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1	New investigations into Sandmeyer chemistry Taylor, Alec Brian January 2000 (has links) No description available. 547 Diazonium ions; Aryl radicals; Kinetics
2	Marcacao, distribuicao e estudo cinetico da benziodarona com I-131 em ratos da linhagem Wistar SHIMIZU, SANAE 09 October 2014 (has links) Made available in DSpace on 2014-10-09T12:23:16Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T13:56:08Z (GMT). No. of bitstreams: 1 01036.pdf: 919968 bytes, checksum: 8432333a9ebb3f09ef6cf9cbf84c9622 (MD5) / Dissertacao (Mestrado) / IEA/D / Instituto de Biociencias, Universidade de Sao Paulo - IB/USP aryl radicals benzofurans drugs e. isotopes iodine 131 reaction kinetics biochemical reaction kinetics tracer techniques
3	Marcacao, distribuicao e estudo cinetico da benziodarona com I-131 em ratos da linhagem Wistar SHIMIZU, SANAE 09 October 2014 (has links) Made available in DSpace on 2014-10-09T12:23:16Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T13:56:08Z (GMT). No. of bitstreams: 1 01036.pdf: 919968 bytes, checksum: 8432333a9ebb3f09ef6cf9cbf84c9622 (MD5) / Dissertacao (Mestrado) / IEA/D / Instituto de Biociencias, Universidade de Sao Paulo - IB/USP aryl radicals benzofurans drugs e. isotopes iodine 131 reaction kinetics biochemical reaction kinetics tracer techniques
4	Salicylic Acid-Catalyzed Radical Arylations from In-situ Formed Arenediazonium Salts Felipe-Blanco, Diego 22 July 2020 (has links) In this thesis, it has been studied the deamination of aromatic amines, through in situ formed diazonium salts as reaction intermediates, catalyzed by salicylic acid, a nontoxic, eco-friendly and economic catalyst. In the early part of the thesis (Chapter I) it has studied the deamination process using THF as solvent as hydrogen donor and anilines as radical source, to carry the hydrodeamination reaction, as well as the process in its deuterodeamination manner using deuterated solvent. Following with this study in Chapter II and Chapter III, it has been studied the addition of the aromatic radicals, generated with the methodology employed in the first chapter, to different types of double bond, to form α-arylketones (Chapter II) and γ-aryl lactones, throw a following intramolecular cyclization (Chapter III). Finally, in Chapter IV was studied the construction of arylphosphonates, starting from anilines as radical source, and triphenylphosphite, and in this case specially, mechanism was hard explored. In every work, the methodologies could be scaled-up above 1 g, reaction mechanisms were proposed and studied through control and mechanistical experiments, and follow reactions were carried out. Aniline Aryl Radical Aryl Radicals Salicylic Acid Radical Reactions Sustainable Chemistry Synthetic Methods Aroamtic Amines Hydrogen Transfer Enol Acetates α-arylketones Diazonium Salts Organophosphorous Hydrocarbon Aromatic Compounds Química Orgánica

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