All modern terawatt- and petawatt-class laser systems are based on the principle of chirped-pulse amplification (CPA). In this work, a compact subsystem that shifts a micro-joule portion of the chirped pulse energy to a new wavelength outside its original bandwidth, then amplifies it to millijoule energy without adding pump lasers, and without compromising the output of the fundamental CPA system in any significant way, has been developed and integrated into a standard terawatt-class CPA system. In this chirped pulse Raman amplifier sub-system, a 30 mJ portion of a chirped 800 nm fundamental pulse within the CPA system was split into two unequal portions, each of which impinged on a Raman-active barium nitrate, or Ba(NO3)2, crystal of length 5 cm. The weaker portion created a weak (15 J) first Stokes pulse (873 nm) by Stimulated Raman Scattering (SRS) in the first crystal, which then seeded a non-collinear four-wave-mixing process driven by the stronger portion of the split-off CPA pulse in the second crystal. The latter process amplified the first Stokes seed pulse to several millijoules with excellent beam quality. A study of Raman gain as a function of time delay between pump and Stokes pulse in the second crystal revealed a sharply peaked narrow interval ( 3 ps FWHM) of high gain and a wider interval ( 50 ps) of low gain. The amplified, chirped first Stokes pulse was successfully compressed to 100 fs duration using a grating pair of different line density than in the main CPA system, based on a comprehensive dispersion analysis of the optical path of the first Stokes pulse. The possibility of generating higher-order Stokes and anti-Stokes sidebands of the CPA pulse is also demonstrated. Further amplification of the sideband pulse by conventional methods, using an additional pump laser, appears straightforward. The chirped pulse Raman amplifier provides temporally synchronized fundamental and Raman sideband pulses for performing two-color, high-intensity laser experiments, some of which are briefly discussed. It can be integrated into any standard CPA system, and provides significant new versatility for high-intensity laser sources. / text

The consequences of fabricating Bragg gratings in various fibres, with or without hydrogen loading, and with varying laser power levels are explored. Three new techniques for fabricating chirped gratings are presented. Beams with dissimilar wavefront curvatures are interfered to give chirped gratings. With the same aim techniques of writing gratings on tapered fibres and on deformed fibres are also covered. With these techniques, a wide variety of gratings has been fabricated from the 'superbroad' (with bandwidths of up to 180 nm), small to medium bandwidth gratings with linear chirp profiles and quadratic chirped gratings. It is demonstrated that chirped grating can be concatenated to form all-fibre Fabry-Perot and Moiré resonators. These are further concatenated with chirped gratings to produce filters with narrow passbands and very broad stopbands. A number of other applications are also addressed. The use of chirped fibre gratings for dispersion compensation and femtosecond chirped pulse amplification is demonstrated. Chirped gratings are used as dispersive elements in modelocked fibre lasers producing ultrashort pulses. A chirped fibre grating Fabry-Perot transmission filter is used in a continuous wave laser that exhibits eleven simultaneously lasing wavelengths. Finally, the use of grating-coupler devices as variable reflectivity mirrors for laser optimisation and gain clamping is considered.

Interference has long been used for precision measurement of path-length changes. Since the advent of the laser, interference has become one of the most versatile tools in metrology. Specifically, ultra-short laser pulses allow unprecedented resolution in absolute length measurements. While ultra-short laser pulses lead to high resolution, for example in white-light interferometry, they are very susceptible to dispersion. Quantum resources have been proposed to overcome some of the problems related to distortions in the interferometric signal. For example, the Hong-Ou-Mandel (HOM) interferometer relies on frequency-entangled photon pairs and features automatic even-order dispersion cancellation and high interference visibility resilient to unbalanced loss. Quantum-OCT is a technique based on HOM interferometry, that promises to overcome Optical Coherence Tomography (OCT) a classical imaging technique based on low coherence light. Furthermore, straightforward modifications of the HOM interferometer can display several different interferometric signals, including the HOM peak, quantum beating, and phase super-resolution. However, the quantum resources required are hard to produce and dim, leading to long integration times and single-photon counting. In this thesis, we introduce the theory behind Chirped-Pulse Interferometry (CPI), a new technique that combines all the advantages of Q-OCT, including even-order dispersion cancellation, but without the need for any quantum resources. We then experimentally implement CPI and demonstrate all the important characteristics shared by the HOM interferometer, but at dramatically larger signal levels. We show how CPI can be used to measure dispersion cancelled axial profiles of an optical sample and show the improvement in resolution over white-light interferometry. Finally, we show that by modifying CPI in analogous ways to HOM, CPI can also be made to produce interferometric signal identical to the HOM peak, quantum beating, and phase super-resolution.

