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We make a first-order calculation of accumulation rates in the catchment of Thwaites Glacier (TG), West Antarctica using the Nye and Daansgard-Johnson methodologies. Both formulations compute accumulations as a function of the age-depth relationship, including a thinning correction due to ice flow. For this purpose, I track and firn-correct two continuous, shallow ice layers obtained from radio echo soundings surveyed during the 2004-05 AGASEA expedition. The layers range from 60 to 700 meters depth between the ice divide and the coast. Dating of layers come from the ice core WDC06A, located on the West Antarctic Ice Sheet (WAIS) ice divide, which have ages 548 and 725 years, respectively. We compare our accumulation results with four independent datasets: 1)IceBridge snow radar (2009-2010), optimized for tracking near-surface layers; 2) a contemporary model of snowfall precipitation, 3) an interpolation of ice core data using satellite passive microwave; 4) ice cores data. We test the hypothesis that accumulation rates have increased since the beginning of the industrial era, a change that has not been observed. Indeed, I find that observations indicate that accumulation rates in the TG catchment have not changed during the past ~700 years. From here I assess the mass balance of the system and analyze what it tells about the history of the glacier. / text

This thesis uses palaeolimnological records to reconstruct Holocene ontogeny trends from four lakes in south western Greenland. The research addresses four hypotheses investigating how Holocene lake ontogeny trends vary under different climatic settings, how long-term changes in ontogeny relate to periods of established climatic change in the region, the similarities between proxies within the lakes and between the lakes, and the role of vegetation in lake ontogeny. The study region occupies the widest ice-free area of south western Greenland and is characterised by a climatic gradient. The area inland and nearer to the ice-margin is arid, receives less precipitation and is warmer relative to the coastal areas. A paired lake approach, using lake records from two inland lakes and two coastal lakes, was adopted to examine the role of climatic setting upon lake development trajectories. Specifically, diatoms were used to reconstruct DI-alkalinity from the lakes using a DI-alkalinity model created from existing training sets in the region (WA Cla model, r2boot = 0.76, RMSEP = 0.28 log alkalinity units), sedimentary pigments to investigate trends in production and sedimentary parameters to reconstruct organic and minerogenic accumulation rates. All four lakes experienced comparable Holocene long-term ontogeny trajectories; maximum alkalinity in the first ~ 1000 cal. year BP of deglaciation followed by maximum production during the peak of Holocene Thermal Maximum (HTM) warming (~7000 -6000 cal. years BP). Following the HTM, all lakes demonstrated oligotrophication and a decline in pH. Vegetation development and catchment stabilisation at the end of the HTM may be important in determining the onset of oligotrophication in vegetated catchments. However, the impact of vegetation development on lake ontogeny cannot be isolated from the changes in the lakes associated with the colder and wetter climate which occurred at the end of the peak HTM warming. The timings of the large transitions in the ontogeny trajectories are comparable with established periods of Holocene climatic variability in the region; climate forcing drives ontogeny in these lakes. However, there are short-term differences between the lakes indicating that lakes have different thresholds of ecological change and may respond differently to the same climate forcing. It is concluded that ontogeny is driven by climate but lakes may respond differently to forcing depending on catchment specific characteristics which can filter out the climate signal or cause climate to influence the lake in a more direct way.

The Gulf of Mexico (GoMx) is among the most productive regions for offshore oil and natural gas recovery. In 2010, the Deepwater Horizon (DWH) drilling rig exploded, burned for three days, sank, and released over 4 million barrels of oil in the subsequent 84 days before it was capped. Some oil was buoyant enough to float to the ocean surface, where some was removed via a myriad techniques. Importantly, a plume of oil remained suspended in the water column at approximately 1,100 m water depth, where it drove a marine snow event, and deposited large quantities of oil on the seafloor. The northern GoMx seafloor is complex and dynamic. Submarine canyons, mounds, channels, and salt domes dominate the seafloor along the continental slope surrounding the DWH well. Using high-resolution bathymetric data, variables derived to characterize the seafloor (water depth, distance, slope, and aspect), and spatial relationships between seafloor stations and the DWH well, relationships between concentrations, fluxes and inventories of polycyclic aromatic hydrocarbons, and other seafloor variables were hypothesized to be statistically significantly related. The most significant seafloor characteristic to predict distributions was water depth, followed by distance, relative aspect, and slope.

