In the present work, novel dewatering aids and a novel centrifuge configuration were developed and applied for the purpose of dewatering fine particles. Three different types dewatering reagents were tested in different filtration and centrifugation units. These chemicals included low-HLB surfactants, naturally occurring lipids, and modified lipids. Most of these reagents are insoluble in water; therefore, they were used in solutions of appropriate solvents, such as light hydrocarbon oils and short-chain alcohols. The role of these reagents was to increase the hydrophobicity of the coal and selected mineral particles (chalcopyrite, sphalerite, galena, talc, clay, phosphate, PCC and silica) for the dewatering. In the presence of these reagents, the water contact angles on the coal samples were increased up to 90o. According to the Laplace equation, an increase in contact angle with the surfactant addition should decrease the capillary pressure in a filter cake, which should in turn increase the rate of dewatering and help reduce the cake moisture. The use of the novel dewatering aids causes a decrease in the surface tension of water and an increase in the porosity of the cake, both of which also contribute to improved dewatering. A series of batch-scale dewatering tests were conducted on a variety of the coal and mineral samples using the novel dewatering aids. The results obtained with a Buchner funnel and air pressure filters showed that cake moistures could be reduced substantially, the extent of which depends on the particle size, cake thickness, drying time, reagent dosage, conditioning time, reagent type, sample aging, water chemistry, etc. It was determined that use of the novel dewatering aids could reduce the cake formation time by a significant degree due to the increased kinetics of dewatering. At the same time, the use of the dewatering aids reduced the cake moistures by allowing the water trapped in smaller capillaries of the filter cake. It was found that final cake moistures could be reduced by 50% of what can be normally achieved without using the reagents. However, the moisture reduction becomes difficult with increasing cake thickness. This problem can be minimized by applying a mechanical vibration to the cake, spraying a short-chain alcohol on the cake and by adding a small amount of an appropriate coagulant, such as alum and CaCl2 to the coal and mineral slurries. The novel dewatering aids were also tested using several different continuous filters, including a drum filter, disc filter and horizontal belt filter (HBF). The results obtained with these continuous filtration devices were consistent with those obtained from the batch filters. Depending on the coal and mineral samples and the type of the reagent, 40 to 60% reductions in moisture were readily achieved. When using vacuum disc filters, the cake thickness increased substantially in the presence of the novel dewatering aids, which could be attributed to the increased kinetics of dewatering. A dual vacuum system was developed in the present work in order to be able to control the cake thickness, which was necessary to achieve lower cake moistures. It was based on using a lower vacuum pressure during the cake formation time, while a full vacuum pressure was used during the drying cycle time. Thus, use of the dual vacuum system allowed the disc filter to be used in conjunction with the novel dewatering aids. Its performance was similar to that of HBF, which is designed to control cake thickness and cake formation time independently. The effectiveness of using the novel dewatering aids were also tested in a full-continuous pilot plant, in which coal samples were cleaned by a flotation column before the flotation product was subjected to the disc filter. The tests were conducted with and without using novel dewatering aids. These results were consistent with those obtained from the laboratory and batch-scale tests. The novel centrifuge developed in the present work was a unit, which combined a gravity force and air pressure. The new centrifuge was based on increasing the pressure drop across the filter cake formed on the surface of the medium (centrifuge wall). This provision made it possible to take advantage of Darcy s law and improve the removal of capillary water, which should help lower the cake moisture. A series of tests were conducted on several fine coal and mineral particles and obtained more than 50% moisture reduction even at very fine particle size (2 mm x 0). Based on the test results obtained in the present work, two proof-of-concept (POC) plants have been designed. The first was for the recovery of cyclone overflows that are currently being discarded in Virginia, and the other was for the recovery of fines from a pond in southern West Virginia. The former was designed based on the results of the plant tests conducted in the present work. Cost vs. benefit analyses were conducted on the two POC plants. The results showed very favorable internal rates of return when using the novel dewatering aids. Surface chemistry studies were conducted on the coal samples based on the results obtained in the present investigation. These consisted mainly of the surface characterization of the coal samples (surface mineral composition, surface area, zeta potential, x-ray photoelectron microscopy (XPS)), acid-base interactions of the solids and liquids, dewatering kinetic tests, contact angle measurements of the coal samples and surface force measurements using AFM. In addition, carbon coating on a silica plate using palsed laser deposition (PLD) and Langmuir-Blodgett (LB) film deposition tests were conducted on the sample to better understand the surfactant adsorption and dewatering processes. The test results showed that the moisture reductions on the fine particles agree well with the surface chemistry results. / Ph. D.

