The objective of this research was to derive an empirical equation that estimates the acoustical shadow zone length (SZL) of roadway noise barriers. The acoustical shadow zone is the area behind a noise barrier of reduced sound levels, generally to some stated level at or near background. The ability to predict the SZL can be used as a method to evaluate the performance, and possibly the design, of roadway noise barriers. The current federally required roadway noise model is the Federal Highway Administration (FHWA) Traffic Noise Model (TNM). TNM uses insertion loss (IL) to evaluate the effectiveness of a barrier. Insertion loss is the difference in sound level between the "no barrier" and the "with barrier" case. One major limitation with TNM is that the reported IL does not take into account how background noise levels influence the mitigated sound levels. Background noise can be defined as the noise present at a barrier location in the absence of roadway noise. The shadow zone represents a region behind the noise barrier where the barrier is effective at reducing noise levels and takes into account how background noise affects the IL and thus the SZL. The inclusion of background noise becomes significant in evaluating barrier effectiveness because as the distance from the barrier increases, background noise begins to overtake roadway noise as the dominate noise source. The derivation of the empirical equation began by collecting in-situ noise measurements at 18 noise barrier locations across Florida. The measured noise data was supplemented by noise data obtained from computer modeling. After a sufficient quantity of measured and modeled IL data was obtained, a contour of equal IL (IL = 5 dB) was plotted for each barrier location. The area defined by the contour is called the shadow zone. All the SZLs were statistically compared to several variables that were expected to influence it. Regression modeling showed that the background noise level, noise barrier height, the distance from the roadway to the noise barrier, and percent of heavy truck traffic volume were statistically significant as useful predictors of SZL. Two empirical equations were derived, one from linear regression and one from polynomial regression, and are referred to as the Shadow Zone Equations.

In a vast majority of cases, seepage barriers increase the reliability of dams. However, it is important to recognize that seepage barriers often drastically increase hydraulic gradients around the boundaries of the barrier, and through any windows or defects in the barrier. The result is increased water pressures and hydraulic gradients behind and around the barrier. These increased pressures and gradients have potential to provide the catalyst for initiation of several modes of internal erosion that were either unlikely or less likely without the seepage barrier. As a consequence, seepage barriers give rise to the potential for additional mechanisms of internal erosion and piping in the dam and the foundation. Mechanisms of erosion and piping that are uniquely related to seepage barriers have been investigated through review of measured performance of existing dams, and through analytical studies. A compendium of 30 case studies of dams that have had seepage barriers in place for over 10 years has been assembled, and observations and insights garnered from these case studies were compiled. Finite element seepage and deformation analyses have been performed to provide better understanding of the performance of seepage barriers and the mechanisms that affect their performance. Based on the findings from the case studies and analyses, potential failure modes specific to dams with seepage barriers were identified, and the sequences of events required for the propagation of these failure modes were developed. The observations and insights acquired in this study were distilled into conclusions regarding the long-term performance of dams with seepage barriers. The information derived from this study will be useful in 1) assessing the potential for internal erosion and piping developing in dams with seepage barriers, 2) designing to minimize that possibility, and 3) assessing the risks associated with these mechanisms of erosion and piping. It is envisioned that the results of this study will provide dam owners and engineers with a better understanding of the issues involved with dams having seepage barriers and that this understanding will lead to improved practices in assessing, designing, and monitoring of dam seepage barriers. In addition, by improving the means by which seepage barriers can be assessed and designed, it is hoped that the confidence level that dam engineers have with regard to properly designed seepage barriers will be increased, and that properly designed seepage barriers can be viewed as safe and viable alternatives for mitigation of seepage problems. / Ph. D.

High-voltage SiC Schottky barrier diodes have been fabricated with 1mm square contacts. The SBD?s were fabricated using both an argon implant and a field plate overlap for edge termination. The current-voltage characterization of the diodes is presented with statistical yield information on the first set of diodes produced from the Mississippi Center for Advanced Semiconductor Prototyping. After packaging, reverse bias breakdown voltages over 500V at 0.1 A/cm2 and an on-state forward voltage drop of less than 2.5V at 100 A/cm2 were demonstrated. A 0.65-0.85 eV barrier height was extracted from the SBD?s using I-V measurements. Field plate terminated devices demonstrated consistent, low standard deviation breakdown voltages and low leakage currents. The argon implanted devices demonstrated a higher breakdown voltage with higher leakage currents and a higher standard deviation. It was proven that the diodes followed the thermionic field emission model for up to one third of the breakdown voltage. Over 15,000 diodes have been tested and results analyzed in this work.

