Thesis (Ph. D.)--Washington State University, August 2006. / Includes bibliographical references (p. 64).

Thesis (Ph. D.)--Washington State University, August 2006. / Includes bibliographical references (p. 64). Also available online.

Thesis (M.S.)--Michigan State University. Dept. of Geological Sciences, 2006. / Title from PDF t.p. (viewed on Nov. 20, 2008) Includes bibliographical references (p. 76-80). Also issued in print.

Thesis (M.S.)--University of Massachusetts Amherst, 2009. / Includes bibliographical references (p. 83-87).

Thesis (Ph. D. ), Memorial University of Newfoundland, 1999. / Bibliography: p. 194-217.

Ever since the development of farming humans have been implicitly linked with the landscape. Influences include the manipulation of natural environments by woodland clearance, field developments and animal husbandry. Development can also be determined by the identification and distribution of soils developed and modified by the addition of organic and inorganic components. Anthropogenic or amended soils have been identified in many forms across north west Europe that retain distinctive physical and chemical indications of historical agrarian and settlement history. This thesis researched the on-site distribution of anthropogenic and amended soils across different landuse areas and identified and quantified a range of black carbonised particles in order to investigate their role in the soils ability to retain high elemental concentrations of manuring and elements associated with domestic activity and industrial processes. Three sites in contrasting environments were chosen for analysis; in Fair Isle, the Netherlands and Ireland on the basis of an excellent agararian and settlement history and previous analysis of anthropogenic soils. The fieldwork results showed extremly deep plaggen soils in the Netherlands but considerably shallower horizons of amended arable soils on Fair Isle and in Ireland contrary to previous analysis. There was however, clear evidence of a reduction in anthropogenic and amended soils with increased distance from the farm centres as a result of less manuring. The soil pH, organic matter, particle size, magnetic susceptibility and bulk elemental analysis results showed unexpected increases in the amended soils of Fair Isle and Ireland and reflected a similar manuring process. In the Netherlands the deep plaggen soils had very low results reflecting modern arable farming. The micromorphology results illustrated distinctive characteristics associated with localised manuring techniques. On Fair Isle and in Ireland the main organic manuring material was peat and burnt peat, whereas in the Netherlands the plaggen soils were predominantly composed of meadowland and heathland turf. At all three sites there was a large number of black carbonised and black amorphous inclusions and point counting and image analysis results showed a decrease with depth and distance from settlement nucleii mirroring the fieldwork observations. The elemental analysis conducted has proved to be an extremly useful tool for the identification of various forms of black carbon and for identifying the provenance of high elemental concentrations. The oxygen:carbon ratios confirmed the origins of organic components used in the development of the amended and anthropogenic soils and the elemental analysis showed that at each site over 80% of visually unidentifiable amorphous black carbon particles were heavily decomposed carbonised inclusions. Overall the elemental concentrations within the black carbonised particles was very low but this reflected the elemental results found in the bulk soils and the inclusions contained higher concentrations of P, Ca, K, Fe and Al and considerably lower concentrations of elements associated with domestic activity or industry Zn, Cu, Ba, Cr, As and Pb.

The aim of Part One was to discover and investigate the physical and chemical properties of coal minesoils occurring within the Big South Fork National River and Recreation Area (BSF) in order to better understand the nature of these anthropogenic soils. In particular, this information was to identify which, if any, un-reclaimed or recently reclaimed minesoils were actively producing acid mine drainage (AMD) and what properties were inhibiting revegetation. Historical knowledge and maps were used to locate more than 30 un-reclaimed and reclaimed minesoil sites, which were mapped with GPS. Soil profiles were exposed on 18 sites and grab samples taken on another 12. The morphological properties of each full profile were described according to the National Soil Survey Handbook and samples were taken from each horizon. Chemical properties analyzed for include: particle size, acid-base account, pH, exchangeable aluminum, manganese oxides, soil organic carbon, cation-exchange capacity, exchangeable bases, Mehlich I-extractable elements, and total elemental concentrations. Significant differences in the following properties (averaged) were discovered between the un-reclaimed and reclaimed minesoils: slope, percent rock fragments, dominant lithology, net neutralization potential, pH, extractable aluminum, base saturation, several Mehlich I-extractable nutrients and total elemental concentrations. Hierarchical clustering analysis revealed similar findings and also highlighted instances where reclaimed minesoils were statistically more similar to un-reclaimed minesoils than to other reclaimed minesoils. This indicated that reclamation efforts may not have been completely successful on these sites. In Part Two, minesoil profiles were classified according to Soil Taxonomy and according to proposed amendments by the International Committee for Anthropogenic Soils (ICOMANTH). The ICOMANTH amendments provided more informative classifications for coal minesoils in the BSF however, shortcomings were noted. Additional recommendations were made and the minesoils were again classified according to these recommendations. Compared to both the Soil Taxonomy and the ICOMANTH classifications, those according to the proposed additional amendments revealed more of the unique properties of the minesoils studied in this project. The results of this study can aid the National Park Service with future land management of the minesoils located within the BSF boundaries and other users of drastically disturbed minesoils.

