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Microbiological Analysis of Residuals and Process Wastewater from Human and Animal Wastes: An Internship with the United States Environmental Protection Agency in Cincinnati, OhioHayes, Gina L. 15 November 2006 (has links)
No description available.
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Material Flow Optimization And Systems Analysis For Biosolids Management: A Study Of The City Of Columbus Municipal OperationsSikdar, Kieran Jonah 10 September 2008 (has links)
No description available.
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A Modeling Approach towards Understanding Solid-Solution Interactions of Metals in BiosolidsDiaz, Maria Eugenia 08 September 2010 (has links)
No description available.
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Anaerobic / Aerobic Digestion for Enhanced Solids and Nitrogen RemovalBanjade, Sarita 22 January 2009 (has links)
Anaerobic digestion of wastewater sludge has widely been in application for stabilization of sludge. With the increase in hauling cost and many environmental and health concerns regarding land application of biosolids, digestion processes generating minimized sludge with better effluent characteristics is becoming important for many public and wastewater utilities.
This study was designed to investigate the performance of anaerobic-aerobic-anaerobic digestion of sludge and compare it to anaerobic-aerobic digestion and single stage mesophilic digestion of sludge. Experiments were carried out in three stages: Single-stage mesophilic anaerobic digestion (MAD) 20d SRT; Sequential Anaerobic/Aerobic digestion (Ana/Aer); and Anaerobic/Aerobic/Anaerobic digestion (An/Aer/An). The Anaerobic/Aerobic/Anaerobic digestion of sludge was studied with two options to determine the best option in terms of effluent characteristics. The two sludge withdrawal options were to withdraw effluent from the anaerobic digester (An/Aer/An – A) or withdraw effluent from the aerobic digester (An/Aer/An – B). Different operational parameters, such as COD removal, VS destruction, biogas production, Nitrogen removal, odor removal and dewatering properties of the resulting biosolids were studied and the results were compared among different processes.
From the study, it was found that An/Aer/An – B (wastage from aerobic reactor) provided better effluent characteristics than An/Aer/An – A (wastage from anaerobic reactor), Ana/Aer or conventional MAD. The study also shows that the Anaerobic/Aerobic/Anaerobic (An/Aer/An, with wastage from the aerobic or anaerobic digester) digestion of the sludge can improve the biosolids quality by improving the dewatering capabilities, with lower optimum polymer dose, reduced CST and increased cake solid concentration, and reduce the odor generation from the biosolids.
Both An/Aer/Ana – A and An/Aer/An – B gave 70% VS removal, compared to 50% with single MAD and 62% with only Ana/Aer. COD removal of both An/Aer/An – A and An/Aer/An – B was 70%, while it was 50% and 66% for single MAD and Ana/Aer respectively. In the aerobic reactors of Ana/Aer and An/Aer/An - B, nitrification and denitrification with removal of nitrogen was observed. The An/Aer/An – B system had more ammonia and TKN removal (70%) than Ana/Aer (64%).
The effluent from each stage was analyzed for dewatering ability, cake solid concentration and odor production potential. Compared with a single Ana/Aer system, the extra anaerobic step in An/Aer/An – A and – B reduced polysaccharides in the effluent. The Ana/Aer system released less protein than the conventional MAD system and the addition of the second anaerobic step - especially with system An/Aer/An – B (discharge from aerobic reactor) - greatly reduced protein, resulting in improved dewaterability and less polymer demand. An/Aer/An (both of the options: A and B) had lower CST than single MAD (both 15d and 20d SRT) and Ana/Aer. Compared to Ana/Aer, a reduction of 52% for An/Aer/An – A and 20% for An/Aer/An – B in polymer dose requirement was observed, indicating improved dewatering characteristics. The An/Aer/An – B has higher biosolid cake concentration than MAD or Ana/Aer. The results showed that An/Aer/An (both options: A and B) biosolid had lower odor generation potential than single MAD (15d and 20d SRT) or Ana/Aer. Of all the stages,the An/Aer/An – A and – B system, generated odor which peaked at shorter time and lasted for shorter duration of time. / Master of Science
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Effects of Thermal Hydrolysis Pre-Treatment on Anaerobic Digestion of SludgeBishnoi, Pallavi 14 September 2012 (has links)
