No description available.

No description available.

Thesis (Ph. D.)--Oregon Graduate Center, 1988.

Thesis (M. Phil.)--University of Hong Kong, 1997. / Includes bibliographical references (leaf 93-94).

Thesis (M. S.)--Civil and Environmental Engineering, Georgia Institute of Technology, 2008. / Committee Chair: Russell, Armistead; Committee Member: Mulholland, James; Committee Member: Odman, Talat.

Thèse--Faculté de droit de Paris. / "Principaux ouvrages à consulter": p. [5]-6.

Thesis (M.Arch.(Prof.))--University of Pretoria, 2005. / Includes summary. Includes bibliographical references. Available on the Internet via the World Wide Web.

We, as human beings, are unique creatures that have a need to form places. This obsession with claiming spaces and turning them into places starts at a young age. Maybe it is the first time a child goes to the park and claims a corner of the sand pit, because they think the sand is better on the right side. Perhaps it is a specific seat in the bleachers a person sits in at every home football game. Or maybe it is much more significant, like the spot on the path by the curved tree, next to the bike shed where you said good-bye to your family the first day of your freshman year in college.

Grain boundaries form the basis of an important Josephson junction technology in the cuprates and also limit the superconducting critical currents attainable in practical, polycrystalline materials. An improved understanding of these defects is therefore important for applications. The status of the current understanding of cuprate grain boundaries is summarised and experimental investigations are presented, focusing on the less well understood high angle boundaries. Measurements of the capacitance of grain boundaries in the overdoped superconductor Y1-xCaxBa2Cu3O7-8, were performed as a function of the calcium content, using the Josephson coupling across the boundaries. Particular care was taken to eliminate the effects of heating and stray capacitance due to the substrate. The effect of thermal noise was also assessed. These measurements provide important information about the area and the width of the grain boundaries, that highlights their inhomogeneous nature. A new technique was applied to measure the normal state properties of YBa2Cu3O7-8 grain boundaries above the critical temperature. Since the resistance of the adjacent material at high temperatures is comparable to, or greater than, that of the grain boundary a compensating Wheatstonebridge structure was used. The errors involved in this technique are carefully assessed and quantified. The normal state resistance of a number of different grain boundary orientations was measured from room temperature to the critical temperature. Detailed characterisation of the grain boundaries, including measurements of the critical current and the current voltage characteristics at low temperatures, was performed. The results obtained are used to assess the validity of the various theories for the grain boundary electrical structure. A tunneling model that accounts for the band structure of the material is developed and applied to potential barriers consistent with a band bending model. This theory is shown to provide a convincing account of the experimental results presented in this thesis.

Critical currents in the latest biaxially textured 'coated conductors' are now limited by 2D networks of low angle grain boundaries (LAGBs) with misorientation θm = 1 - 10°. In order to understand and optimise current transfer in these materials it is essential to elucidate the electromagnetic behaviour of the LAGB. This work presents an investigation into the transport properties of [001]-tilt LAGBs formed by the thin film deposition of YBa2Cu3O7 onto bicrystalline substrates. Through the use of a precision two-axis goniometer, measurements of the V-I characteristic and critical current density were made as magnetic field was rotated in angles θ and φ relative to the LAGB defect. It is found that for fields applied parallel to the LAGB defect plane, dissipation is dominated by the viscous flux flow of vortices along the boundary. Clear evidence for this is found in the V-I characteristic, which displays an increased linearity indicative of the viscous regime. It is shown that the number of vortex rows involved in the flow process can discontinuously switch, leading to a V-I characteristic made up of straight segments of different gradient. For fields applied away from the LAGB defect plane a kinked vortex structure develops and the boundary critical current density, JcGB, is determined by the channelling of vortex segments still lying within the LAGB. The channelling regime is seen in angular measurements as a marked decrease in JcGB(θ,φ) as field becomes aligned to within critical angles φK or θK of the LAGB. The aligned vortices experience a reduction in dimensionality that is manifest in a reduced temperature dependence of JcGB(T). For fields applied at a sufficiently large angle from the defect plane the deleterious effects of the LAGB on current transport are mitigated considerably. In this regime a collinear vortex structure is regained and transport is controlled by the intragranular (IG) sections of the LAGB track; JcGB = δJcIG where δ ~ 0.8, a result that is independent of field, temperature and angle for a 4.9° LAGB. For rotation of the applied field within the LAGB defect plane, the presence of a pinning peak in JcGB for field aligned to the dislocation array is confirmed and modelled. The peak is found to be absent in IG track measurements and increases relative to the intrinsic peak with both increasing field and temperature. In addition, a pronounced angular hysteresis is presented, which is directly linked to a corresponding 'static' hysteresis in JcGB(B) with field. Magneto-optic measurements confirm that this effect is controlled by the flux density profile in the IG regions of the LAGB track. Finally, above a temperature, angle and sample dependent merging field, B*, the LAGB is found to be effectively transparent, as δ ~ 1. This is due to the irreversibility line, above which dissipation occurs across the whole LAGB track.