Suite à des usages intensifs d’origines industrielles, des surfaces considérables de sols dégradés, peu fertiles, voire contaminés sont délaissées. Dans un contexte de raréfaction des sols et de pressions foncières et économiques grandissantes, la réhabilitation de ces sols fortement anthropisés et délaissés peut-être un enjeu. Toutefois, pour envisager une réutilisation de ces sols, il est nécessaire de mieux les caractériser. L’étude de la qualité des sols prend rarement en compte la biodiversité et le fonctionnement biologique. Ainsi, l’objectif de ce travail de thèse était de caractériser des sols délaissés, en prenant en compte leurs paramètres abiotiques, biotiques et fonctionnels. Pour cela, six sols fortement anthropisés délaissés du nord-est de la France, correspondant à différentes activités industrielles, ont été étudiés in situ et en laboratoire. Plusieurs groupes biotiques (bactéries, champignons, mésofaune, macrofaune et flore) ont été étudiés afin d’avoir une approche quasi-exhaustive de la biodiversité des sols. Une approche taxonomique et fonctionnelle (basée sur les traits) de la biodiversité a été réalisée pour les champignons, la méso- et la macrofaune. De plus, l’évolution in situ au cours du temps des paramètres abiotiques et biotiques a été prise en compte sur un des six sols délaissés étudiés. Enfin, les interactions biotiques entre une espèce de collembole, de champignon mycorhizien à arbuscules et de plante herbacée ont été étudiées dans deux sols délaissés, en laboratoire. Nous avons montré que les sols délaissés étaient caractérisés par une biodiversité significative, comparable selon les cas, à celles d’autres types de sols, comme les sols forestiers, de prairies ou agricoles. Toutefois, des différences de densité, de richesse et de structures taxonomiques et fonctionnelles entre les sols délaissés existent et dépendent du groupe biotique étudié. Ces différences sont notamment liées aux propriétés physico-chimiques contrastées de ces sols. Ainsi, un sol construit, amendé en compost, était l’écosystème le moins perturbé des sols étudiés, contrairement à un autre sol construit et contaminé en métaux lourds. Nous avons montré que les paramètres physico-chimiques, et surtout biologiques, évoluaient rapidement au cours du temps (environ un an) dans le sol construit contaminé en métaux lourds. Enfin, nous avons mis en évidence, dans les deux sols étudiés en laboratoire, des modifications des interactions biotiques sous l’influence de nombreux paramètres comme le volume de sol, la durée de l’interaction, la présence d’une microflore indigène etc. Finalement, nous avons montré que ces sols pouvaient être le support de services écosystémiques tels que l’habitat pour la biodiversité et qu’ils pouvaient être fonctionnels, permettant ainsi de considérer leur potentielle valorisation / Due to industrial activities intensification, large surfaces of degraded soils, with low fertility and sometimes contamination, are derelict. In the context of land depletion and economic pressure, the rehabilitation of these derelict anthropogenic soils could be a key issue. However, these derelict soils needs to be better characterized before to consider their potential use. Soil quality studies rarely take into account the biodiversity and the biological functioning. Thus, the aim of this PhD work was to characterize derelict soils by considering their abiotic, biotic and functional parameters. To this end, six derelict strongly anthropogenic soils from north-eastern France, resulting from different industrial activities, were studied in situ and in laboratory. Several biotic components (bacteria, fungi, mesofauna, macrofauna and flora) were studied to have an almost complete approach of the soil biodiversity. Taxonomical and functional (trait-based approach) study of biodiversity was performed for fungi, meso- and macrofauna. Moreover, the in situ evolution over time of abiotic and biotic parameters was taken into account in one of the six studied derelict soils. Lastly, biotic interactions between a species of Collembola, of arbuscular mycorrhizal fungi and of herbaceous plant were studied in two derelict soils, in a growth chamber. We showed that derelict soils were characterized by a significant biodiversity, comparable case to case with other kinds of soils like forest, grassland or crop. Nevertheless, differences in terms of density, richness and taxonomical and functional structure community were observed between soils and depend on considered biotic group. These differences were notably linked with contrasting physico-chemical parameters between soils. Thus, a compost-amended constructed soil was the less disturbed among the six studied soils, in contrast with a heavy metal-contaminated constructed soil. We showed that abiotic parameters, notably biotic parameters, evolved quickly (within one year) in the metal-contaminated constructed soil. In the two derelict soils where interactions between Collembola and mycorrhizal fungi were studied, biotic interactions were affected by several parameters like soil volume, time of interaction, indigenous microflora presence etc. Finally, we have shown that these derelict soils support ecosystems services such as biodiversity reserve and could be functional, allowing potential re-use

