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<p>The Arctic Ocean and Western Antarctic Peninsula (WAP) are the fastest warming regions on the planet and are undergoing rapid climate and ecosystem changes. Until we can fully resolve the coupling between biological and physical processes we cannot predict how warming will influence carbon cycling and ecosystem function and structure in these sensitive and climactically important regions. My dissertation centers on the use of high-resolution measurements of surface dissolved gases, primarily O2 and Ar, as tracers or physical and biological functioning that we measure underway using an optode and Equilibrator Inlet Mass Spectrometry (EIMS). Total O2 measurements are common throughout the historical and autonomous record but are influenced by biological (net metabolic balance) and physical (temperature, salinity, pressure changes, ice melt/freeze, mixing, bubbles and diffusive gas exchange) processes. We use Ar, an inert gas with similar solubility properties to O2, to devolve distinct records of biological (O2/Ar) and physical (Ar) oxygen. These high-resolution measurements that expose intersystem coupling and submesoscale variability were central to studies in the Arctic Ocean, WAP and open Southern Ocean that make up this dissertation. </p><p>Key findings of this work include the documentation of under ice and ice-edge blooms and basin scale net sea ice freeze/melt processes in the Arctic Ocean. In the WAP O2 and pCO2 are both biologically driven and net community production (NCP) variability is controlled by Fe and light availability tied to glacial and sea ice meltwater input. Further, we present a feasibility study that shows the ability to use modeled Ar to derive NCP from total O2 records. This approach has the potential to unlock critical carbon flux estimates from historical and autonomous O2 measurements in the global oceans.</p> / Dissertation

Approved for public release; distribution in unlimited. / The recent decreasing trend of sea ice cover in the Arctic region and its projected future reduction has direct implications for the global thermohaline circulation and the U.S. Navy. This thesis provides a qualitative and quantitative analysis of the freshwater export from the Arctic Ocean through the Canadian Arctic Archipelago (CAA) and the Fram Strait into the deep-water formation region of the Labrador Sea, using model data from 1979 to 2002. The results of this thesis directly aid the Navy in preparing personnel, ships, and weapons systems to operate efficiently in a possible ice-free Arctic. A coupled ice-ocean model of the pan-Arctic region at a 1/12-degree and 45-level grid resolution was used to produce data over a 24-year time period. The 24-year averaged annual velocity, temperature, and salinity profiles were compared for each of the analyzed stations. Additionally, 24-year mean monthly volume and freshwater flux time series plots and annual cycle plots were also produced to analyze the region's interannual variability from 1979 to 2002. The results show that the Canadian Arctic Archipelago is the major contributor of freshwater to the Labrador Sea. The CAA is a direct pathway for increased freshwater export from the Arctic into the sub-arctic seas where North Atlantic Deep Water(NADW)forms. The increased freshwater flux through the CAA, found in this study, supports the earlier reports on the freshening of NADW and a possibility of reduction in the meridional overturning rate in the North Atlantic. An increase in freshwater export from the Arctic is a good indicator of increasing sea ice reduction. The predicted opening of the Arctic to commercial and military vessels poses a direct threat to U.S. economical and strategic interests in the Arctic region. This thesis supports the U.S. Navy's ability to operate in a possibly ice-free Arctic. / Ensign, United States Navy

Deep troughs and ridges of the Arctic Basin are some of the least known features of the Earth's crust. Some of the ridges, eg. Chukchi and Nordwind, are connected directly to the continental shelves and are certainly submarine promontories of the latter. The character of the Lomonosov Ridge as a narrow slice of continental crust that separated from the Eurasian margin in the early Cenozoic (by opening of the Eurasian Basin), is not in doubt. Recent drilling (ACEX) and piston coring have confirmed this interpretation. However there are many other ridges and some of the troughs that are of uncertain origin. Seismic research in combination with potential field data over the East-Siberian margin, Podvodnikov and Makarov basins and the Mendeleev Ridge, presented here, provides a framework for understanding this enigmatic part of the Earth. The constrained models of the crust illustrate their structure. The crust beneath the East Siberian margin is up to 40 km thick; it thins to about 20 km towards to the Podvodnikov Basin. The models over the Arlis Gap, in the middle of the Podvodnikov Basin, and the Mendeleev Ridge have shown that the crust beneath both these features is anomalously thick (up to 28–32 km) and has a velocity structure that suggests the presence of highly attenuated continental crust. The crustal thickness over the Makarov Basin varies from 8 km to 15 km. Reflection profiles provide evidence of the character and thickness of the sedimentary cover (mostly Cenozoic and late Mesozoic), both on the ridges and beneath the troughs. Presented here is evidence that some of the ridges (eg. Marvin Spur) appear to be fragments of continental crust rifted off the Lomonosov Ridge (with a similar, unconformable Cenozoic cover); however, they gently plunge into and beneath troughs (eg. Makarov Basin). Reflection seismic data collected by the HOTRAX expedition in 2005 over the central part of the Lomonosov Ridge illustrate the sedimentary structure on the top of the Ridge and in an internal basin. The main sedimentary units can be interpreted by correlation with the ACEX results. The major fault separating the surrounding ridges from the internal basin appears to have a roll over anticline in the hanging wall, suggesting that the basin was created by a growth fault. The seismic lines provide evidence of gently folded basement beneath the Lomonosov Ridge with intra basement reflections are usually parallel to the upper surfaces; in combination with velocities (c. 4–5 km/s), these suggest the presence of old well-consolidated sediments.

