<p>  </p> <p>Since the commercialization of dicamba-resistant soybean and cotton, numerous instances of suspected off-target dicamba movement onto sensitive plant species have been reported. Further investigation into chemical and environmental factors that influence dicamba volatilization is warranted to better understand the mechanisms that lead to increased dicamba off-target movement via volatilization and plant response to dicamba vapor. The environmental impacts of dicamba must be minimized in order to ensure the sustainability and continued use of dicamba, which is an important herbicide for controlling broadleaf weeds in key cropping systems and non-crop sites. </p> <p>Controlled environment experiments were conducted to characterize the chemical interactions with dicamba volatility for three formulations of dicamba on glass slides. Dicamba volatility was similar for spray solution pH levels 4 to 8 for the diglycolamine (DGA) and the diglycolamine with VaporGrip® (DGA+VG) formulations. For the N,N-Bis-(3- aminpropyl) methylamine (BAPMA) formulation, dicamba volatility increased at a pH level of 5 with continued increases in volatility occurring as spray solution continued to decrease indicating that BAPMA formulation is more sensitive to pH fluctuations than the DGA and the DGA+VG formulations. While spray solution pH levels below 4 increased dicamba volatility for all three formulations compared to each formulation applied at a native pH level (5.53, 5.2, and 6.28 for the DGA, DGA+VG, and BAPMA formulations, respectively), the largest increase in dicamba volatility occurred when ammonium or iron was added to spray solution. Therefore, applicators should avoid mixing dicamba with other tank-mix partners that contain ammonium or iron to minimize the likelihood for dicamba volatilization. </p> <p>While extensive research exists documenting the process of dicamba volatilization, there has been little confirmation regarding how volatilized dicamba enters sensitive plants. Dicamba-sensitive (DS) soybean with different levels of canopy conductance, from different watering regimes and exposure time of day, were exposed to dicamba vapor. The DS soybean response was positively correlated with soybean canopy conductance during the dicamba vapor exposure suggesting that dicamba vapor route of entry into soybean is facilitated through the stomata. An additional experiment was conducted that exposed the single side of a hypostomatic leaf to dicamba vapor on different northern red oak trees. Northern red oak tree response was substantially greater when the abaxial leaf surface (high stomatal density) was exposed to dicamba vapor compared to when the adaxial leaf surface (no stomata) was exposed to dicamba vapor. Thus, dicamba vapor entry into plants is largely facilitated via stomata and secondly through re-deposition onto the leaf surface, where dicamba is absorbed through the plant cuticle, albeit minor. If dicamba vapor is redeposited onto leaf surfaces, dicamba acid absorption through the cuticle can be limited without the presence of a surfactant. Field and greenhouse experiments confirmed that the presence of surfactants from applications of other formulated herbicides can exacerbate soybean response to dicamba acid that was deposited on the leaf surface. </p> <p>In the midwestern United States, off-target dicamba movement to DS soybean has been problematic as DS soybean are extremely sensitive to very low concentrations of dicamba. Field and greenhouses studies confirmed that there are phenotypic differences amongst different soybean genotypes and their response to dicamba. Estimations of visual soybean injury was approximately 10% less for genotypes that were less sensitive to dicamba compared to genotypes with increased sensitivity. The future identification of the mechanisms that lead to decreased sensitivity to dicamba could be used to identify soybean cultivars that could mitigate the impacts of dicamba off-target movement to DS soybean. </p> <p>Lastly, a field experiment was conducted that investigated the influence of simulated dew on dicamba volatility from dicamba treated soybean leaves, in addition to soybean response in the presence of dicamba vapor. The results from a field experiment determined that consecutive simulated dew applications increase dicamba volatility from dicamba treated soybean. Furthermore, this is the only research demonstrating that DS-soybean response increases from dicamba vapor in the presence of dew. The results from this dissertation provide further insight into the chemical and environmental factors that influence dicamba volatility, the route of entry of dicamba vapor into plants, and soybean response to dicamba.</p>