In an interdisciplinary study requiring the synergistic association of historical evidence and chemical and biochemical analyses, this thesis investigates the properties and characteristics of historically modified soils known as anthrosols. These soils, developed through the anthropogenic addition of high volumes of organic-rich municipal waste materials to land, including human and animal waste, as part of the waste management practices in medieval urban communities in Scotland at St Andrews, Roxburgh and Elgin, offer an insight to the state and dynamics of these organic material. Soil is one of the most sensitive environmental domains to transformation. These transformations are visible from the alterations to the physical and chemical properties of soil. Anthropogenic activities may leave behind signatures in the soil in the form of artefacts, ecofacts, elemental enrichment or depletion, enhancement in soil magnetic properties and organic matter content. In the historical dimension of this study, the observable features and measurable properties of soil profiles are exploited to reveal past organisation and functions of cultural landscapes by carefully studying the stratigraphic units of soil profile, and examining the association of each unit with settlement artefacts and soil properties. Through comparison with historical records of past events on the respective study sites, the relationship between the soils record of past human activities is observed through physical, chemical and biochemical properties. The historical record is used to assess if such evidence can be used reliably to develop the account of site use for the medieval burghs of Scotland. In the environmental aspect, investigation focuses on the physical and chemical conditions of these soils in terms of their carbon content, composition, residence time estimates and their role in global C cycle and terrestrial carbon budgeting. Past investigations of anthopogenically-deepened soils have been interpreted with respect to historical site use, however, the environmental implications of the resultant accumulated organic material or residue have not previously been considered in much detail. A particular novelty of this aspect of the project is that it is an in-depth examination of anthropogenic soils with known histories extending into the medieval period. This time-depth allows a new understanding of the processes and products of decomposition of known organic materials that were added to soil. The biophysicochemical data obtained from these soils such as their extant organic carbon content and variability with depth, the composition of the various carbon species that together constitute soil organic matter, and biological community and activity (microorganisms and enzymes) provides critical information on the relative recalcitrance, state of decomposition, and the mechanism of stabilisation of these materials in the soil.

Deep anthropogenic topsoils – those augmented through long-term additions of mineral bulk among fertilising agents – retain in both their physical and chemical make-up significant indicators for cultural activity. This project researched the geographical distribution and historical context of deep anthropogenic topsoils in Scotland and the Isles, and used this information to investigate the impact of current land cover upon the cultural information they retain. In so doing, the project investigated the potential for conservation of this significant cultural resource. A review of the historical information available on agricultural and manuring practices for Scotland identified several factors likely to affect deep topsoil distribution and frequency. These were: the availability of bulk manures to Scottish farmers, the significance of the seaweed resource in determining fertiliser strategies in coastal areas, and the influence of urban settlement and associated patterns of domestic and industrial waste disposal on the location of deep topsoils. Evidence for widespread deep topsoil development was limited. The primary data source used – the First Statistical Account of Scotland – was manipulated into a spatial database in ArcView GIS, to which geographical data from the Soil Survey of Scotland and national archaeological survey databases were added. This was used to devise a survey programme aiming both to investigate the potential factors affecting soil development listed above, and to locate deep topsoil sites for analysis. Three sites were identified with deep topsoils under different cover types (woodland, arable and pasture). The urban-influenced context of two of these highlighted the significance of urban settlement to the location of Scottish deep topsoils. Analysis of pH, organic matter, and total phosphorus content showed a correlation between raised organic matter and a corresponding increase in phosphorus content in soils under permanent vegetation. By contrast, soils under arable cultivation showed no such rise. This was attributed to the action of cropping in removing modern organic inputs prior to down-profile cycling. The potential for pasture and woodland cover to affect relict soil signatures was therefore observed. Thin section analysis aimed to both provide micromorphological characterisation of the three deep topsoil sites and investigate the effect of modern land cover on micromorphological indicators. Distinctive differences in micromorphological character were observed between the rural and urban deep topsoils, with the latter showing a strong focus on carbonised fuel residues and industrial wastes. All sites showed a highly individual micromorphological character, reflective of localised fertilising systems. There was no correlation between land cover type and survival of material indictors for anthropogenic activity, with soil cultural indicators surviving well, particularly those characteristic of urban-influenced topsoils. Suggestions for preservation strategies for this potentially rare and highly localised cultural resource included the incorporation of deep anthropogenic topsoil conservation into current government policy relating to care of the rural historic environment, and the improvement of data on the resource through ongoing survey and excavation.