The increased demand for advanced techniques in anaerobic digestion over the last few years has led to the employment of various pre-treatment methods prior to anaerobic digestion to increase gas production. These pre-treatment methods alter the physical and chemical properties of sludge in order to make it more readily degradable by anaerobic digestion. The thermal hydrolysis process has been used in several treatment plants around the world, but none currently operate in the US. Thermal hydrolysis causes cell walls to rupture under the effect of high temperature and high pressure and results in highly solubilized product which is readily biodegradable. The performance of the process was evaluated for a treatment plant located in Dallas, TX. The performance assessment was based on various characteristics including pH, solids removal, COD removal and gas production. The study was conducted in two phases to investigate the effect of change in mesophilic temperature (37°C and 42°C) and the effect of solids retention time (SRT) (15 days and 20 days). Thermally hydrolyzed combined (1:1) primary and waste activated sludge was fed to a Thermal Hydrolysis (TH) anaerobic digester and its performance was compared to a conventional mesophilic anaerobic digester receiving non pre-treated sludge. The thermal hydrolysis pre-treatment was found to be more effective as compared to the conventional anaerobic digester. The efficiency of the process varied slightly with increase in temperature but the change in SRT was seen to have a greater impact on the digester's performance. The pre-treatment technique was observed to deliver the best results at a 20 day SRT. / Master of Science
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Anaerobic Digestion: Factors Effecting Odor GenerationVerma, Nitin 12 August 2005 (has links)
Land application of anaerobically stabilized biosolids is a beneficial method of handling the solid residuals from a wastewater treatment plant. One of the main issues that restrict land application of biosolids is nuisance odors associated with biosolids. Despite its importance, few studies have been done to enhance our knowledge of odor causing processes. This study was conducted to evaluate the effects of some factors that have been thought to be linked to odor generation from biosolids. The first part of this study has looked at the role of metals, iron and aluminum in particular, in determining the odor causing processes. The results showed that iron correlated well with headspace organic sulfur odor. In general, as the iron content of sludge increased greater amounts of odorous sulfur gases were produced from dewatered biosolids cakes. Aluminum did not show any relationship with organic sulfur odors. Parameters commonly used for assessing the performance of anaerobic digesters (volatile solids reduction (VSR), residual biological activity (RBA) and effluent volatile fatty acid (VFA) content) also showed no correlation with odors.
The second part of the study focused on determining the impact of anaerobic digester solids retention time (SRT) on the odor generation from dewatered biosolids cakes and also on elucidating the nature and impact of the various Extracellular Polymeric Substances (EPS) fractions on odors. The results showed that odors decreased with an increase in the anaerobic digester SRT. VSR and RBA correlated with odors; however, as only one type of sludge was assessed, the conclusions about any relationship may not be universal. The results also showed that sulfur gas generation was a function of EPS material bound to iron, again showing that iron plays an important role in odor generation from dewatered sludge cakes.
The third part of the study looked at the effects of advanced digestion processes on odor generation. Digested sludge from acid/gas and temperature phased anaerobic digestion systems were analyzed in the lab. The results show that both acid/gas system and temperature phased digestion had a positive impact on odor generation from dewatered biosolids cake. Comparison of sludge from pancake shaped and egg shaped digesters showed that egg shaped digester was more efficient with regard to odor reduction. / Master of Science
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The Effect of Temperature on Lignin Degradation in Municipal Solid WasteMiroshnikova, Olga 20 November 2006 (has links)
Paper and paperboard are the major constituents found in US landfills. Typically paper consists of 79% to 98% of lignocellulose which is considered to be the most abundant source of natural carbon on earth. Lignocellulose decomposition depends on the association of biodegradable cellulose and hemicellulose with lignin. Lignin is a recalcitrant material which hinders cellulose degradation in conventional landfills. Because of this property of lignin cellulose to lignin ratio (C/L) is a common landfill stabilization parameter. Refuse degradation in landfills is a microbiological process and is highly dependent on temperature, moisture, and pH. Bioreactor landfills are designed to enhance biodegradation of refuse by providing favorable conditions for microorganisms. Effect of elevated temperature and moisture on possibility of lignin degradation is studied in this work. Synthetic and newspaper lignin were preheated and then inoculated with anaerobically digested sludge. Newspaper in distilled water exposed to 95°C for 48 hours released 8 times more of solubilized lignin then non preheated newspaper. Moreover lignin monomers were detected as a result of 95°C pretreatment indicating the positive effect of high temperature on the providing lignin in more bioavailable form for microbes. Digested sludge inocula was found to be capable of lignin monomers degradation as well as low but significant mineralization of synthetic lignin with approximately 6% of carbon originated from lignin mineralized into methane and carbon dioxide. An exponentially increasing trend for lignin monomers solubilization as a function of temperature was observed for three types of substrate, synthetic lignin, cardboard, and newspaper with the highest rate of solubilization for newspaper. Results of this study suggest that some lignin degradation can occur at conditions typical for bioreactor landfills. / Master of Science