Systeme von Vorlandbecken repräsentieren bedeutende geologische Archive und dienen dem Verständnis von Rückkopplungen zwischen oberflächennahen und tektonischen Prozessen. Außerdem dokumentieren sie die Entwicklung unmittelbar angrenzender Bergketten. Die sedimentären Abfolgen in Vorlandbecken reflektieren das Gleichgewicht zwischen tektonischer Subsidenz, der Bildung langzeitlichen Akkommodationsraumes und des Sedimenteintrages, welcher wiederum die Wirksamkeit von Erosions- und Massenneuverteilungsprozessen wiederspiegelt. Um die Effekte von Klima und Tektonik in einem solchen System zu erforschen, untersuchte ich die Oligo-Miozänen Sedimente in den Vorlandbecken der südlichen Elburs Bergkette, einem intrakontinentalen Gebirge in Nord-Iran, das im Zuge der Arabisch-Eurasischen Kontinent-Kollision herausgehoben wurde. In dieser Studie der Vorlandbeckensedimente wurden Datierungstechniken angewandt (40Ar/39Ar, (U-Th)/He Thermochronologie und Magnetostratigraphie), die Sedimente und deren Herkunft analysiert und die Tonmineralogie, sowie Sauerstoff- und Kohlenstoffisotope untersucht. Die Ergebnisse zeigen, dass auf einer Zeitskala von 105 bis 106 Jahren eine systematische Korrelation zwischen „coarsening upward“ Zyklen und den sedimentären Akkumulationsraten besteht. Während sukzessiver Überschiebungsphasen werden die durch Hebung der Bergkette bereitgestellten groben Kornfraktionen in proximale Bereiche des Beckens geliefert und feinkörnige Fazies in distalen Beckenregionen abgelagert. Variationen in der Sedimentherkunft in Phasen größerer tektonischer Aktivität zeugen von erosionaler Abdeckung und/oder der Umorganisation natürlicher Entwässerungsstrukturen. Außerdem zeigen die Untersuchungen an stabilen Isotopen, dass die verstärkte tektonische Aktivität das Anwachsen der Topographie förderte und damit die Wirksamkeit einer topographischen Barriere erhöhte. Wenn aufgrund nachlassender Beckenabsenkung die grobe Kornfraktion nicht vollständig im Nahbereich des Beckens aufgenommen werden kann breitet sie sich in ferne Beckenregionen aus. Im Elburs wird die verringerte Subsidenz durch eine interne Hebung des Vorlandes hervorgerufen und ist mit einer lateralen Stapelung von Flussbetten assoziiert. Dokumentiert wird dies anhand konsequenten Schichtwachstums, tektonischer Schrägstellung und sedimentärer Umlagerung. Gleichzeitig nehmen die Sedimentationsraten zu. Die Sauerstoff-Isotope der Paläoböden zeigen, dass dieser Anstieg mit einer Phase feuchteren Klimas einhergeht, wodurch Oberflächenprozesse effizienter werden und Heraushebungssraten steigen, was eine positive Rückkopplung erzeugt. Des Weiteren zeigen die isotopischen und sedimentären Daten, dass seit 10-9 Millionen Jahren (Ma) das Klima durch saisonalen Anstieg der Niederschläge zunehmend feuchter wurde. Da bedeutende klimatische Veränderungen zu dieser Zeit auch im Mittelmeerraum und Asien beobachtet wurden, ist anzunehmen, dass die klimatische Veränderung, die im Elburs Gebirge beobachtet wird, höchstwahrscheinlich Änderungen der atmosphärischen Zirkulationen der nördlichen Hemisphäre reflektiert. Aus den Ergebnissen dieser Studie lassen sich zusätzliche Implikationen für die Entwicklung des Elburs Gebirges und die Arabisch-Eurasische kontinentale Kollisionszone ableiten. Die orogen-weite Hauptdeformation propagierte nicht gleichmäßig nach Süden, sondern seit dem Oligozän schrittweise vorwärts und rückwärts. Insbesondere von ~17,5 bis 6,2 Ma wurde das Gebirge durch eine Kombination aus frontaler Akkretion und interner Keildeformation in Schritten von 0,7 bis 2 Millionen Jahren herausgehoben. Darüber hinaus deuten die Sedimentherkunftsdaten darauf hin, dass sich noch vor 10-9 Ma die Haupteinengungsrichtung von NW-SE nach NNE-SSW veränderte. Regional erlaubt die Geschichte der untersuchten Becken und angrenzenden Gebirgszüge Rückschlüsse auf ein neues geodynamisches Model zur Entwicklung der Arabisch-Eurasischen kontinentalen Kollisionszone. Zahlreiche Sedimentbecken des Elburs Gebirges und anderer Lokalitäten der Arabisch-Eurasischen Deformationszone belegen einen Wechsel von einem tensionalen zu einem kompressionalen tektonischen Regime vor ~36 Ma . Dieser Wechsel könnte den Beginn der Subduktion von gedehnter arabischer kontinentaler Lithosphäre unter Zentral-Iran bedeuten, was zu einer moderaten Plattenkopplung und Deformation von Unter- sowie Oberplatte geführt hat. Der Anstieg der Deformationsraten im südlichen Elburs Gebirge seit ~17,5 Ma lässt vermuten, dass die Oberplatte, wahrscheinlich aufgrund steigender Plattenkopplung, seit dem frühen Miozän signifikant deformiert wurde. Diese Veränderung könnte der Subduktion mächtigerer arabischer kontinentaler Lithosphäre zugeschrieben werden und den Anfang echter kontinentaler Kollision bedeuten. Dieses Model erklärt daher die Zeitverzögerung zwischen der Initiation der Arabisch-Eurasischen kontinentalen Kollision (Eozän-Oligozän) and