In an attempt to investigate the cause of change in the competitive ability between monocots and dicots in a pastureland in Farnham, Quebec under CO2 enrichment, I chose to study the response of Plantago major (dicot) and Poa pratensis (monocot) grown in ambient and elevated CO2 chambers, hypothesizing that a large increase in root biomass of dicots would be observed under elevated CO 2. A transient stimulation of root biomass of Plantago major was found during the first month of CO2 exposure but disappeared later. / The second objective of this study was to examine the effect of 5 years of CO2 enrichment both on root biomass and on total C and N content of roots and soil in the pasture. The largest belowground growth was recorded for Taraxacum officinale. Plantago major responded by achieving the highest aboveground growth. / N content of CO2 enriched roots was reduced. This change in the elemental composition of root tissues might negatively affect the process of decomposition and therefore, the nutrient availability to soil microbes and plants. The observed reduction of NO3 in CO2 enriched soil maybe due to greater N immobilization caused by the expected increase in microbial populations.

A climate controlled, dynamic chamber was used to measure carbon dioxide (CO$ sb2$) and methane (CH$ sb4$) exchange on an ombrotrophic peatland. The study periods were July to early November 1995, and early May to July 1996. Five sample sites, showing ecological and hydrological contrast, were investigated. Measurements of Net Ecosystem Exchange showed peak photosynthetic capacity (GP$ sb{ max})$ ranging from 0.52 $ pm$ 0.04 mg C m$ sp{-2}$ s$ sp{-1}$ (June 1996) to 0.03 $ pm$ 0.02 mg C m$ sp{-2}$ s$ sp{-1}$ (early November 1995). Dark respiration measurements ranged from $-$0.21 $ pm$.02 mg C m$ sp{-2}$ s$ sp{-1}$ (June 1996) to $-$0.02 $ pm$.01 mg C m$ sp{-2}$ s$ sp{-1}$ (late May 1996), and showed significant relationships to soil temperature at all sites. Site average methane measurements ranged from 29-72 mg m$ sp{-2}$ d$ sp{-1}$, and showed a strong relationship to water table on a seasonal basis, but a poor correlation to simultaneous NEE. Modelled Net Ecosystem Productivity (NEP) among sites ranged from 17.1 to 115 gC over the entire study period. The CO$ sb2$ exchanges in late spring and early fall made a large contribution to the figure due to the imbalance in the photosynthetic and dark respiration components of the carbon budget. No discernible relationship was found between seasonal NEP and methane release. The results suggest a large importance of the extreme ends of the growing season in an analysis of the carbon budget of peatlands, periods hitherto little investigated. They also suggest that NEP/methane connections may be restricted in their significance to mainly flooded mires.

We examined how fast- and slow-growing families (based on height at 10 years) of Pinus banksiana Lamb. are affected by a climate altered by CO$ sb2$ during their first growing season. Our primary objective was to evaluate the possibility that genotypes performing best under present conditions may not necessarily do best under projected warmer climate. Seedlings were grown for six months in two climatic environments (350 $ mu$L/L CO$ sb2$ x present temperatures and 700 $ mu$L/L CO$ sb2$ x 4$ sp circ$C warmer temperatures) and with 100 ppm and 5 ppm nitrogen. / The CO$ sb2$T$ sp circ$ environment had a significant effect on most biomass components of seedlings and water-use efficiency but not on height and other growth variables. The nitrogen fertilization was generally the most significant effect of the treatments for most growth variables. / All the families responded in a similar way to variations in the growing environments except for WUE. Family differences were more important for measurements of height and growth variables than for biomass components. The architecture of seedlings was also highly variable between families. Norm of reaction graphs were built for several growth variables to outline which families were overall most successful in an enriched CO$ sb2$T$ sp circ$ environment. Of the 15 families studied, four of them were classified as most successful in a projected high CO$ sb2$T$ sp circ$ climate.

Thesis (M.S.)--Ohio University, June, 2008. / Title from PDF t.p. Includes bibliographical references.

