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<p>G1 and G2 dendrimeric salicylaldimine ligands containing both substituted and unsubstituted aryl rings were synthesized via a Schiff base condensation of the appropriate salicylaldehyde and the peripheral amino groups of the corresponding G1 and G2 polypropyleneimine dendrimers. The new ligands were characterized using FTIR, 1H NMR and 13C NMR spectroscopy, elemental analysis and ESI mass spectrometry. The dendrimeric ligands were converted to multinuclear nickel complexes by reaction with nickelacetate. The metal complexes were characterized by FTIR spectroscopy, elemental analysis and ESI mass spectrometry.</p> <p>Some of the dendritic complexes were evaluated as catalyst precursors in the oligomerization of &alpha / -olefins such as ethylene and 1-pentene, using aluminium alkyls such as EtAlCl2 and modified methylaluminoxane (MMAO) as activators. All the dendrimeric catalysts evaluated are active in the oligomerization reactions. From the oligomerization results it was observed that there is a clear dendritic effect, in that both catalyst activity as well as selectivity are impacted by the dendrimer generation. In most cases it was observed that the second generation complexes show higher activity than the corresponding first generation complexes.</p> <p>The dendrimeric complexes were also evaluated as catalyst precursors in the vinyl polymerization of norbornene. In this case methylaluminoxane (MAO) were employed as an activator. Once again it was noted that a dendritic effect is operative, with second generation metallodendrimers having a higher activity than the first generation complexes.</p>

The Betic Cordillera of southern Spain is an orogen formed in response to convergence between Africa and Iberia, from the late Mesozoic to the present. The orogen consists of three main tectonic complexes, two of which have been subducted to depth, then exhumed back to the surface over short timescales. Subduction in the structurally higher of these complexes is relatively well constrained to the Eocene, but the timing of high-pressure metamorphism in the structurally lower complex, known as the Nevado-Filabride Complex, has been a topic of debate for several years due to conflicting geochronological data. Several proposed tectonic models for the Nevado-Filabride Complex are based on ages of single mineral phases. For example, models based primarily on 40Ar/ 39Ar dating on white mica in high-pressure schists require that the Nevado-Filabride and the overlying tectonic unit, the Alpujarride Complex, were coevally subjected to high-pressure metamorphism in the Eocene, and subsequently exhumed at different rates. More recent models, based on Lu-Hf dating on prograde garnets in eclogites, separate the timing of high-pressure metamorphism of the Nevado-Filabride Complex from the Alpujarride Complex by at least 10 m.y. We examine the viability of these models using multimineral Rb-Sr dating of blueschist and eclogite facies rocks in the Nevado-Filabride Complex. The multimineral isochron method uses the whole high-pressure mineral assemblage rather than a single phase, which allows testing for isotopic disequilibrium. Statistically valid Rb-Sr ages of two schists and one eclogite from the Nevado-Filabride Complex yield ages of 15.78+/-0.47, 15.8+/-1.1, and 17.6+/-1.1 Ma, respectively. The early Miocene Rb-Sr ages are in agreement with garnet Lu-Hf ages and zircon U-Pb ages for high-pressure conditions in the Nevado-Filabride Complex. The new ages imply that two episodes of subduction, punctuated by a period of extension and exhumation, occurred in the Western Mediterranean.

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D.Sc. / Please view full text to see abstract

A 10 km x 10 km study area in the western Bushveld Complex, south of the Pilanesberg Complex, was selected for testing the inversion of vertical component gravity (Gz) data to determine the geometry of the Bushveld Complex/Transvaal Supergroup contact. This contact has a density contrast of ~0.350 g.cm-3 making it a suitable target for gravity inversion. The resulting 3D gravity model agrees well with the 3D seismic interpretation, indicating that the depths determined from the seismic data are appropriate. The gravity inversion could be extended laterally to investigate regions without seismic data coverage. This methodology may prove useful where upwellings in the floor of the Bushveld Complex distort seismic data, but can be imaged by gravity inversions. The Gz dataset was created from converted Airborne Gradient Gravity (AGG) data, combined with upward continued ground Gz gravity data, providing extensive coverage. This combined dataset was used in an interactive, iterative 3D gravity inversion methodology used to model the geometry of the Bushveld Complex/Transvaal Supergroup contact and densities of the Bushveld Complex, Transvaal Supergroup and Iron-Rich Ultramafic Pegmatoids (IRUPs). The resulting 3D gravity model provides an acceptable first-pass model of the Bushveld Complex/Transvaal Supergroup contact. In the shallow south-west region of the study area, the steeply dipping contact was determined from borehole intersections. 3D seismic data was the only constraint towards the north-east, where the contact flattens out to a sub-parallel contact, at ~2 000 m depth. In the north-western section, the Bushveld Complex/Transvaal Supergroup contact is fault-bounded by a conjugate set of the Rustenburg Fault, causing the Bushveld to onlap the Transvaal sediments. In the southern region, the contact changes as the conjugate fault dies out, and the Bushveld Complex becomes layered/sub-parallel to Transvaal sediments. This, and other geological features (e.g. faulting, folding, dykes), can be explained in relation to the regional tectonic history, relating to motion along the Thabazimbi-Murchison Lineament (TML). Pre-Bushveld emplacement NW-SE far-field stress caused NW trending extensional features in the region (e.g. Rustenburg Fault). Re-orientation of the compressive force to NE-SW, in syn- to post-emplacement, caused compressive features in the region (e.g. open folds with axes trending NW). Ground gravity data (100 m x 100 m station- and line-spacing) were also inverted to obtain a 3D model of the overburden, constrained by borehole data. However, the inversion failed to satisfy the gravity data and borehole data simultaneously, relating to difficulties in modelling the regional gravity field and the gradational nature of the weathered contact. Several rapid variations in overburden thickness were mapped, with particular success in the high frequency ground gravity survey (30 m x 30 m station- and line-spacing) with the identification of a deeply weathered (~10 m deep) channel relating to an mapped fault.

by Wing-kwong Ip. / Bibliography: leaf 105 / Thesis (M.Phil.)--Chinese University of Hong Kong, 1983