Interference has long been used for precision measurement of path-length changes. Since the advent of the laser, interference has become one of the most versatile tools in metrology. Specifically, ultra-short laser pulses allow unprecedented resolution in absolute length measurements. While ultra-short laser pulses lead to high resolution, for example in white-light interferometry, they are very susceptible to dispersion. Quantum resources have been proposed to overcome some of the problems related to distortions in the interferometric signal. For example, the Hong-Ou-Mandel (HOM) interferometer relies on frequency-entangled photon pairs and features automatic even-order dispersion cancellation and high interference visibility resilient to unbalanced loss. Quantum-OCT is a technique based on HOM interferometry, that promises to overcome Optical Coherence Tomography (OCT) a classical imaging technique based on low coherence light. Furthermore, straightforward modifications of the HOM interferometer can display several different interferometric signals, including the HOM peak, quantum beating, and phase super-resolution. However, the quantum resources required are hard to produce and dim, leading to long integration times and single-photon counting. In this thesis, we introduce the theory behind Chirped-Pulse Interferometry (CPI), a new technique that combines all the advantages of Q-OCT, including even-order dispersion cancellation, but without the need for any quantum resources. We then experimentally implement CPI and demonstrate all the important characteristics shared by the HOM interferometer, but at dramatically larger signal levels. We show how CPI can be used to measure dispersion cancelled axial profiles of an optical sample and show the improvement in resolution over white-light interferometry. Finally, we show that by modifying CPI in analogous ways to HOM, CPI can also be made to produce interferometric signal identical to the HOM peak, quantum beating, and phase super-resolution.

A wide band linearly chirped erbium-doped fiber laser has been developed. The erbium-doped fiber laser using a rotating mirror/grating combination as one of the reflectors in a Fabry-Perot laser cavity has been tuned over a 46 nm spectral range. Linearization of the chirp rate has been achieved using feedback from a fiber Fabry-Perot interferometer (FFPI) to adjust the voltage ramp which drives the rotating mirror. In a demonstration of monitoring an array of two fiber Bragg grating (FBG) sensors, a wavelength resolution of 1.7 pm has been achieved. The linearly chirped fiber laser has been used in measuring the optical path difference (OPD) of interferometric fiber optic sensors by performing a Fourier transform of the optical signal. Multiplexing of an array of three FFPI sensors of different lengths has been demonstrated, with an OPD resolution ranging from 3.6 nm to 6.3 nm. Temperature was measured with one of the sensors over the range from 20°C to 610°C with a resolution of 0.02°C. Short FBGs are used to form the two mirrors of a fiber Bragg grating pair interferometer (FBGPI) sensor, so that the mirror reflectances change gradually as a function of temperature. Modulating the drive current of a DFB laser produces chirping of the laser frequency to scan over ~2.5 fringes of the FBGPI reflectance spectrum. Because the fringes are distinguished due to the FBG reflectance change, the ambient temperature can be determined over the range from 24 oC to 367 oC with a resolution of 0.004 oC. Multiplexing of FBGPI sensors of different lengths with a linearly chirped fiber laser has demonstrated improved sensitivity and multiplexing capacity over a conventional FBG WDM system. The FBG spectral peak position and the phase shift of an FBGPI are determined through the convolution of the sensor reflected signal with an appropriately matched reference waveform, even though the reflectance spectra for the FBGs from different sensors overlap over a wide temperature range. A spectral resolution for the FBG reflectance peak of 0.045 GHz (0.36 pm), corresponding to a temperature resolution of 0.035 oC, has been achieved.

This work focuses on finding the complete iodine and nitrogen nuclear electric quadrupole coupling tensors for fluoroiodoacetonitrile using chirped-pulse Fourier transform microwave spectroscopy. Fluoroiodoacetonitrile contains two hyperfine nuclei, iodine (I=5/2) and nitrogen (I=1) and the spectra were observed with great resolution. A total of 499 transitions were observed for this molecule. The a, b and c rotational constants were obtained. A study of chloropentafluoroacetone was also done using chirped-pulse Fourier transform microwave spectroscopy. The two chlorine isotopes for this molecule, Cl-35 and Cl-37 were observed and 326 and 170 transitions were recorded, respectively.

