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The development of future electronics depends on the availability of suitable functional materials. Printed electronics, for example, relies on access to highly conductive, inexpensive and printable materials, while strong light absorption and low carrier recombination rates are demanded in photocatalysis industry. Despite all efforts to develop new materials, it still remains a challenge to have all the desirable aspects in a single material. One possible route towards novel functional materials, with improved and unprecedented physical properties, is to form composites of different selected materials. In this work, we report on hydrothermal growth and characterization of graphene/zinc oxide (GR/ZnO) nanocomposites, suited for electronics and photocatalysis application. For conductive purposes, highly Al-doped ZnO nanorods grown on graphene nanoplates (GNPs) prevent the GNPs from agglomerating and promote conductive paths between the GNPs. The effect of the ZnO nanorod morphology and GR dispersity on the nanocomposite conductivity and GR/ZnO nanorod bonding strength were investigated by conductivity measurements and optical spectroscopy. The inspected samples show that growth in high pH solutions promotes a better graphene dispersity, higher doping and enhanced bonding between the GNPs and the ZnO nanorods. Growth in low pH solutions yield samples characterized by a higher conductivity and a reduced number of surface defects. In addition, different GR/ZnO nanocomposites, decorated with plasmonic silver iodide (AgI) nanoparticles, were synthesized and analyzed for solar-driven photocatalysis. The addition of Ag/AgI generates a strong surface plasmon resonance effect involving metallic Ag0, which redshifts the optical absorption maximum into the visible light region enhancing the photocatalytic performance under solar irradiation. A wide range of characterization techniques including, electron microscopy, photoelectron spectroscopy and x-ray diffraction confirm a successful formation of photocatalysts. Our findings show that the novel proposed GR-based nanocomposites can lead to further development of efficient photocatalyst materials with applications in removal of organic pollutants, or for fabrication of large volumes of inexpensive porous conjugated GR-semiconductor composites.

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Constrained sintering is an important process for many applications. The sintering process almost always involves some form of constraint, both internal and external, such as rigid particles, reinforcing fibers and substrates to which the porous body adheres. The densification behavior of zinc oxide and cordierite-base crystallizable glass constrained on a rigid substrate was studied to add to the understanding of the behavior of various materials undergoing sintering when subjected to external substrate constraint. Porous ZnO films were isothermally sintered at temperatures between 900°C and 1050°C. The results showed that the densification of films constrained on substrates is severely reduced. This was evident in the sintered microstructures where the particles are joined together by narrower necks forming a more open structure, instead of the equiaxed grains with wide grain boundaries observed in the freestanding films. The calculated activation energies of densification were also different. For the density range of 60 to 64%, the constrained film had an activation energy of 391 ± 34 kJ/mole compared to 242 ± 21 kJ/mole for the freestanding film, indicating a change in the densification mechanism. In-plane stresses were observed during the sintering of the constrained films. Yielding of the films, in which the stresses dropped slight or remained unchanged, occurred at relative densities below 60% before the stresses climbed linearly with increasing density followed by a gradual relaxation. A substantial amount of the stresses remained after cooling. Free and constrained films of the cordierite-base crystallizable glass (glass-ceramic) were sintered between 900°C and 1000°C. The substrate constraint did not have a significant effect on the densification rate but the constrained films eventually underwent expansion. Calculations of the densification activation energy showed that, on average, it was close to 1077 kJ/mole, the activation energy of the glass, indicating that the prevailing mechanism was still viscous flow. The films expanded earlier and faster with increasing sintering temperature. The expansion was traced to the formation of pores at the interface with the silicon substrate and to a lesser extent on aluminum nitride. It was significantly reduced when the silicon substrate was pre-oxidized at 900°C, leading to the conclusion that the pore formation at the interface was due to poor wetting, which in turn was caused by the loss of the thin oxide layer through a reaction with the glass. / Ph. D.

This work investigates the feasibility of developing a self-powered structural health monitoring (SHM) smart tire using piezoelectric materials. While this work is divided into two components: SHM and energy harvesting, the context of smart tire in this work is defined as the development of a SHM system that (i) has self-powering capabilities, and (ii) addresses the potential of embedding sensors. The use of impedance based SHM on a tire is severely limited due to the low stiffness and high damping characteristics of the tire. This work propose the use of a high voltage impedance analyzer, and the addition of electrical circuit to enhance the damage detection process. Experimental work was conducted on an aluminum beam and on a tire section with commercially available piezoelectric sensors. The use of a high voltage impedance analyzer was demonstrated to provide insight on damage type and damage location. Two sensors were connected in parallel as an effective sensory system, and was shown to reduce interrogation time, but reduce damage identification sensitivity. With added electrical circuits, a belt separation on the tire was successfully detected by the shift in electrical impedance signature. For the energy harvesting portion of this work, a bimorph piezoelectric energy harvester model was derived using extended Hamilton's principle and the linear constitutive relations of piezoelectric materials. Comparison of model with experimental data at increasing loading conditions demonstrated the monotonic increase in voltage output, with linear asymptotes at extreme loading conditions (short-circuit and open-circuit). It also demonstrated the existence of an optimal resistive load for maximum power output. To address the ability to embed sensors, an existing fabrication process to grow arrays of ZnO nanowires in carbon fiber reinforced polymer was used in this work. Comparison of power generation from a composite beam with ZnO nanowires with a composite beam without ZnO nanowires demonstrated the power generation capabilities of the nanowires. A maximum peak voltage of 8.91 mV and peak power of 33.3 pW was obtained. After the application of 10V DC, a maximum of 45 pW was obtained. However, subsequent application of 20V DC reduced the maximum peak power output to 2.5 pW. Several attempts to increase power generation including adding a tip mass and changing the geometry of the composite beam were conducted. Finally, the theoretical voltage frequency response function obtained from the theoretical piezoelectric constant and dielectric constant of a single ZnO nanowire were compared to the experimental voltage frequency response function. The discrepancies were discussed. / Master of Science