<p dir="ltr">Blockchain technology, once the backbone of Bitcoin, has burgeoned into a powerhouse of potential, signaling a revolutionary shift across various sectors, including finance, supply chains, and digital identity. This paradigm shift, which replaces trust in centralized entities with a decentralized ledger of transparency, is rapidly gaining traction among global entities. Despite the promise, blockchain's smart contract evolution has also introduced significant risks, as demonstrated by notorious breaches like the DAO hack. This research offers a dual-focused inquiry into the technological sophistication and social implications of blockchain, particularly smart contracts, assessing both their promise and their perils. It meticulously examines their design, potential vulnerabilities, and recounts sobering lessons from historical breaches.</p><p dir="ltr">To address these concerns, the study presents advanced strategies for vulnerability detection and proactive remedies, recognizing the critical need for security in our digitally convergent economy. In Chapter 3, a novel methodology is employed that uses a comprehensive dataset against advanced detection tools, aiming to address and mitigate vulnerabilities. Chapter 4 provides empirical evidence of the methodology's efficacy, underpinning a critical discussion with real-world applicability and challenges.</p><p dir="ltr">Ultimately, this paper acts as a clarion call for vigilant and innovative strides in blockchain security, emphasizing the technology's vast capabilities against the need for solidified trust. It invites the global research community to join a collaborative effort in addressing the open challenges and fostering advancements to ensure the safe expansion of blockchain technology.</p>

Yes / Cementitious composites, the most abundant human-made materials in the world, are challenged to be more sustainable, durable and cost-effective to adapt to the development of structural engineering, economy and environment. Owing to their excellent strength, toughness and durability, nano-fillers reinforced cementitious materials have attracted broad attention in civil engineering researches and applications. However, it is worth noting that nano-fillers reinforced cementitious materials achieve their proprieties by using of different industrial nano-fillers, i.e., graphenes, carbon nanotubes, carbon nanofibers, etc. Although the properties of conventional cementitious materials are improved, the incorporation of the above nano-fillers are high cost and environmental footprint. Different from high-energy consuming carbon nanofillers, nanocellulose is one of the biomass-derived nanofillers with excellent nanometer properties, biological performances and composite effects, and it has proved to be a promising green filler to enhance the mechanical properties, durability and functional properties and lower the carbon footprint of cementitious composites. Therefore, this paper provides an overview on biomass-derived nanocellulose modified cementitious composites, mainly focusing on their fabrication, properties (early performance, mechanical performance, durability, and functional performance) and applications. It also concludes with an outline of some future opportunities and challenges in the development of biomass-derived nanocellulose modified cementitious composites.

In the process of exploring the thorium fuel application in CANDU reactors, it is important to consider the proliferation resistance level as a parameter for comparison with current natural uranium fuel. The concept of a whole fuel cycle was introduced to show the variations in the proliferation resistance level as the material is flowing through the cycle. The depletion and decay histories were simulated with SCALE 6.1 code and the results such as isotopes composition, decay heat, and radioactivity were used to analyze the material attractiveness of pure heavy metal for weapon production. They also served as the intrinsic features during the proliferation resistance level calculation. The Multi-Attribute Utility Analysis (MAUA) method developed by Chalton was used to compare different CANDU fuel cycles with quantified values (PR) from the viewpoint of proliferation resistance. To improve the biased MAUA results that gave a PR of 0.76 to CANDU while 0.93 to PWR, the attributes of size/weight and refueling scheme were reconsidered. In addition, the sensitive technology involved was added for the proliferation resistance recalculation. The results showed an increased PR value of 0.82 for natural uranium CANDU reactor as well as a decreasing trend of PR at the back end. PWR has a PR of 0.82 with revised MAUA method. The PR comparison of thorium and natural uranium fuel indicated that Th/Pu fuel has a slightly higher PR value in the reactor. The Figure of Merit (FOM) method developed by Bathke was used to validate the PR results from another perspective: the attractiveness of pure heavy metals that are suitable for nuclear weapon production. The results showed that FOM of plutonium keeps increasing with decay time and the trend becomes more significant after disposal in the deep geological repository. The FOM of uranium from Th/Pu cases is higher than that of Pu within several hundred years but maintains a decreasing trend. The decreasing FOM of uranium is preferred for direct disposal in deep geological repository. The decreased PR level and the increased FOM value of plutonium at the back end of a fuel cycle indicate the importance of implementing the security and safeguard for each facility dealing with nuclear materials. The comparison results of PR and FOM values for different fuel provided feedback and suggestions for the new fuel application. / Thesis / Master of Applied Science (MASc)

