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Increased development in Canadas northern environments has increased the need for accurate methods to detect adverse impacts on tundra ecosystems. Ammonium nitrate is a common water pollutant associated with many industrial and municipal activities, including diamond mining, and is of special concern due to the toxicity of ammonia in aquatic systems. One solution to reduce exposure of sensitive aquatic systems to nitrogenous compounds is to atomize (atmospherically disperse in fine particles) contaminated water over the arctic tundra which will reduce N loading to surface water. However, the toxicity of ammonium nitrate to arctic soils is poorly understood. In this study I investigate the potential toxicity of ammonium nitrate solutions to arctic soil functions such as carbon mineralization, nitrification and plant growth, to determine concentrations that can be applied without causing significant inhibition to these processes. <p>Arctic ecosystems are based on a soil type termed a cryosol that has an underlying permafrost layer. Often these soils are subject to cryoturbation, a process which heaves and mixes the soil, bringing the mineral horizons to the surface. I hypothesized that phytotoxicity test results in arctic soils would be highly variable compared to other terrestrial ecosystems due to the cryoturbation process and subsequent range of soil characteristics. The variability associated with phytotoxicity tests was evaluated using Environment Canadas standardized plant toxicity test in three cryoturbated soils from Canadas arctic exposed to a reference toxicant, boric acid. The phytotoxicity of boric acid to northern wheatgrass (<i>Elymus lanceolatus </i>) in cryosols was much greater than commonly reported in other soils, with less than 150 ug boric acid g-1 soil needed to inhibit root and shoot growth by 20%. There was also large variability in the phytotoxicity test results, with coefficients of variation for 10 samples ranging from 160 to 79%. Due to this variability in cryoturbated arctic soils, more than 30 samples should be collected from each control and potentially impacted area to accurately assess contaminant effects, and ensure that false negatives of toxicant impacts in arctic soils are minimized. <p>To characterize the toxicity of ammonium nitrate I exposed a variety of arctic soils and a temperate soil to different concentrations of ammonium nitrate solution over a 90 day time period. Dose responses of carbon mineralization, nitrification and phytotoxicity test parameters were estimated for ammonium nitrate applications. In addition to direct toxicity, the effect of ammonium nitrate on ecosystem resistance was investigated by dosing nitrogen impacted soils with boric acid. Ammonium nitrate solutions had no effect on carbon mineralization activity, and affected nitrification rates in only one soil, a polar desert soil from Cornwallis Island. In contrast, ammonium nitrate applications (43 mmol N L-1 soil water) significantly impaired seedling emergence, root length and shoot length of northern wheatgrass. Concentrations of ammonium nitrate in soil water that inhibited plant parameters by 20% varied between 43 to 280 mmol N L-1 soil water, which corresponds with 2,100 to 15,801 mg L-1 in the application water. Arctic soils were more resistant to ammonium nitrate toxicity than the temperate soil under these study conditions. However, it is not clear if this represents a general trend for all polar soils, and because nitrogen is an essential macro-nutrient, nitrogenous toxicity should likely be considered a special case for soil toxicity. As soil concentrations could be maintained under inhibitory levels with continual application of low concentrations of ammonium nitrate over the growing season, atomization of wastewater contaminated with ammonium nitrate is a promising technology for mitigation of nitrogen pollution in polar environments. <p>Increased development in Canadas northern environments has increased the need for accurate methods to detect adverse impacts on tundra ecosystems. Ammonium nitrate is a common water pollutant associated with many industrial and municipal activities, including diamond mining, and is of special concern due to the toxicity of ammonia in aquatic systems. One solution to reduce exposure of sensitive aquatic systems to nitrogenous compounds is to atomize (atmospherically disperse in fine particles) contaminated water over the arctic tundra which will reduce N loading to surface water. However, the toxicity of ammonium nitrate to arctic soils is poorly understood. In this study I investigate the potential toxicity of ammonium nitrate solutions to arctic soil functions such as carbon mineralization, nitrification and plant growth, to determine concentrations that can be applied without causing significant inhibition to these processes. <p>Arctic ecosystems are based on a soil type termed a cryosol that has an underlying permafrost layer. Often these soils are subject to cryoturbation, a process which heaves and mixes the soil, bringing the mineral horizons to the surface. I hypothesized that phytotoxicity test results in arctic soils would be highly variable compared to other terrestrial ecosystems due to the cryoturbation process and subsequent range of soil characteristics. The variability associated with phytotoxicity tests was evaluated using Environment Canadas standardized plant toxicity test in three cryoturbated soils from Canadas arctic exposed