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Identification and generation pattern of odor-causing compounds in dewatered biosolids during long-term storage and effect of digestion and dewatering techniques on odorsKacker, Ritika 08 September 2011 (has links)
The main objective of this research was to identify the compounds responsible for persistent odors in biosolids during long-term storage using olfactometry measurements and to determine their generation pattern with regard to time of appearance and decline using gas chromatography-mass spectrometry (GC-MS). Another objective of this study was to investigate the effect of various digestion and dewatering techniques on odors and determine if there is a correlation between the peak concentration and time of appearance of short-tem organic sulfur odors and persistent odors. Headspace analysis was used to quantify short-term odor-causing organic sulfur compounds and persistent odors from compounds such as indole, skatole, butyric acid and p-cresol for an incubation period up to 150 days.
A unique odor generation pattern was observed for each of the compounds analyzed for all the dewatered cakes tested in this study. Dewatered cake samples were also analyzed to determine their detection threshold by a trained odor panel and the results were consistent with the general pattern of odor generation observed in this study. Positive correlations were observed between the peak concentration of organic sulfur and persistent odor compounds whereas little or no relationship was observed between their times of appearance. The type of sludge used in digestion (primary sludge, WAS and mix) was found to affect the production of odor-causing compounds significantly. Primary sludge produces the highest odors followed by mix. WAS was found to produce biosolids with a low odor concentration. Positive correlation was observed between odor concentration and digestion SRT. Significant reduction in odor concentration was observed when the SRT was increased from 12-days to 25-days. At 45-day SRT, further reduction in odors was not very significant. Moreover, the results from this study indicate that methanogens play an important role in the degradation of both organic sulfur and persistent odors. Although the highest odors during biosolids incubation came from sulfur compounds, the persistent odors must be managed as part of a comprehensive sludge management approach. / Master of Science
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Drought Resistance Response of Tall Fescue Established in Disturbed Urban Soils Utilizing BiosolidsBoyd, Adam Philip 18 February 2016 (has links)
Urban soils are typically degraded due to land disturbance. The poor quality physical and chemical properties of the soil can benefit from application of organic amendments. Local sources of such amendments are biosolids, which are treated domestic wastewater sludges. The objective of this experiment was to compare effects of various high quality biosolids-based soil amendments with synthetic fertilizer on the growth and quality of tall fescue (Schedonorus arundinaceus) under two different soil moisture regimes. The research site was a disturbed soil at the Virginia Tech Turfgrass Research Center in Blacksburg, Virginia. The experimental design was a split plot with irrigation regime as the main factor and soil amendments as the split factor. All treatments were arranged in four randomized complete blocks. The study was established in late summer 2013. Soil amendment treatments, applied prior to seeding in September 2013, were: 1) inorganic N, P, K applied according to soil test laboratory recommendations; 2) anaerobically digested, dewatered biosolids to supply agronomic N rate; 3) anaerobically digested, dewatered biosolids blended with sand and sawdust to supply agronomic N rate; 4) anaerobically digested, dewatered biosolids blended with sand and sawdust to supply agronomic P rate; and 5) composted biosolids to supply agronomic N rate. The agronomic N rate for the turfgrass was 224 kg of estimated plant available nitrogen (PAN) ha-1. Inorganic fertilizer was applied to supply annual P and K requirements prior to seeding in late summer, and the N was split into three application timings (September 2013, April 2014, and June 2014). Supplemental fertilizer N to achieve full