L'elemento che distingue un'operazione di cartolarizzazione consiste, secondo la definizione espressa nell'accordo di Basilea2, nell'identificazione di almeno due differenti posizioni di rischio (tranche), stratificate e subordinate, emesse a fronte di uno specifico portafoglio di attività. Nonostante il ricorso al tranching sia ampiamente diffuso e standardizzato le determinanti che giustificano il ricorso all'emissione multi-tranche sono ad oggi poco approfondite. Inoltre, i titoli emessi a fronte di operazioni di cartolarizzazione (CDO) possiedono profili di esposizione al rischio di credito differenziati, in termini di incidenza delle perdite attese ed inattese, ed in termini di correlazione con altri fattori di rischio: la valutazione del profilo di rischio è condizione necessaria per l'attribuzione di un giudizio di rating e per la definizione di un appropriato premio al rischio (pricing). Si rivela necessaria tanto la stima della distribuzione delle perdite del portafoglio (credit risk modelling) quanto l'analisi strutturale dei flussi di cassa generati e l'allocazione degli stessi alle tranche (cash flow modelling). Sulla base della letteratura di security design la tesi intende valutare l'efficienza del processo di intermediazione basato sulla cartolarizzazione multi-tranche rispetto all'intermediazione bancaria tradizionale e a forme di asset-backed security con unica tranche e focalizza l'analisi attraverso una verifica empirica delle teorie economiche a supporto del tranching, con particolare riferimento alla cartolarizzazione dei prestiti concessi ad imprese di piccola e media dimensione, oggetto di analisi specifica condotta nell'ambito di un'esperienza di stage presso il Fondo europeo degli investimenti. Quindi, grazie alla realizzazione di un modello computazionale sviluppato con un software di pianificazione finanziaria multidimensionale (Quantrix), la tesi presenta un approfondimento delle technicalities, mediante una modellizzazione dei flussi e della loro allocazione (Waterfall Payment Order), allo scopo di apprezzare il valore aggiunto di queste strutture di intermediazione. Aspetto, questo, non sviluppato nella letteratura accademica. L'analisi si rivolge alle operazioni realizzate nell'ambito dei due principali programmi di cartolarizzazione dei prestiti alle PMI attuati in Europa (Ftpyme e Promise). / Securitisation is a structured finance instrument which involves pooling of financial assets (such as loans and bonds) and creating multiple tranched liabilities, collateralized debt obligation (CDO), of a single issuer with different risk-return characteristics, which are sold as separate securities. According to the New Basel Capital Accord, tranching is the key feature that distinguishes securitisation transactions; although commonly applied, the factors that determine the extent and the nature of tranching remain largely unknown. Moreover, because tranching allows the risk characteristics of the collateral pool to be transformed, it contributes to transaction complexity in assessing the risk properties of such structured instruments: the risk profile that can be generated through tranched exposure, in terms both of expected/unexpected incidence losses and correlated default of pool assets, can lead to substantial differences among tranches, depending on the level of subordination below a certain tranche. Key to the reliability of structured finance pricing and ratings is the accuracy in assessing the credit risk in the underlying portfolio (credit risk modelling), as well as the accurate modelling of the distribution of cash flows to different classes of CDO (cash flow modelling). By analyzing the finance literature relating to security design and securitization this thesis provides an analysis of the efficiency of financial intermediation model based on securitisation and an empirical test of theories supporting the economic added value of tranching, with regard to SMEs loan securitisation, which topic was specifically investigated during a stage at the European Investment Fund. By realization of a computational model, performed using a multidimensional modelling software (Quantrix), the thesis closely examines securitisation transaction's technicalities, by modelling both portfolio cash flows and funds allocation (Waterfall Payment Order), in order to asses the ability of the structure to withstand various stressed scenarios. This analysis offers an analytical and micro-approach to securitisation transactions, which has not deeply investigated in academic literature yet. The model applies to SMEs loan securitisation transactions, concluded within specific securitisation European Programme (Ftpyme in Spain and Promise in Germany).

Three mathematical models, two of primary alkaline battery cathode discharge, and one of primary alkaline battery discharge, are developed, presented, solved and investigated in this thesis. The primary aim of this work is to improve our understanding of the complex, interrelated and nonlinear processes that occur within primary alkaline batteries during discharge. We use perturbation techniques and Laplace transforms to analyse and simplify an existing model of primary alkaline battery cathode under galvanostatic discharge. The process highlights key phenomena, and removes those phenomena that have very little effect on discharge from the model. We find that electrolyte variation within Electrolytic Manganese Dioxide (EMD) particles is negligible, but proton diffusion within EMD crystals is important. The simplification process results in a significant reduction in the number of model equations, and greatly decreases the computational overhead of the numerical simulation software. In addition, the model results based on this simplified framework compare well with available experimental data. The second model of the primary alkaline battery cathode discharge simulates step potential electrochemical spectroscopy discharges, and is used to improve our understanding of the multi-reaction nature of the reduction of EMD. We find that a single-reaction framework is able to simulate multi-reaction behaviour through the use of a nonlinear ion-ion interaction term. The third model simulates the full primary alkaline battery system, and accounts for the precipitation of zinc oxide within the separator (and other regions), and subsequent internal short circuit through this phase. It was found that an internal short circuit is created at the beginning of discharge, and this self-discharge may be exacerbated by discharging the cell intermittently. We find that using a thicker separator paper is a very effective way of minimising self-discharge behaviour. The equations describing the three models are solved numerically in MATLABR, using three pieces of numerical simulation software. They provide a flexible and powerful set of primary alkaline battery discharge prediction tools, that leverage the simplified model framework, allowing them to be easily run on a desktop PC.