to a reference toxicant, boric acid. The phytotoxicity of boric acid to northern wheatgrass (<i>Elymus lanceolatus </i>) in cryosols was much greater than commonly reported in other soils, with less than 150 ug boric acid g-1 soil needed to inhibit root and shoot growth by 20%. There was also large variability in the phytotoxicity test results, with coefficients of variation for 10 samples ranging from 160 to 79%. Due to this variability in cryoturbated arctic soils, more than 30 samples should be collected from each control and potentially impacted area to accurately assess contaminant effects, and ensure that false negatives of toxicant impacts in arctic soils are minimized. <p>To characterize the toxicity of ammonium nitrate I exposed a variety of arctic soils and a temperate soil to different concentrations of ammonium nitrate solution over a 90 day time period. Dose responses of carbon mineralization, nitrification and phytotoxicity test parameters were estimated for ammonium nitrate applications. In addition to direct toxicity, the effect of ammonium nitrate on ecosystem resistance was investigated by dosing nitrogen impacted soils with boric acid. Ammonium nitrate solutions had no effect on carbon mineralization activity, and affected nitrification rates in only one soil, a polar desert soil from Cornwallis Island. In contrast, ammonium nitrate applications (43 mmol N L-1 soil water) significantly impaired seedling emergence, root length and shoot length of northern wheatgrass. Concentrations of ammonium nitrate in soil water that inhibited plant parameters by 20% varied between 43 to 280 mmol N L-1 soil water, which corresponds with 2,100 to 15,801 mg L-1 in the application water. Arctic soils were more resistant to ammonium nitrate toxicity than the temperate soil under these study conditions. However, it is not clear if this represents a general trend for all polar soils, and because nitrogen is an essential macro-nutrient, nitrogenous toxicity should likely be considered a special case for soil toxicity. As soil concentrations could be maintained under inhibitory levels with continual application of low concentrations of ammonium nitrate over the growing season, atomization of wastewater contaminated with ammonium nitrate is a promising technology for mitigation of nitrogen pollution in polar environments.

Interpersonal transport of expiratory droplets and droplet nuclei constitutes a prerequisite for the transmission of pathogens as well as the transmission of respiratory diseases. This study modeled the physical process of interpersonal transport of droplets and droplet nuclei in a ventilated room. The impacts of a number of parameters in three length scales and three corresponding physical processes were analyzed, including dispersion and evaporation of droplets/droplet nuclei at 1 to 100 μm, human exhalation flows and body plumes at 0.1 to 1 m, and the indoor environment at 1 to 10 m. The strong hygroscopicity of the solutes in the droplet is capable of keeping the droplet with an equilibrium size in humid air, larger than that of a dried particle. Mathematical models were developed to predict the droplet nucleus size in both dry air and humid air, by simplifying the composition of one expiratory droplet to NaCl solution and suspended spherical particles. For a droplet with an initial diameter of 100 μm, initial NaCl concentration of 0.9%, and initial solids ratio of 1.8%, the droplet nucleus size was estimated to be 42 μm in an ambient relative humidity of 90% (25°C), which is 30% larger than it was in a relative humidity of 30% (25°C). A numerical model was also developed to predict droplet evaporation and dispersion in a constant turbulent buoyant jet. Droplets with initial sizes larger than 80 μm were predicted to deposit on the floor at a distance of ~1.25 m (~1.7 m for 60 μm) away from the mouth, while droplets with initial sizes less than 40 μm travelled to the end of the jet. A series of experiments was conducted to assess the characteristics of human exhalation airflows and thermal plume, using a full-scale test room and a breathing thermal manikin. The impacts of the ventilation system were illustrated by comparing the velocity distribution of the exhalation airflows and airflows induced by thermal plume. Further experiments employing two breathing thermal manikins were carried out to evaluate the interpersonal transport of the expiratory contaminants that were simulated by tracer gas. When the two manikins with the same heights were standing face to face at a mutual distance of 0.8 m, the exhalation airflows from the mouth of the source manikin could directly travel into the breathing region of the susceptible manikin, resulting in a high exposure. The high exposure decreased sharply with an increase in the mutual distance from 0.5 m to 1.0 m. Between 1.0 m to 3.0 m, the exposure by the susceptible manikin remained at a low and constant level. Numerical simulations considering droplet evaporation and droplet nucleus sizes were carried out; and the impacts of the parameters of droplet initial size, humidity, vicinity, ventilation conditions and synchronization of exhalation were evaluated. Fine droplets and droplet nuclei were predicted to travel toward the upper part of the test room, whereas large droplets tend to be deposited on the floor. With a high relative humidity, 95%, most of the droplets were deposited on the floor within 16 seconds. Meanwhile, all of the droplets evaporated to droplet nuclei and remained suspended in