Software applications’ performance is hindered by a variety of factors, but most notably by the well-known CPU-memory speed gap (often known as the memory wall). This results in the CPU sitting idle waiting for data to be brought from memory to processor caches. The addressing used by caches cause non-uniform accesses to various cache sets. The non-uniformity is due to several reasons, including how different objects are accessed by the code and how the data objects are located in memory. Memory allocators determine where dynamically created objects are placed, thus defining addresses and their mapping to cache locations. It is important to evaluate how different allocators behave with respect to the localities of the created objects. Most allocators use a single attribute, the size, of an object in making allocation decisions. Additional attributes such as the placement with respect to other objects, or specific cache area may lead to better use of cache memories. In this dissertation, we proposed and implemented a framework that allows for the development and evaluation of new memory allocation techniques. At the root of the framework is a memory tracing tool called Gleipnir, which provides very detailed information about every memory access, and relates it back to source level objects. Using the traces from Gleipnir, we extended a commonly used cache simulator for generating detailed cache statistics: per function, per data object, per cache line, and identify specific data objects that are conflicting with each other. The utility of the framework is demonstrated with a new memory allocator known as equivalence class allocator. The new allocator allows users to specify cache sets, in addition to object size, where the objects should be placed. We compare this new allocator with two well-known allocators, viz., Doug Lea and Pool allocators.

Industry 4.0 is associated with the technological complexity of designing frameworks for factory automation. In that case, since the robots are used in factory operations, this paper proposes a framework that can be used for (near) real-time applications (RTA) in the robotic system. Real-time application is a time constraint that works within a time frame, making it essential to set up a high-speed system in data computation and processing. Monitoring sensors are exposed to different physical variables, such as noise and vibration temperature, from the system, which leads to inefficient data and delay in the data computations. Adaptive Sampling Algorithm A.S.A. was used to reduce the amount of data to be computed. A self-adaptive software (i.e., Rainbow framework) was used to implement the algorithm—Hardware-in-the-loop (HiL) simulation technique used in the simulation of A.S.A. The hardware used in this scenario is the Speedgoat real-time target machine. The proposed framework was tested in an implementation scenario where the robot system had high latency, above 10ms, and had to be reduced to 5ms and below. The results showed fewer samples were collected from the test signal after implementing the algorithm. Hence reducing high latency and increasing real-time application in robot systems. In summary, the proposed framework could be used to develop real-time applications in robotic systems for Industry 4.0.

Digital Twins are softwarized mirrors of physical systems. They can represent their corresponding physical counterparts in real-world applications and reflect the behavior of the latter under different scenarios with decent accuracy. In this thesis, we consider the case where an application requests data from multiple digital twins, each representing a physical system. The digital twins are hosted on execution servers located between the application and the set of physical devices. Each digital twin has to be periodically updated by its physical system and uses a portion of the execution server’s computing resource to refresh itself. Due to the scarcity of computation resources of the execution servers, in this thesis, we have tackled the problem of optimal digital twin placement onto a limited set of execution servers. We are aiming at minimizing the latency of the digital twins’ responses to the application’s requests while keeping the age of information of served data below a certain threshold. We first formulate the problem as an integer quadratic program (IQP) and then transform it into a semidefinite program (SDP). We prove that the problem is NP-complete and propose polynomial-time approximation algorithms that solve the problem with different trade-offs between the accommodation of the application’s request latency and the achievement of data age targets. / Thesis / Master of Applied Science (MASc)

The Grid has revolutionized the way computations are done on the Internet. Access to remote computational resources and ad hoc creation of virtual organizations across administrative domains opens new opportunities on the Grid. The newly developed web services based Open Grid Services Architecture makes the Grid more accessible by allowing the Grid to be constructed from distinct platform independent components. Together they provide an environment for application sharing (or trading), collaborations and access to remote data repositories. The application marketplace is a natural extension to this application sharing environment. The marketplace addresses the fact that the existing infrastructure is still incomplete without provisions for publishing and discovering applications and resources, including the application descriptors that must be moved between the market participants. This work demonstrates a web service instance-based infrastructure, the application market that allows the sellers, the application and the CPU providers to publish their applications for the users to find and use. The application market uses a portal architecture built on top of Globus toolkit 3.0 that interacts with the providers and the users. The market services provide distinct interfaces that allow providers to advertise applications and users to select, configure, and run these applications. The applications themselves are modeled as stateful objects represented using XML which can be exchanged between the providers and users when required. The marketplace, through its interfaces, effectively hides the compute resource and application complexity thus allowing end users to explore and use applications unfamiliar to them with ease.

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