the condensation reaction between o-phenylenediamine and a pyrrole derivative. The monomer was polymerized electrochemically to produce the new polymer material - polymerized(N,N'-Bis-(1H-pyrrol-2-ylmethylene)-benzene-1,2-diamine) PBPPD. This novel polymer material was deposited at the surface of a screen-printed carbon electrode, as a thin film, in the development of chemical sensors for the detection of polycyclic aromatic hydrocarbons (PAHs). The monomer material was characterized in terms of its optical (spectroscopy) and thermal properties. The polymer material was characterized in terms of its surface morphology and its redox electrochemistry. Fourier transform infrared spectroscopy (FTIR) was used to confirm the azomethine bond formation during the condensation reaction of an aldehyde and primary amine derivative. / 2020-08-31

This thesis provides a general methodology for classifying and describing many combinatoric problems, systematising and finding theoretical expressions for quantities of interest, and investigating their feasible numerical evaluation. Unifying notation and definitions are provided. Our knowledge of random allocations is also extended. This is achieved by investigating new processes, generalising known processes, and by providing a formal structure and innovative techniques for analysing them. The random allocation models described in this thesis can be classified as occupancy urn models, in which we have a sequence of urns and throw balls into them, and investigate static, waiting-time and dynamic processes. Various structures are placed on the relationship(s) between cells, balls, and the selection of items being distributed, including varieties, batch arrivals, taboo sets and blocking sets. Static, waiting-time and dynamic processes are investigated. Both without-replacement and with-replacement sampling types are considered. Emphasis is placed on the distributions of waiting-times for one or more events to occur measured from the time a particular event occurs; this begins as an abstraction and generalisation of a model of departures of cars parked in lanes. One of several additional determinations is the platoon size distribution. Models are analysed using combinatorial analysis and Markov Chains. Global attributes are measured, including maximum waits, maximum room required, moments and the clustering of completions. Various conversion formulae have been devised to reduce calculation times by several orders of magnitude. New and extended applications include Queueing in Lanes, Cake Displays, Coupon Collector's Problem, Sock-Sorting, Matching Dependent Sets (including Genetic Code Attribute Matching and the game SET), the Zig-Zag Problem, Testing for Randomness (including the Cake Display Test, which is a without-replacement test similar to the standard Empty Cell test), Waiting for Luggage at an Airport, Breakdowns in a Network, Learning Theory and Estimating the Number of Skeletons at an Archaeological Dig. Fundamental, reduction and covering theorems provide ways to reduce the number of calculations required. New combinatorial identities are discovered and a well-known one is proved in a combinatorial way for the first time. Some known results are derived from simple cases of the general models. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1309598 / Thesis (Ph.D.) -- University of Adelaide, School of Mathematical Sciences, 2007

This thesis provides a general methodology for classifying and describing many combinatoric problems, systematising and finding theoretical expressions for quantities of interest, and investigating their feasible numerical evaluation. Unifying notation and definitions are provided. Our knowledge of random allocations is also extended. This is achieved by investigating new processes, generalising known processes, and by providing a formal structure and innovative techniques for analysing them. The random allocation models described in this thesis can be classified as occupancy urn models, in which we have a sequence of urns and throw balls into them, and investigate static, waiting-time and dynamic processes. Various structures are placed on the relationship(s) between cells, balls, and the selection of items being distributed, including varieties, batch arrivals, taboo sets and blocking sets. Static, waiting-time and dynamic processes are investigated. Both without-replacement and with-replacement sampling types are considered. Emphasis is placed on the distributions of waiting-times for one or more events to occur measured from the time a particular event occurs; this begins as an abstraction and generalisation of a model of departures of cars parked in lanes. One of several additional determinations is the platoon size distribution. Models are analysed using combinatorial analysis and Markov Chains. Global attributes are measured, including maximum waits, maximum room required, moments and the clustering of completions. Various conversion formulae have been devised to reduce calculation times by several orders of magnitude. New and extended applications include Queueing in Lanes, Cake Displays, Coupon Collector's Problem, Sock-Sorting, Matching Dependent Sets (including Genetic Code Attribute Matching and the game SET), the Zig-Zag Problem, Testing for Randomness (including the Cake Display Test, which is a without-replacement test similar to the standard Empty Cell test), Waiting for Luggage at an Airport, Breakdowns in a Network, Learning Theory and Estimating the Number of Skeletons at an Archaeological Dig. Fundamental, reduction and covering theorems provide ways to reduce the number of calculations required. New combinatorial identities are discovered and a well-known one is proved in a combinatorial way for the first time. Some known results are derived from simple cases of the general models. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1309598 / Thesis (Ph.D.) -- University of Adelaide, School of Mathematical Sciences, 2007