Climate change threatens global food security by increasing extreme-weather shocks and reducing the productivity of major global crops. While recent research has highlighted the risk of rising extreme heat, comparatively little is known about how the intensity distribution of rainfall, and rainfall’s interactions with heat, influence global crops. Further, as the broader climate transition gains momentum, the industrial activities needed to mitigate and adapt to climate change will emit CO₂. These emissions remain unquantified and largely ignored in research and policy, and thus present an under-assessed risk to crops and society at large.This thesis advances the understanding of present and future agricultural risks from two aspects of hydroclimatic complexity: hourly rainfall intensity and temperature-moisture (T-M) couplings. Both aspects are expected to shift under climate change, with highly uncertain crop impacts. It further simulates the adaptation and mitigation emissions embedded in the broader climate transition, illuminating a previously under-appreciated benefit of enhance climate ambition. Climate warming is expected to intensify rainfall, decreasing the frequency of drizzle while boosting heavy and extreme events. I show that surprisingly heavy rainfall is optimal for US maize and soy yields, with yield loss due to drizzle and very extreme downpours. As a result, the future concentration of rainfall into fewer, heavier hourly events will benefit crop yields 2-3%, partly offsetting larger damages from warming. T-M couplings arising from land-air interactions and atmospheric circulation may shift under 21st Century warming, altering the likelihood of concurrent heat and drought extremes, with uncertain risks to crops. I demonstrate that maize and soy grown in regions with strong T-M couplings historically suffered enhanced crop sensitivity to heat. These couplings will strengthen over most of global croplands this century, worsening the impact of warming on crops by 5% globally, with large regional variations. The energetic demands of the broader climate transition – such as steel for wind turbines, and concrete for coastal barriers – will initially be satisfied by fossil fuels. I show that simulated mitigation and adaptation will emit 185GtCO₂ by 2100 under a transition path consistent with current policies (~2.7°C warming by 2100), equivalent to half the remaining carbon budget for 1.5°C. However, these emissions can be reduced by 90% under a 1.5°C transition path, a previously unidentified co-benefit of enhanced climate ambition.

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Atmospheric carbon dioxide (CO₂) concentrations have increased rapidly in recent decades due to the burning of fossil fuels, deforestation, and other industrial practices. The excessive accumulation of CO₂ in the atmosphere leads to global warming, ocean acidification, and other environmental imbalances, which may ultimately have wider societal implications. One potential solution to closing the carbon cycle is utilizing CO₂, rather than fossil fuels, as the carbon source for fuels and chemicals production. This lowers atmospheric CO₂ levels while simultaneously providing an economic incentive for capturing and converting CO₂ into more valuable products. This dissertation includes studies on three hybrid catalytic reactor systems coupling electrochemistry, thermochemistry, and plasma chemistry for the conversion of CO₂ into value-added oxygenates, such as methanol and C3 oxygenates (propanal and 1-propanol). First, a tandem two-stage system is described where CO₂ is electrochemically reduced into syngas followed by the thermochemical methanol synthesis reaction. The work here specifically focuses on the electrochemical CO₂ reduction reaction to produce syngas with tunable H₂/CO ratios. Using a combination of electrochemical experiments, in-situ characterization, and density functional theory calculations, palladium-, gold-, and silver-modified transition metal carbides and nitrides were found to be promising catalysts for enhancing electrochemical activity while reducing the overall precious metal loading. Second, another tandem two-stage system is demonstrated where CO₂ is electrochemically reduced into ethylene and syngas followed by the thermochemical hydroformylation reaction to produce propanal and 1-propanol. The CO₂ electrolyzer was evaluated with Cu catalysts containing different oxidation states and with modifications to the gas diffusion layer hydrophobicity, while the hydroformylation reactor was tested over a Rh₁Co₃/MCM-41 catalyst. The tandem configuration achieved a C₃ oxygenate selectivity of ~18%, representing over a 4-fold improvement compared to direct electrochemical CO₂ conversion to 1-propanol in flow cells. Third, a hybrid plasma-catalytic system is investigated where CO₂ and ethane are directly converted into multi-carbon oxygenates in a one-step process under ambient conditions. Oxygenate selectivity was enhanced at lower plasma powers and higher CO₂ to C₂H₆ ratios, and the addition of a Rh₁Co₃/MCM-41 catalyst increased the oxygenate selectivity at early timescales. Plasma chemical kinetic modeling, isotopically-labeled CO₂ experiments, and in-situ spectroscopy were also used to probe the reaction pathways, revealing that alcohol formation occurred via the oxidation of ethane-derived activated species rather than a CO₂ hydrogenation pathway. It is critical to assess whether the proposed CO₂ conversion strategies consume more CO₂ than they emit. A comparative analysis of the energy costs and net CO₂ emissions is conducted for various reaction schemes, including four hybrid pathways (thermocatalytic-thermocatalytic, plasma-thermocatalytic, electrocatalytic-thermocatalytic, and electrocatalytic-electrocatalytic) for converting CO₂ into C₃ oxygenates. The hybrid processes can achieve a net reduction in CO₂ provided that low-carbon energy sources are used, however further catalyst improvements and engineering optimizations are necessary. Hybrid catalytic systems can provide an alternative approach to traditional processes, and these concepts can be extended to other chemical reactions and products, thereby opening new opportunities for innovative CO₂ utilization technologies.

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