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In this thesis, first we propose a new approach to solve Semi Infinite Linear Optimization Problems (SILP). The new algorithm uses the idea of adding violated cut or cuts at each iteration. Our proposed algorithm distinguishes itself from Luo, Roos, and Terlaky's logarithmic barrier decomposition method, in three aspects: First, the violated cuts are added at their original locations. Second, we extend the analysis to the case where multiple violated cuts are added simultaneously, instead of adding only one constraint at a time. Finally, at each iteration we update the barrier parameter and the feasible set in the same step. In terms of complexity, we also show that a good approximation of an optimal solution will be guaranteed after finite number of iterations. Our focus in this thesis is mainly on the implementation of our algorithm to approximate an optimal solution of the SILP. Our numerical experiences show that unlike other SILP solvers which are suffering from the lack of accuracy, our algorithm can reach high accuracy in a competitive time. We discuss the linear algebra involved in efficient implementation and describe the software that was developed. Our test problem set includes large scale second order conic optimization problems. / Thesis / Master of Applied Science (MASc)

No / Recent progress in the development of European standards has allowed the in situ testing of roadside noise barriers. CEN/TS 1793-5 describes a test method using maximum length sequences (MLS) for the characterisation of airborne sound insulation. However, many barriers are tested according to a laboratory standard, EN 1793-2, based on measurements carried out in reverberant chambers and in the case of timber barriers with a relatively low airborne sound insulation it is not clear to what extent the results of the two tests compare. The paper describes the results of tests carried out using both methods. Six samples of timber barrier were compared including single-leaf and double-leaf constructions and single-leaf constructions with an absorptive core. Very good agreement was found especially when account was taken of the valid frequency range in each test method. The results open up the possibility of routinely evaluating the performance of timber barriers at the roadside where build quality can be variable and there are concerns that the acoustic performance may not match that obtained under laboratory test conditions where typically the barrier is more carefully constructed.

Yes / The in situ measurement of the airborne sound insulation, as outlined in EN 1793-6:2012, is becoming a common means of quantifying the performance of road traffic noise reducing devices. Newly installed products can be tested to reveal any construction defects and periodic testing can help to identify long term weaknesses in a design. The method permits measurements to be conducted in the presence of background noise from traffic, through the use of impulse response measurement techniques, and is sensitive to sound leakage. Factors influencing the measured airborne sound insulation are discussed, with reference to measurements conducted on a range of traffic noise barriers located around Auckland, New Zealand. These include the influence of sound leakage in the form of hidden defects and visible air gaps, signal-to-noise ratio, and noise barrier height. The measurement results are found to be influenced by the presence of hidden defects and small air gaps, with larger air gaps making the choice of measurement position critical. A signal-to-noise ratio calculation method is proposed, and is used to show how the calculated airborne sound insulation varies with signal-to-noise ratio. It is shown that the measurement results are influenced by barrier height, through the need for reduced length Adrienne temporal windows to remove the diffraction components, prohibiting the direct comparison of results from noise barriers with differing heights. / The authors would like to thank the NZ Transport Agency for sponsoring the Auckland traffic noise barrier testing work, and the Auckland Motorway Alliance for assisting with access to the test sites.

The objective of this study was to determine if the method of incorporation of a silicate layered nanoclay into a polymer matrix can affect the barrier properties of the pristine polymer in order to decrease the transport of volatile organic compounds (VOC) in indoor air. Building materials are a primary source for VOCs. These emissions are a probable cause of acute health effects and discomfort among occupants and are known to diminish productivity. The predicted concentrations of several of the VOCs emitted by structural insulated panels (SIP) are of concern with respect to health and comfort of occupants. The main issue related to the barrier membranes is the dispersion properties of the nanoclays in the polymer matrix, and the generation of a tortuous pathway that will decrease gas permeation. The tortuous pathway is created by a nanoclay filler, whose ideal exfoliated structure has high surface area, and high aspect ratio. By choosing the appropriate surfactants, the nanoclays can be modified to allow improved molecular interactions between the nanoclay and the polymer matrix. Several studies were performed in order to evaluate the dispersion properties of the nanoclay in the polymer matrix. Polymer/clay nanocomposites barrier membranes were generated via different synthesis methods. In the first study, barrier membranes were composed of a polyurethane, Estane ® 58315, and different nanoclays, Cloisite ® 10A, Cloisite ® 20A, Cloisite ® 30B. The interaction of the polyurethane and the different surfactants used to organically modify the nanoclay was evaluated. The dispersion of the clay platelets was analyzed by varying the pre-processing method; sonication vs stirring. The decrease in gas permeability results was enhanced by the effect of pre-processing via sonciation in comparison to plain stirring. These results also suggest that nanoclay platelets modified with alkylammonium groups with one tallow tail Cloisite ® 10A and Cloisite ® 30B, allow better dispersion and penetration of the polymer within the basal spacing of the nanoclays. Once the decrease in gas permeability was confirmed, the next challenge was to study and evaluate the performance of the polyurethane/clay nanocomposites barrier membranes in the determination of diffusivity coefficients for volatile organic compounds (VOCs). This was achieved via gravimetric sorption characterization. This method allowed for characterization of the sorption and desorption phenomena of VOC in barrier membranes. Barrier membranes pretreated with sonication demonstrated lower diffusivity coefficients than those only treated with stirring. At high clay loadings, 50 wt% of nanoclay in the polymer, the decrease in diffusivity coefficients for VOCs such as butanol and toluene, was found to be one order of magnitude. Other VOCs such as decane and tetradecane also showed a significant decrease in diffusivity coefficient. The results for VOC sorption studies suggest that there is some variability. In order to enhance the exfoliation of the clay, we decided to examine in situ polymerization of poly (n-butyl methacrylate) in the presence of nanoclay. In this study the clay wt% was kept at a low concentration of 1-5 wt%. The surface modification of natural montmorillonite, Cloisite ® Na+, was achieved via ion exchange, and the effect of pre-processing was also explored. The modification rendered a tethered group on the surface of the clay that was able to react with the monomer/oligomer chains and thus expand and exfoliate the clay platelets. Gas permeation data suggest that sonication also produced better barrier properties than its counterpart stirring. XRD diffractograms also confirmed exfoliation of the clay platelets in the poly (n-butyl methacrylate) polymer matrix. Thermogravimetric analysis (TGA) suggested that exfoliation of the clay platelets led to improved thermal stability by increasing the decomposition temperature of the membranes. A small increase in Tg also suggested restricted segmental chain motion within the clay platelets. Overall gas permeation decreased even at low clay content. Phenomenological models such as those of Cussler and Nielsen were used to model the experimental permeation results. These models suggest that although the aspect ratio of the clay platelets is within the specifications provided by the manufacturer, it does not reflect the ideal behavior of the models. The last step of this work was to achieve exfoliation of the modified nanoclay platelets via emulsion polymerization of poly (n-butyl methacrylate). The clay concentration in the emulsion was kept the same as in the in situ polymerization. DLS results suggest a uniform distribution of the polymer/clay nanocomposites particles in the emulsion. Permeation data indicated higher permeation values than the in situ method of synthesis of the nanocomposite membranes. This led us to explore the use of glassy co-polymer of poly(n-butyl methacrylate)-poly(methyl methacrylate) as the matrix. The addition of a more glassy component in the polymer matrix led to improved barrier properties of the nanocomposite membranes. As expected, the copolymer had a higher Tg than the PMMA polymer. Analysis via phenomenological models, also suggested that the chemistry of the co-polymer played an important role in decreasing gas permeability within the polymer/clay nanocomposite membranes, although the effect of the glassy component in the matrix was not quantified by the phenomenological models. / Ph. D.