the air when the relative humidity was 35%. Mixing ventilation that supplied fresh air with a ventilation rate of 5.6 h-1 resulted in drafts and strong turbulence, which made droplets and droplet nuclei dispersed in the room. The average vertical position was higher than that when the ventilation rate was 3.0 h-1. Displacement ventilation led to the vertical temperature stratification in the room. The vertical temperature gradient could neutralize the buoyancy force and weaken body plumes and the vertical dispersion of droplets and droplet nuclei. The inhalation of the droplets and droplet nuclei by the susceptible person and the deposition of the droplets and droplet nuclei on the body surface of the susceptible person were investigated at mutual distances of 0.5, 1.0, 1.5 and 3.0 m. For one breath from the source person, 1,600 droplets were released. Three and 9 droplet nuclei were inhaled by the susceptible person at a mutual distance of 0.5 and 1.0 m, respectively. No droplet nuclei were inhaled at 1.5 and 3.0 m. / published_or_final_version / Mechanical Engineering / Doctoral / Doctor of Philosophy

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abstract: This dissertation describes a process for interface capturing via an arbitrary-order, nearly quadrature free, discontinuous Galerkin (DG) scheme for the conservative level set method (Olsson et al., 2005, 2008). The DG numerical method is utilized to solve both advection and reinitialization, and executed on a refined level set grid (Herrmann, 2008) for effective use of processing power. Computation is executed in parallel utilizing both CPU and GPU architectures to make the method feasible at high order. Finally, a sparse data structure is implemented to take full advantage of parallelism on the GPU, where performance relies on well-managed memory operations. With solution variables projected into a kth order polynomial basis, a k+1 order convergence rate is found for both advection and reinitialization tests using the method of manufactured solutions. Other standard test cases, such as Zalesak's disk and deformation of columns and spheres in periodic vortices are also performed, showing several orders of magnitude improvement over traditional WENO level set methods. These tests also show the impact of reinitialization, which often increases shape and volume errors as a result of level set scalar trapping by normal vectors calculated from the local level set field. Accelerating advection via GPU hardware is found to provide a 30x speedup factor comparing a 2.0GHz Intel Xeon E5-2620 CPU in serial vs. a Nvidia Tesla K20 GPU, with speedup factors increasing with polynomial degree until shared memory is filled. A similar algorithm is implemented for reinitialization, which relies on heavier use of shared and global memory and as a result fills them more quickly and produces smaller speedups of 18x. / Dissertation/Thesis / Doctoral Dissertation Aerospace Engineering 2015

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abstract: A new theoretical model was developed utilizing energy conservation methods in order to determine the fully-atomized cross-sectional Sauter mean diameters of pressure-swirl atomizers. A detailed boundary-layer assessment led to the development of a new viscous dissipation model for droplets in the spray. Integral momentum methods were also used to determine the complete velocity history of the droplets and entrained gas in the spray. The model was extensively validated through comparison with experiment and it was found that the model could predict the correct droplet size with high accuracy for a wide range of operating conditions. Based on detailed analysis, it was found that the energy model has a tendency to overestimate the droplet diameters for very low injection velocities, Weber numbers, and cone angles. A full parametric study was also performed in order to unveil some underlying behavior of pressure-swirl atomizers. It was found that at high injection velocities, the kinetic energy in the spray is significantly larger than the surface tension energy, therefore, efforts into improving atomization quality by changing the liquid's surface tension may not be the most productive. From the parametric studies it was also shown how the Sauter mean diameter and entrained velocities vary with increasing ambient gas density. Overall, the present energy model has the potential to provide quick and reasonably accurate solutions for a wide range of operating conditions enabling the user to determine how different injection parameters affect the spray quality. / Dissertation/Thesis / M.S. Aerospace Engineering 2013

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The aim of the present work was to experimentally investigate the influence of atomizing medium on combustion properties of methyl-ester of rapeseed oil. The experiments were carried out in a water-cooled horizontal combustion chamber. The pneumatic atomization using effervescent atomizer was used in test. As atomizing medium compressed air and superheated steam was chosen. The tests were performed at GLR = 15, 20 and 25 %. The experiments were focused on the investigation of the flame characteristics, quality of combustion, emissions, temperature of flue gas, distribution of heat fluxes and stability of combustion. Results revealed that atomization by compressed air is more efficient (approximately by 6 %), on the other hand it leads to higher NO emissions (for 15 mg/mN3 due to higher in-flame temperature).