Distributed optical fiber sensors offer unprecedented advantages, and the most remarkable one is the ability to continuously measure physical or chemical parameters along the entire optical fiber, which is attached to the device, structure and system. As the most recently investigated distributed optical fiber sensors, phase-sensitive optical time domain reflectometry (φ-OTDR), Brillouin optical time domain analysis (BOTDA) and Brillouin dynamic grating-optical time domain reflectometry (BDG-OTDR) techniques have been given tremendous attention on the advantage of quantitative measurements ability over high sensitivity and absolute measurement with long sensing distance, respectively. However, the accompanying limitations in terms of static measurement range, acquisition rate, laser frequency drifting noise, and spatial resolution limitations in these techniques hinder their performance in practical applications. This thesis pays particular attention to the above three distributed sensing techniques to explore the fundamental limitations of the theoretical model and improve the sensing performance. Before presenting the novel sensing scheme with improved sensing performance, an introduction about distributed fiber optical sensing, including three main light scattering mechanisms in optical fiber, the recent advancements in distributed sensing and key parameters of Rayleigh scattering- and Brillouin scattering-based sensing systems. After that, a study on the theoretical analysis of large chirping rate pulse generation and the theoretical model of using chirped pulse as interrogation signal in φ-OTDR, BOTDA and BDG-OTDR systems are given. In the disruptive experimental implementations, the sensing performance has been improved in different aspects. By using a random fiber grating array as the distributed sensor, a high-precision distributed time delay measurement in a CP φ-OTDR system is proposed thanks to the enhanced in-homogeneity and reflectivity. In addition, a simple and effective method that utilizes the reference random fiber grating to monitor the laser frequency drifting noise is demonstrated. Dynamic strain measurement with a standard deviation of 66 nε over the vibration amplitude of 30 με is achieved. To solve the limited static measurement range issue, a multi-frequency database demodulation (MFDD) method is proposed to release the large strain variation induced time domain trace distortion by tuning the laser initial frequency. The maximum measurable strain variation of about 12.5 με represents a factor of 3 improvements. By using the optimized chirped pulse φ-OTDR system, a practical application of monitoring the impact load response in an I-steel beam is demonstrated, in which the static and distributed strain variation is successfully reconstructed. To obtain an enhanced static measurement range without a complicated database acquisition process, a photonic approach for generating low-frequency drifting noise, arbitrary and large frequency chirping rate (FCR) optical pulses based on the Kerr effect in the nonlinear optical fiber is theoretically analyzed and experimentally demonstrated by using both fixed-frequency pump and chirped pump. Due to the Kerr effect-induced sinusoidal phase modulation in the nonlinear fiber, high order Kerr pulse with a large chirping rate is generated. Thus the static measurement range of higher order Kerr pulse is significantly improved. Chirped pulse BOTDA based on non-uniform fiber is also analyzed, showing a high acquisition rate that is only limited by the sensor length and averaging times due to the relative Brillouin frequency shift (BFS) changes are directly extracted through the local time delays between adjacent Brillouin traces from two single-shot measurement without frequency sweep process. BFS measurement resolution of 0.42 MHz with 4.5 m spatial resolution is demonstrated over a 5 km non-uniform fiber. A hybrid simultaneous temperature/strain sensing system is also demonstrated, showing a strain uncertainty of 4.3 με and temperature uncertainty of 0.32 °C in a 5 km non-uniform fiber. Besides, the chirped pulse is also utilized as a probe signal in the Brillouin dynamic grating (BDG) detection along the PM fiber for distributed birefringence variations sensing. The strict phase-matching condition only enables part of the frequency components within the chirped probe pulse to be reflected by BDG, giving an adjustable spatial resolution without photo lifetime limitation. The spatial resolution is determined by the frequency chirping rate of the probe pulse.