Airborne microorganisms, such as bacteria, viruses and fungi, are abundant in the natural and built environments. This research encompasses two studies on virus aerosolization and transport in the built environment and the subsequent implications for human health. In the first study, we quantified the impact of a barrier on the spatial distribution of different-sized particles released by speaking in a poorly ventilated room. The room was outfitted with 108 passive sampling sites. The barrier resulted in an increase in 0.5 µm particles deposited on the source-side of the barrier and an increase in 0.5 µm particles at other locations 4-6 m from the source. The barrier had minor impacts on the distribution of 1, 6, 10 and 20 µm particles. The results from this study indicated that barriers may not serve as adequate protection to others in the room, depending on their locations relative to the barrier and the timescale of exposure. In the second study, we reviewed the applications of next-generation sequencing for viruses in water environments. We also characterized the occurrence of two viruses (crAssphage and SARS-CoV-2) from a local wastewater treatment plant (WWTP) in both water and air samples at two locations within the WWTP (influent and aeration basin). We found that crAssphage, a fecal indicator, was quantifiable in most air and water samples, but was not detected in control samples. SARS-CoV-2 N2 RNA was detected in a fraction of the water and air samples but was present in the control water samples, so results for this virus are confounded by laboratory contamination. We also found that there was no correlation between airborne and waterborne SARS-CoV-2 concentrations at the WWTP. A quantitative microbial risk assessment model was constructed to determine inhalation risks associated with airborne SARS-CoV-2 for WWTP operators. The probability of infection ranged from about 2.4 x 10-4 to 5.6 x 10-8 and was heavily dependent on exposure time, airborne concentration and other parameters. / Doctor of Philosophy / Airborne microorganisms, such as bacteria, viruses and fungi, are abundant in the natural and built environments. This research encompassed two studies that evaluated the impact of viruses in the built environment on public health. The first study investigated whether a barrier, like Plexiglas, could protect people from another person's exhaled particles in a poorly ventilated room. The barrier resulted in an increase in the smallest particles (0.5 µm) on the same side of the barrier as the source and an increase in these particles at other locations 4-6 m from the source, indicating that individual exposure depends on their location relative to the barrier. The barrier had minor impacts on larger particles (1, 6, 10, and 20 µm). The second study focused on viruses at wastewater treatment plants (WWTPs). As part of this study, we reviewed how one can use knowledge about the DNA and RNA of viruses in water and wastewater. We also measured the amount of two viruses (crAssphage and SARS-CoV-2) in wastewater and in air surrounding the WWTP. We detected crAssphage, a virus that infects bacteria and a marker for human activity, in most wastewater and air samples. We also detected SARS-CoV-2 in some wastewater and air samples, but this virus was also present in some control samples, so laboratory contamination was an issue. Using the concentrations of airborne SARS-CoV-2, we constructed a computational model to estimate the risk of infection for SARS-CoV-2 inhalation for WWTP employees. Our calculations indicated that the risk of infection ranged from 2.4 x 10-4 to 5.6 x 10-8 and heavily depended on parameters such as exposure time and airborne SARS-CoV-2 concentrations.