One of the most important industrial uses of pyrotechnic compositions is as delay fuses in electric detonators. Many factors influence the rate of burning of such fuses. These include (a) the primary choice of chemical components, followed by (b) the physical properties of these components, particularly the particle-size and distribution of the fuel, (c) the composition of the system chosen and (d) the presence of additives and/or impurities. A full experimental study of the influences of even a few of these factors, while attempting to hold other potential variables constant, would be extremely time consuming and hence attention has been focused on the possibilities of modelling pyrotechnic combustion. Various approaches to the modelling of pyrotechnic combustion are discussed. These include:- (i) one-dimensional finite-difference models; (ii) two-dimensional finite-element models; (iii) particle-packing considerations; (iv) Monte Carlo models. Predicted behaviour is compared with extensive experimental information for the widely-used antimony/potassium permanganate pyrotechnic system, and the tungsten /potassium dichromate pyrotechnic system. The one-dimensional finite-difference model was investigated to give a simple means of investigating the effects of some parameters on the combustion of a pyrotechnic. The two-dimensional finite-difference model used similar inputs, but at the expense of considerably more computer power, gave more extensive information such as the shape of the burning front and the temperature gradients throughout the column and within the casing material. Both these models gave improved results when allowance was made for autocatalytic kinetics in place of the usual assumption of an "order-of-reaction", n ≤ 1. The particle-packing model investigated the qualitative relationship between the maximum burning rate of a pyrotechnic system and the maximum number of contact points (per 1.00 g composition) calculated for that system. Qualitative agreement was found for those systems which are presumed to burn mainly via solid-solid reactions. The Monte Carlo model investigated the effect of the random packing of fuel and oxidant particles on the variability of the burning rate of a pyrotechnic composition.

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Thesis (M. S.)--Aerospace Engineering, Georgia Institute of Technology, 2009. / Committee Chair: Menon, Suresh; Committee Member: Ruffin, Stephen; Committee Member: Sankar, Lakshmi; Committee Member: Seitzman, Jerry; Committee Member: Stoesser, Thorsten

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A dissertation submitted to the faculty of Engineering and the Built Environment, University of the Witwatersrand, in fulfillment of the requirements for the degree of Master of Science in Engineering. 21 November 2016 / In this work a comprehensive exergy analysis and heat integration study was carried out on a coal based oxy-combustion power plant simulated using ASPEN plus. This is an extension on the work of Fu and Gundersen (2013). Several of the assumptions made in their work have been relaxed here. Their impact was found to be negligible with the results here matching closely with those in the original work. The thermal efficiency penalty was found to be 9.24% whilst that in the original work was 9.4%. The theoretical minimum efficiency penalty was determined to be 3% whilst that in the original work was 3.4%. Integrating the compression processes and the steam cycle was determined to have the potential to increase net thermal efficiency by 0.679%. This was close to the 0.72% potential reported in the original work for the same action. / MT2017

Pulsed Detonation Engines (PDEs) have the potential to revolutionize fight by better utilizing the chemical energy content of reactive fuel/air mixtures over conventional combustion processes. Combustion by a super-sonic detonation wave results in a significant increase in pressure in addition to an increase in temperature. In order to harness this pressure increase and achieve a high power density, it is desirable to operate PDEs at high frequency. The process of detonation initiation impacts operating frequency by dictating the length of the chamber and contributing to the overall cycle time. Therefore a key challenge in the development of a practical PDEs is the requirement to rapidly initiate a detonation in hydrocarbon-air mixtures. This thesis evaluates the influence of spark energy and airflow velocity on this challenging initiation process. The influence of spark energy, number of sparks and airflow velocity on Deflagration-to-Detonation Transition (DDT) was studied during cyclic operation of a small-scale PDE at the General Electric Global Research Center. Experiments were conducted in a 50 mm square transitioning to cylindrical channel PDE with optical access operating with stoichiometric ethylene-air mixture. Total spark energy was varied from 250 mJ to 4 J and was distributed between one and four spark plugs located in the same axial location. Initial flame acceleration was imaged using high-speed shadowgraph and was characterized by the time to reach 20 cm from the spark plug. Measurements of detonation wave velocity and emergence time, the time it takes the detonation wave to exit the tube, was measured using dynamic pressure transducers and ionization probes. It was found that the flame front spread was faster at higher spark energies and with more spark locations. Initial flame acceleration was 16% faster for the 4-spark, 4 J case when compared to the baseline 1-spark, 1 J case. When looking at the effect of airflow on the influence of spark energy, it was found that airflow had a larger effect on emergence time at high energies, versus energies less than 1 J. Finally, for a selected case of 0.25 J spark energy and 4 sparks, the velocity of the fuel-air mixture during fill was found to have a varying influence on detonation initiation and emergence time.