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6,6’-Dimethoxygossypol (DMG) is a natural product of the cotton variety Gossypium barbadense and a derivative of gossypol. Gossypol has been shown to form an abundant number of clathrates with a large variety of compounds. One of the primary reasons why gossypol can form clathrates has been because of its ability to from extensive hydrogen bonding networks due to its hydroxyl and aldehyde functional groups. Prior to this work, the only known solvate that DMG formed was with acetic acid. DMG has methoxy groups substituted at two hydroxyl positions, and consequently there is a decrease in its ability to form hydrogen bonds. Crystallization experiments were set up to see whether, like gossypol, DMG could form clathrates. The following results presented prove that DMG is capable of forming clathrates (S1 and S2) and two new polymorphs (P1 and P2) of DMG have been reported.

京都大学 / 0048 / 新制・課程博士 / 博士(理学) / 甲第20164号 / 理博第4249号 / 新制||理||1611(附属図書館) / 京都大学大学院理学研究科物理学・宇宙物理学専攻 / (主査)准教授 池田 隆介, 教授 石田 憲二, 教授 川上 則雄 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM

There has been in the past ten to fifteen years a surge of activity concerning the cohomology of semi-direct product groups of the form $\mathbb{Z}^{n}\rtimes$G with G finite. A problem first stated by Adem-Ge-Pan-Petrosyan asks for suitable conditions for the Lyndon-Hochschild-Serre Spectral Sequence associated to this group extension to collapse at second page of the Lyndon-Hochschild-Serre spectral sequence. In this thesis we use facts from integer representation theory to reduce this problem to only considering representatives from each genus of representations, and establish techniques for constructing new examples in which the spectral sequence collapses.