agronomic N rate was applied to the treatment plots that received the agronomic P rate of blended biosolids-sand-sawdust. The area was seeded on September 13, 2013 with a tall fescue blend at a rate of 488 kg ha-1. Following full tall fescue establishment, in June 2014, two irrigation regimes, consisting of 0% and 80% evapotranspiration replacement every three days, were initiated. The study had three phases denoted as the pre-drought, drought, and recovery phases which started in April and concluded in August of 2014. Turfgrass color and quality, volumetric soil moisture percentage to a 5 cm depth, normalized difference vegetative index (NDVI), clipping yield, and turfgrass N uptake were measured bi-weekly throughout the growing season. During the first May through July 2014 irrigation season, results were that the fertilizer control consistently provided improved responses relative to the biosolids amended treatments. Clipping yield, quality, and NDVI were all significantly greater in the inorganic fertilizer treatment, but volumetric soil moisture percentages were slightly greater in the biosolids treatments. Turfgrass responses appeared to have been associated with plant available nitrogen, which was lower in the biosolids treatments than in the fertilizer treatment. Calculated PAN for the biosolids products was too low to achieve ideal turfgrass growth and quality. Improving the estimated PAN and/or splitting the organic amendment application times should improve the growth and quality of the turfgrass. / Master of Science
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Biosolids as a source of soil conditioning and fertility for turfgrassBadzmierowski, Mike J. 04 November 2019 (has links)
Wastewater treatment plants are shifting towards producing exceptional quality (EQ) biosolids to increase recycling rates to land, especially urban areas. Other methods of improving the environmental impact of wastewater treatment includes additions of iron (Fe) to reduce phosphorus (P) concentrations in outgoing treated water and precipitate the P into the biosolids. Proper management of biosolids to rehabilitate anthropogenically disturbed urban soils for improved plant growth and effects on the cycling of nutrients requires further study. Our objectives were: 1) to determine whether various EQ biosolids could be managed to improve degraded soil properties and turfgrass quality while minimizing risk of P loss in a field study; and 2) to use spectral reflectance data to compare relationships of vegetation indices to soil and turfgrass parameters. We found that after an initial lag-time of one year, biosolids amendments increased turfgrass clipping biomass and aesthetic quality greater than did synthetic fertilizer. Repeated topdressing applications of biosolids reduced soil bulk density and increased soil organic carbon (OC) and nitrogen (N) stocks. Biosolids applied at the agronomic N rate did not increase water-soluble P (15 and 18 mg P kg-1 of soil) compared to biosolids applied at the agronomic P rate (9.6 mg P kg-1 of soil) and synthetic fertilizer (13 mg P kg-1 of soil) after five years. We further demonstrated at this field site that collecting continuous data improves spectral reflectance vegetation indices relationships to turfgrass quality, clipping biomass, and tissue N accumulation. Soil volumetric water content was best correlated to the water band index (r = 0.60) and the green-to-red ratio index (r = 0.54) vegetation indices. Differences in soil and turfgrass measured parameters were best detected when there was drought-stressed versus irrigated turfgrass. / Doctor of Philosophy / Biosolids are the sanitized and nutrient-rich organic solids and semi-solids resulting from treatment of wastewater. The nutrient-rich organic solids provide plant-essential elements (e.g., nitrogen) and can improve soil physical parameters such as soil compaction. Wastewater treatment plants are adopting processes that produce cleaner, exceptional quality (EQ) biosolids to increase biosolids recycling rates to land, especially to urban areas to improve urban soil quality. Adding iron to treated wastewater further improves the quality of biosolids and effluent released to surface water by removing phosphorus from wastewater and concentrating this essential plant nutrient within biosolids. Our research objectives were to quantify the potential benefits of EQ biosolids for improving degraded urban soils, providing sufficient plant available nitrogen to improve turfgrass quality, avoiding increasing soil phosphorus to levels that could result in pollution, and increasing the long-term storage of soil carbon to mitigate climate change. We learned that biosolids were the best long-term solution for providing a high quality turfgrass stand and improve soil properties. Repeated applications of EQ biosolids reduced soil bulk density and increased soil organic carbon and nitrogen stocks. The increased iron in the biosolids reduced water-soluble phosphorus and may reduce phosphorus loss to surface waters.
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