4 ABSTRACT The synthesis has been described yielding a new type of rigid conjugated polymer networks which possess a high content of permanent micropores and macropores and exhibit high surface areas up to 1469 m2/g. The networks have been prepared via chain-growth coordination polymerization catalysed with insertion catalysts based on Rh complexes. This polymerization has been newly applied to bifunctional acetylenic monomers of diethynylarene type (1,4-diethynylbenzene, 1,3-diethynylbenzene and 4,4'-diethynylbiphenyl). The covalent structure of the networks consists of the polyacetylene main chains densely connected by arylene struts. The W and Mo metathesis catalysts have been revealed as inefficient for the synthesis of these networks. The increase in the polymerization temperature and time has been shown to affect positively the content and the diameter (up to 22 nm) of the mesopores in the networks. A mechanism has been proposed that explains the mesopores formation as a result of mutual knitting of small particles of the microporous polymer. The application of emulsion polymerization technique allowed to prepare texturally hierarchical polyacetylene networks possessing interconnected open macropores (diameter up to 4,8 μm) the walls of which exhibited micro/mesoporous texture. It was demonstrated...

Pasak prancūzų etnologo Daniel Fabre, istorinis paminklas yra viena akivaizdžiausių manifestacijų, kuria Vakarų Europa per pastaruosius šimtmečius teigė savo istoriškumą . Šiandien ši idėja tampa teorinės polemikos objektu. Šio darbo pagrindinis tikslas – ištirti ir įvertinti naujausius teorinius debatus, skirtus istorinio paminklo idėjos genezei, raidai, bei krizei, visuotinai įsigalėjus heterogeninei sąvokai „paveldas“, taip pat pasiginti į aktualizavimo galimybes ir naujas alternatyvas. Istorinio paminklo genezė tiriama iš dviejų perspektyvių. Pirmoji - tradicinė progresyvioji perspektyva, istorinį paminklą traktuojanti kaip moderniųjų laikų idėją ir didelį dėmesį skirianti juridiniam momentui. Ryškiausi dabartiniai atstovai –André Chastel, Françoise Choay, Dominique Poulot. Antroji – novatoriška antropologinė perspektyva, kvestionuojanti istorinio paminklo kaip moderniųjų laikų. idėjos sampratą Analizuojami šių autorių tekstai – Daniel Fabre, Jean-Michel Leniaud, Olivier Poisson. Kritiškai įvertinus šias dvi perspektyvas, pasigilinama į daugiaperspektyvinio modelio galimybes. Istorinio paminklo paradigminė krizė analizuojama trijose dimensijose – ideologiniame, monumentalumo ir istorinės vertės. Įvertinamas šios krizės mąstai lyginant su perdėm heterogeniška tampančia ir už gnoseologijos ribų išslystančia paveldo samprata, pasigilinama į istorinio paminklo aktualizavimo galimybes bei alternatyvas. Kaip pagrindinė alternatyva analizuojama Pierre Nora „atminties vietų“... [toliau žr. visą tekstą] / According to the French ethnologist, Daniel Fabre, a historic monument is one of the most obvious manifestations that landed itself to maintaining historicism throughout Western Europe in recent centuries. Today this idea becomes object of theoretical debates. The main purpose of this work is to study and evaluate the modern theoretical debate, when heterogenic concept ,,heritage” is universally accepted and set in, about genesis of historic monument idea, development and the crisis. Also, it is necessarily to go deep into opportunity of actualization and new alternatives. There are two perspectives of inquiring the genesis of historic monument. The works on the traditional progressive perspective tend to present a classic image of historic monument, i.e. a his¬toric monument is exhibited as an idea of modernity, with big attention to juridical aspects. One of the most substantial contemporary scientists representing the classic conception is André Chastel, Françoise Choay, Dominique Poulot. As an alternative to this monoperspective theory emerges an innovative interpretation of the modernism of historic mo¬nument developed by contemporary French ethnologists and anthropologists - Daniel Fabre, Jean-Michel Leniaud, Olivier Poisson. This work presents and analyses dif¬ferent visions of the development of his¬toric monument. It aims at attempting to reflect the presented positions and to evaluate the possibilities and challenges of a presumable multi-perspective model. The... [to full text]

This master thesis deals with design and implementation of betting agent. It covers issues such as theoretical background of an online betting, probability and statistics. In its first part it is focused on data mining and explains the principle of knowledge mining form data warehouses and certain methods suitable for different types of tasks. Second, it is concerned with neural networks and algorithm of back-propagation. All the findings are demonstrated on and supported by graphs and histograms of data analysis, made via SAS Enterprise Miner program. In conclusion, the thesis summarizes all the results and offers specific methods of extension of the agent.