Thesis (M.S.)--Virginia Polytechnic Institute and State University, 1994. / Vita. Abstract. Includes bibliographical references (leaves 75-77). Also available via the Internet.

High Concentrated Photovoltaics (H-CPV) promise a more efficient, higher power output than traditional photovoltaic modules. This is achieved by concentrating sunlight onto a small triple junction (CTJ) InGaP/InGaAs/Ge cell (ranging from 3.14 mm2 to 1 cm2) by using precision optical systems. These systems utilise non-imaging optics to concentrate and distribute the incident solar flux uniformly onto the CTJ device receiver to achieve maximum performance and power output from an H-CPV module. However, the performance of the device can be reduced due to the partial or complete absorption of a range of wavelengths present in the solar spectrum by the optical materials that are used for concentration. An investigation to determine the current density topographies of each subcell in a CTJ cell by multiple raster scans of an optical fibre receiver of a spectrometer in the plane of the aperture of the secondary’s optical element was conducted. Results showed that the physical properties of the optical elements’ material absorbed different amounts of the spectral content with respect to the subcell photosensitive wavelength regions. The facet properties of the primary optical Fresnel lens showed that the more rounded the Fresnel facets were, the lower the concentration of sunlight incident onto the CTJ cell. The increase in facet numbers showed an increase in scattering of the incident sunlight and chromatic aberrations. Chromatic aberration created by the refractive optics showed a variation in the amount of concentration on each individual subcell as well as the difference in intensity profiles across for the different subcells. Based on these results and the development of new multi-junction devices by industry, the performance of a four and six-junction device with the optical materials was investigated by simulations. The simulations showed that the careful integration of an additional subcell in a multi-junction device could rectify current mismatch between the subcells in the device. Based on the simulations, the best performing multi-junction cell was identified as the four-junction device that showed a cell and module efficiency under operation of 42.5 % and 35.5 %, respectively. Additionally, based on the performance results observed from the H-CPV module, the development of an HCPV module that would attempt to harness the incident tracked diffuse sunlight available to a concentrator photovoltaic (CPV) module for additional energy yield was undertaken. The part of the study comprised of measurements of the solar source, design of a prototype Hybrid High Concentrator Photovoltaic (HH-CPV) module. Results showed that power generation from the H-CPV system was highly dependent on the DNI levels and fluctuates greatly with variation in the DNI. The irradiance levels within the diffuse regions of the H-CPV module showed that the baseplate and vertical sides had an average irradiance range of 140-450 and 50-225 W.m-2, respectively. Irradiance topographic raster scans revealed that the baseplate and vertical sides had a relatively uniform intensity distribution and was identified as favourable sites for diffuse cell population. Simulations of various PV technologies showed the most suitable technology for the placement within the cavity of the HH-CPV module. The developed HH-CPV module was finalized with the utilization of CIS modules to harness the diffuse irradiance. During a 3 month power monitoring of the HH-CPV system, it was determined that the major power generation for the HH-CPV module come from the CPV component, while the CIS modules showed a minor power contribution. The total energy yield for the monitoring period was 45.99, 3.89 and 1.76 kW.h for the CPV, four-vertical sides and baseplate components, respectively. The increase in energy yield of the HH-CPV module when compared to the standard H-CPV module was determined to be 12.35 % for the monitoring period. The incorporation of the CIS modules into the H-CPV module to create the HH-CPV module did increase the energy yield of the module during high DNI conditions and did offset the almost zero power generation during low DNI conditions.