The reconstruction of past environmental conditions is a fascinating research area that attracts the interest of many individuals in various geological disciplines. Paleoenvironmental reconstruction studies can shed light on the understanding of past climates and are a key to the prediction of future climate changes and their consequences. These studies take on special significance when focused on areas sensitive to climate change. The Arctic region, which is experiencing dramatic changes today in its peatlands and in its ocean, is prime example. The entire region plays a major role in global climate changes and has recently received considerable interest because of the potential feedbacks to climate change and its importance in the global carbon cycle. For a better understanding of the role of Arctic peatlands and the Arctic Ocean to global climate changes, more records of past conditions and changes in the region are needed. This work applies different geochemical proxies, with special emphasis on lipid biomarkers, to the study of a permafrost peat deposit collected from the Eastern European Russian Arctic and a marine core retrieved from the Lomonosov Ridge in the central Arctic Ocean. The results reported of this study show that molecular stratigraphy obtained from the analysis of lipid biomarkers in both peat and marine profiles, combined with other environmental proxies, can contribute significantly to the study of Arctic ecosystems of the past. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 2: Manuscript. Paper 3: Manuscript. Paper 4: Manuscript.</p>

Thesis (Ph. D.)--University of Wisconsin--Madison, 1971. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.

The Arctic marine system is currently undergoing transition as a result of climate change. This study examines the effects of this transition on rates of air-sea CO2 exchange within the eastern Canadian Arctic. Continuous seawater pCO2 measurements revealed this area to be a strong summertime sink of atmospheric CO2. Total alkalinity and stable oxygen isotopes were utilized as freshwater tracers, revealing areas of significant sea ice melt and riverine inputs. Eastern Baffin Bay and Barrow Strait were found to be strongly influenced by sea ice melt, lowering seawater pCO2; whereas Kennedy Channel contained significant river discharge, raising seawater pCO2. Primary production in surface waters was low throughout the region, with the exception of Petermann Fjord where glacial ice melt likely transports nutrients to the surface. This region is anticipated to represent a weaker CO2 sink in the future, due mainly to predicted decreases in sea ice thickness and extent. / February 2016

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Submarine topographic features of the channels, sounds, fiords, and bays can best be explained as the products of extensive glacial excavation of a pre-existing drainage system. Troughs, hanging troughs, strings of deeps or basins, terminal sills, linear rises and depressions, and oversteepened deltas are considered direct or indirect evidence of glacial scour. Following glaciation, a negative movement of the Sverdrup Basin was accompanied by flooding of the northern part of the Archipelago. Only the upper portions of former interfluvial areas remained above sea level. These topographic highs are the present-day islands of the Canadian Arctic Archipelago. Statistical analyses of beach, fluvial, deltaic, and offshore marine sediments reveal characteristics that may be unique to polar deserts and ice-covered seas. Textures of beach and fluvial sediments are a function of associated relief and parent material. The deltaic environment is defined as that portion of the sea floor extending from the mouth of a river to approximately 3,200 feet from shore. Deltaic sediments show a progressive decrease in grain size seaward. Size distribution is related to the settling velocities of particles of different diameters. Offshore sediments have uniform textural properties. They are a combination of silt and clay (settled from suspension), and a minor but significant portion of sand- to granule-sized sediment (ice-rafted). An increase in mean grain size on the crests of submarine topographic highs suggests that winnowing by currents is taking place over these features. Two large areas of the sea floor lack a cover of Recent sediment. Organic carbon constitutes 0.84 to 2.14% of the offshore sediments. A dual source, terrigenous and phytoplanktonic, may explain the relatively high percentage of organic carbon. There is a positive correlation between percent organic carbon and amount of clay in the samples. Results of semiquantitative clay-mineral analyses of source rock, fluvial, deltaic, and offshore marine sediments indicate that montmorillonite, kaolinite, and illite are the dominant clay minerals. In this northern region, there is no change in clay mineralogy during weathering and transport. It is suggested that this may be characteristic of weathering under polar desert conditions. The mineralogy of parent materials on the islands controls the clay mineral distribution in offshore areas. In Louise Fiord, well-crystallized kaolinite is differentially flocculated close to shore. A study of the roundness of quartz grains of sand, silt, and clay size reveals that the distribution of this property is bimodal. Coarse and medium sands are well rounded, fine sands through coarse silts are angular, and fine silt and clay-sized particles are well rounded. High roundness of grains in the medium to coarse sand grades is attributed to abrasion. Well rounded quartz in the silt-clay size range is considered to be a product of solution. / text