The main objective of this study was to investigate the factors that influence the oxidation rate of large (five to eight millimeters in diameter) coal and char particles. To accomplish this, experiments were performed in which the gas temperature, gas velocity, particle size, partial pressure of oxygen, and total pressure were varied. The experiments were performed with the cantilever balance attachment and the high pressure controlled profile reactor. Approximately 90 combustion experiments were performed with Pittsburgh, Utah Blind Canyon, and Wyodak-Anderson coal. These experiments were performed at atmospheric pressure with air and varied gas temperature, gas velocity, and particle size. Following the experiments performed with coal, approximately 70 experiments were performed with char made from Pittsburgh coal. These experiments varied all the environmental conditions mentioned above as well as partial pressure of oxygen and total pressure. After the experiments were completed, the data were analyzed and the following conclusions were made. An increase in the partial pressure of oxygen dramatically increased the oxidation rate when the total pressure remained constant. The oxidation rate was only slightly affected when the partial pressure of oxygen was raised by increasing the total pressure. The oxidation rate dramatically decreased when the partial pressure of oxygen was held constant and the total pressure was raised. The oxidation rate noticeably increased when the initial mass of the particle was decreased. The gas temperature and gas velocity did not affect the oxidation rate greatly for the experiments performed with coal. The oxidation rate increased for the experiments performed with char at the high gas temperature and high gas velocity conditions.

Afin de répondre aux besoins croissants en énergie primaire, le groupe Europlasma a développé le procédé CHO-Power permettant de valoriser énergétiquement un mélange de refus de tri d’ordures ménagères et de résidus de biomasse. L’une des particularités de ce procédé est l’utilisation d’un réacteur de dégradation thermique des goudrons et des particules solides fines par assistance plasma. L’objectif de cette étude de mieux appréhender les mécanismes réactionnels mis en jeu lors de l’épuration thermique du gaz. Dans cette optique, un réacteur pilote a été dimensionné puis construit sur la plate-forme de Recherche et Développement d’Europlasma. Il a été ensuite nécessaire de modifier le schéma réactionnel permettant la modélisation numérique de la dégradation des goudrons. Ce schéma réactionnel, couplé à l’utilisation d’un logiciel de mécanique des fluides numérique, permet de représenter les processus couplés (chimie, aéraulique, transferts thermiques) se déroulant au sein du réacteur. Deux modifications importantes ont été alors apportées au modèle cinétique simplifié jusque-là utilisé : la modélisation d’une phase discrète réactive permettant de prendre en compte la gazéification des particules de résidus carbonés et l’ajout de nouvelles voies réactionnelles afin de mieux modéliser la formation des particules de suie et de ses précurseurs. À terme, la comparaison des valeurs expérimentales à celle issues de la modélisation numérique permettra de valider ou non le schéma réactionnel dans sa globalité. / In order to contest to the high world demand for primary energy, the Europlasma group developed a new process, called CHO-Power, to enhance the thermochemical potential of a mixture of urban waste and biomass residues. One of the characteristics of this process is the use of a high temperature reactor assisted by a plasma torch for tar and soots thermal cracking. The aim of this study to improve the knowledge of the global reaction mechanism involved during the thermal treatment of gas. In this context, a pilot plant reactor was designed and built on the Europlasma Research and Development Center. During this work, the reaction pathway used to represent tars cracking at high temperature has been enhanced. Coupled to a computational fluid Dynamics Software, allow simulating the complex processes occurring within the reactor (aeraulics, reaction, and heat transfer). Two major changes were made to the simplified kinetic model previously used: the modeling of a discrete and reactive phase to take into account the possible particle gasification of carbonaceous residues and the addition of new reaction pathways to enhance the modeling of the formation of soot and its precursors. The comparison between the experimental and numerical values will validate or not the global reaction scheme and will give important information about the next evolution of the tar degradation scheme.