dem Beginn ausgedehnter Deformation in der Kollisionszone (Miozän). / Foreland-basin systems are excellent archives to decipher the feedbacks between surface and tectonic processes in orogens. The sedimentary architecture of a foreland-basin system reflects the balance between tectonic subsidence causing long-term accommodation space and sediment influx corresponding to efficiency of erosion and mass-redistribution processes. In order to explore the effects of climatic and tectonic forcing in such a system, I investigated the Oligo-Miocene foreland-basin sediments of the southern Alborz mountains, an intracontinental orogen in northern Iran, related to the Arabia-Eurasia continental collision. This work includes absolute dating methods such as 40Ar/39Ar and zircon (U-Th)/He thermochronology, magnetostratigraphy, sedimentological analysis, sandstone and conglomerate provenance study, carbon and oxygen isotope analysis, and clay mineralogy study. Results show a systematic correlation between coarsening-upward cycles and sediment accumulation rates in the basin on 105 to 106yr time scales. During thrust loading phases, the coarse-grained fraction supplied by the uplifting range is stored in the proximal part of the basin (sedimentary facies retrogradation), while fine-grained sediments are deposited in distal sectors. Variations in sediment provenance during these phases of enhanced tectonic activity give evidence for erosional unroofing phases and/or drainage-reorganization events. In addition, enhanced tectonic activity promoted the growth of topography and associated orographic barrier effects, as demonstrated by sedimentologic indicators and the analysis of stable C and O isotopes from calcareous paleosols and lacustrine/palustrine samples. Extensive progradation of coarse-grained deposits occurs during phases of decreased subsidence, when the coarse-grained fraction supplied by the uplifting range cannot be completely stored in the proximal part of the basin. In this environment, a reduction in basin subsidence is associated with laterally stacked fluvial channel deposits, and is related to intra-foreland uplift, as documented by growth strata, tectonic tilting, and sediment reworking. Increase in sediment accumulation rate associated with progradation of vertically-stacked coarse-grained fluvial channels also occurs. Paleosol O-isotope data shows that this increase is related to wetter climatic phases, suggesting that surface processes are more efficient and exhumation rates increase, giving rise to a positive feedback. Furthermore, isotopic and sedimentologic data show that starting from 10-9 Ma, climate became less arid with an increase in seasonality of precipitation. Because important changes were also recorded in the Mediterranean Sea and Asia at that time, the evidence for climatic variability observed in the Alborz mountains most likely reflects changes in Northern Hemisphere atmospheric circulation patterns. This study has additional implications for the evolution of the Alborz mountains and the Arabia-Eurasia continental collision zone. At the orogenic scale, the locus of deformation did not move steadily southward, but stepped forward and backward since Oligocene time. In particular, from ~ 17.5 to 6.2 Ma the orogen grew by a combination of frontal accretion and wedge-internal deformation on time scales of ca. 0.7 to 2 m.y. Moreover, the provenance data suggest that prior to 10-9 Ma the shortening direction changed from NW-SE to NNE-SSW, in agreement with structural data. On the scale of the entire collision zone, the evolution of the studied basins and adjacent mountain ranges suggests a new geodynamic model for the evolution of the Arabia-Eurasia continental collision zone. Numerous sedimentary basins in the Alborz mountains and in other locations of the Arabia-Eurasia collision zone record a change from a tensional (transtensional) to a compressional (transpressional) tectonic setting by ~ 36 Ma. I interpret this to reflect the onset of subduction of the stretched Arabian continental lithosphere beneath central Iran, leading to moderate plate coupling and lower- and upper-plate deformation (soft continental collision). The increase in deformation rates in the southern Alborz mountains from ~ 17.5 Ma suggests that significant upper-plate deformation must have started by the early Miocene most likely in response to an increase in degree of plate coupling. I suggest that this was related to the subduction of thicker Arabian continental lithosphere and the consequent onset of hard continental collision. This model reconciles the apparent lag time of 15-20 m.y between the late Eocene to early Oligocene age for the initial Arabia-Eurasia continental collision and the onset of widespread deformation across the collision zone to the north in early to late Miocene time.

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