The process of Synchronization between two buses in a power system plays a vital role, especially during blackstart or bulk power system restoration period. The synchronization process is primarily monitored in the presence of experienced personnel at the substation level, which might not control or even predict the after effects of synchronization as soon as the synchronizing breaker between the two buses respective to the two islands is closed. However, with the advent of phasor measurement units (PMUs) providing time synchronized synchrophasor data, synchroscope functionality can now be implemented at a centralized remote control platform, usually the control room of the specific utility. This thesis presents a technique along with the actual implementation of such a PMU Synchroscope analytic developed as a part of the Department of Energy sponsored open and Extensible Control and Analytics platform for synchrophasor data (openECA project). The challenges faced to realize this functionality at the centralized remote location along with methods to overcome these hurdles have been discussed in the document. Additional features in comparison to the conventional synchroscope device are also added to facilitate a smoother and successful synchronization, reducing error on behalf of the user /operator and thus, facilitating a faster power system restoration. / Master of Science / Successful and proper synchronization between different nodes of a power system is one of the most crucial stages of restoring power after a major wide area electricity outage. Improper synchronization may lead to additional system outages and might delay the restoration process. In this regards, it is desired to perform this vital task at the electric utility’s central remote control room. This thesis develops an application to perform the successful reconnection between two nodes of a system overcoming the various challenges and incorporating system delays. The application designed is based on real-time measurements and is integrated with an open source framework platform for ease of the user.

The South African coal industry produces a large quantity of coal per annum. The rejects from various unit operations, such as spirals, consist of fine coal that joins the plants tailings dam waste. As existing high quality resources become depleted, the need to improve recovery of this fine coal grows. This project investigates the use of a teetered bed separator (TBS); a hindered settling gravity concentration device for fine coal recovery. This device has proven successful in the United Kingdom and in Australian collieries for fine coal separation in the size range between 2mm and 0.3mm. It has also been used for decades as a classifying device for silica sand and tin. The TBS operates in the size range of water-only cyclones and spiral concentrators, and could potentially be used to separate a broader size range of coal fines so as to offer a lower footprint device for the fines recovery section of a plant. Spiral concentrators cannot always be operated efficiently at a separating specific gravity of lower than 1.6; a TBS may also extend the density range for separation and thus improve recovery. The objective of this project was to gain a full understanding of the TBS from fundamental particle interaction and develop a lab scale unit, which is capable of separation to about 0.1mm at optimum conditions. This involved the development of design parameters based on the various distributor plates and flow pattern modelling. The hydrodynamics of the separator were investigated using the Eulerian-Eulerian modelling approach of commercial CFD package, Fluent 6.1. Seven distributor plates of varying aperture size and geometric arrangement were considered. Coal and shale particles, sized between 2mm and 0.038mm with a specific gravity (SG) range of 1.2 to 2.0, were separated using the laboratory scale unit. The results of both the simulations and the laboratory tests were then compared. The simulations revealed that Plate 3 was the best option for implementation. It had an even upward velocity profile compared to the other plates, with minimum wall effects and disturbances. The upward water flow rate (teeter water) was varied experimentally and the composition of the teeter bed, underflow and overflow were analysed using 1.5, 2 and Smm cubic density tracers with an SG range of 1.2-2.0. Analysis of the partition curves of the distributor plates revealed that Plate 3 had the lowest Ecart Probable (Ep) and cut- point densities. The comparison of simulated results and experimental results show that the simulator could predict the distributor plate design with the lowest Ep in practical tests. The simulator could be beneficial when optimising an industrial scale unit, by allowing prediction of improved segregation patterns and thus separation efficiency. / Thesis (M.Sc.)-University of KwaZulu-Natal, Durban, 2005.