Microwave spectroscopy is a gas phase technique typically geared toward measuring the rotational transitions of Molecules. The information contained in this type of spectroscopy pertains to a molecules structure, both geometric and electronic, which give insight into a molecule's chemistry. Typically this type of spectroscopy is high resolution, but narrowband ≤1 MHz in frequency. This is achieved by tuning a cavity, exciting a molecule with electromagnetic radiation in the microwave region, turning the electromagnetic radiation o, and measuring a signal from the molecular relaxation in the form of a free induction decay (FID). The FID is then Fourier transformed to give a frequency of the transition. "Fast passage" is defined as a sweeping of frequencies through a transition at a time much shorter (≤10 s) than the molecular relaxation (≈100 s). Recent advancements in technology have allowed for the creation of these fast frequency sweeps, known as "chirps", which allow for broadband capabilities. This work presents the design, construction, and implementation of one such novel, high-resolution microwave spectrometer with broadband capabilities. The manuscript also provides the theory, technique, and motivations behind building of such an instrument. In this manuscript it is demonstrated that, although a gas phase technique, solids, liquids, and transient species may be studied with the spectrometer with high sensitivity, making it a viable option for many molecules wanting to be rotationally studied. The spectrometer has a relative correct intensity feature that, when coupled with theory, may ease the difficulty in transition assignment and facilitate dynamic chemical studies of the experiment. Molecules studied on this spectrometer have, in turn, been analyzed and assigned using common rotational spectroscopic analysis. Detailed theory on the analysis of these molecules has been provided. Structural parameters such as rotational constants and centrifugal distortion constants have been determined and reported for most molecules in the document. Where possible, comparisons have been made amongst groups of similar molecules to try and get insight into the nature of the bonds those molecules are forming. This has been achieved the the comparisons of nuclear electric quadrupole and nuclear magnetic coupling constants, and the results therein have been determined and reported.

The goal of this thesis is developing a two-color Ytterbium (Yb) fiber amplifier system that can be used for generation of mid-infrared radiation. Previously, our group reported generating 20 µW of average power, at a wavelength of 18µm. This was accomplished through the amplification of a two color-seed with peaks at 1040nm and 1110nm, through a two stage amplification without any compression. The mid-infrared radiation (MIR) was generated with a 4.5 ps pulse duration by the method of difference-frequency mixing, using 300 mW of average power from the two-color Yb-fiber amplifier. Because there was no limitation by two-photon absorption, MIR output power could be scaled by increasing the amplifier power. The current project aims to increase the peak power of the laser pulses to improve the efficiency of the nonlinear mixing. The two-colour seed is generated by continuum generation in a photonic crystal fibre, pumped by 200 mW of average power from a mode-locked Yb:fibre laser. In order to efficiently increase the energy of the two wavelengths, the 4.6 mW seed pulse is now pre-amplified up to 21 mW in a 2.7 m length single mode, single core Yb:fibre . The pre-amplifier used a double-ended pumping scheme with two single mode diode lasers at 976 nm each having 150 mW maximum pump power. A notch filter was placed in the output beam to eliminate any Amplified Spontaneous Emission. After further amplification in a 7 m length of double clad, Yb-fibre, a maximum average power of 727 mW was achieved for two colours peaked at 1035 nm and 1105 nm wavelengths. The pump power for this stage was 6 W. A grating stretcher is now used to select the two-colour input along with stretching the pulses. A three grating compressor is used to compress the output pulses to 466 fs pulse duration. After compression the average power of the two colours is 350 and 110 mW for wavelengths at 1035 and 1105nm, respectively. These higher power pulses are planned to be used to increase the mid-infrared generation efficiency.

The goal of this thesis is developing a two-color Ytterbium (Yb) fiber amplifier system that can be used for generation of mid-infrared radiation. Previously, our group reported generating 20 µW of average power, at a wavelength of 18µm. This was accomplished through the amplification of a two color-seed with peaks at 1040nm and 1110nm, through a two stage amplification without any compression. The mid-infrared radiation (MIR) was generated with a 4.5 ps pulse duration by the method of difference-frequency mixing, using 300 mW of average power from the two-color Yb-fiber amplifier. Because there was no limitation by two-photon absorption, MIR output power could be scaled by increasing the amplifier power. The current project aims to increase the peak power of the laser pulses to improve the efficiency of the nonlinear mixing. The two-colour seed is generated by continuum generation in a photonic crystal fibre, pumped by 200 mW of average power from a mode-locked Yb:fibre laser. In order to efficiently increase the energy of the two wavelengths, the 4.6 mW seed pulse is now pre-amplified up to 21 mW in a 2.7 m length single mode, single core Yb:fibre . The pre-amplifier used a double-ended pumping scheme with two single mode diode lasers at 976 nm each having 150 mW maximum pump power. A notch filter was placed in the output beam to eliminate any Amplified Spontaneous Emission. After further amplification in a 7 m length of double clad, Yb-fibre, a maximum average power of 727 mW was achieved for two colours peaked at 1035 nm and 1105 nm wavelengths. The pump power for this stage was 6 W. A grating stretcher is now used to select the two-colour input along with stretching the pulses. A three grating compressor is used to compress the output pulses to 466 fs pulse duration. After compression the average power of the two colours is 350 and 110 mW for wavelengths at 1035 and 1105nm, respectively. These higher power pulses are planned to be used to increase the mid-infrared generation efficiency.