In this study, commercially available Computational Fluid Dynamics (CFD) software, CFX-4.4 has been used for the simulations of aerosol transport through various aerosol-sampling devices. Aerosol transport was modeled as a classical dilute and dispersed two-phase flow problem. Eulerian-Lagrangian framework was adopted wherein the fluid was treated as the continuous phase and aerosol as the dispersed phase, with a one-way coupling between the phases. Initially, performance of the particle transport algorithm implemented in the code was validated against available experimental and numerical data in the literature. Code predictions were found to be in good agreement against experimental data and previous numerical predictions. As a next step, the code was used as a tool to optimize the performance of a virtual impactor prototype. Suggestions on critical geometrical details available in the literature, for a virtual impactor, were numerically investigated on the prototype and the optimum set of parameters was determined. Performance curves were generated for the optimized design at various operating conditions. A computational model of the Linear Slot Virtual Impactor (LSVI) fabricated based on the optimization study, was constructed using the worst-case values of the measured geometrical parameters, with offsets in the horizontal and vertical planes. Simulations were performed on this model for the LSVI operating conditions. Behavior of various sized particles inside the impactor was illustrated with the corresponding particle tracks. Fair agreement was obtained between code predictions and experimental results. Important information on the virtual impactor performance, not known earlier, or, not reported in the literature in the past, obtained from this study, is presented. In the final part of this study, simulations on aerosol deposition in turbulent pipe flow were performed. Code predictions were found to be completely uncorrelated to experimental data. The discrepancy was traced to the performance of the code's turbulent dispersion model. A detailed literature survey revealed the inherent technical deficiencies in the model, even for particle dispersion. Based on the results of this study, it was determined that while the code can be used for simulating aerosol transport under laminar flow conditions, it is not capable of simulating aerosol transport under turbulent flow conditions.

In this study, commercially available Computational Fluid Dynamics (CFD) software, CFX-4.4 has been used for the simulations of aerosol transport through various aerosol-sampling devices. Aerosol transport was modeled as a classical dilute and dispersed two-phase flow problem. Eulerian-Lagrangian framework was adopted wherein the fluid was treated as the continuous phase and aerosol as the dispersed phase, with a one-way coupling between the phases. Initially, performance of the particle transport algorithm implemented in the code was validated against available experimental and numerical data in the literature. Code predictions were found to be in good agreement against experimental data and previous numerical predictions. As a next step, the code was used as a tool to optimize the performance of a virtual impactor prototype. Suggestions on critical geometrical details available in the literature, for a virtual impactor, were numerically investigated on the prototype and the optimum set of parameters was determined. Performance curves were generated for the optimized design at various operating conditions. A computational model of the Linear Slot Virtual Impactor (LSVI) fabricated based on the optimization study, was constructed using the worst-case values of the measured geometrical parameters, with offsets in the horizontal and vertical planes. Simulations were performed on this model for the LSVI operating conditions. Behavior of various sized particles inside the impactor was illustrated with the corresponding particle tracks. Fair agreement was obtained between code predictions and experimental results. Important information on the virtual impactor performance, not known earlier, or, not reported in the literature in the past, obtained from this study, is presented. In the final part of this study, simulations on aerosol deposition in turbulent pipe flow were performed. Code predictions were found to be completely uncorrelated to experimental data. The discrepancy was traced to the performance of the code's turbulent dispersion model. A detailed literature survey revealed the inherent technical deficiencies in the model, even for particle dispersion. Based on the results of this study, it was determined that while the code can be used for simulating aerosol transport under laminar flow conditions, it is not capable of simulating aerosol transport under turbulent flow conditions.

Concentrating Photovoltaic systems are good candidates for low cost and clean electricity generation from solar energy. CPV means replacing much of the expensive semiconductor photovoltaic cells with the cheaper optics. Although the idea is simple, CPV systems have several problems inherent to their system design, such as module thickness, expensive PV cells and overheating. Light guide systems are good alternatives to classical CPV systems that can clear off most of the problems of those systems. In this thesis we explore a new light-guide based solar concentrator by optical design and simulations. It is shown that this solar concentrator can reach 1000x geometric concentration, 96.5% optical efficiency with a &plusmn / 1 degree acceptance angle. As a result of simulations, effectiveness of the horizontally staggered light guide solar concentrators is proved. A practical module study is carried on to improve the knowledge related to light guide CPV systems. The concentrator geometry is fabricated as a medium concentrator system with a geometric concentration of 45x and +-2 degrees acceptance angle. With the prototype level injection molding 74% optical efficiency is achieved and can be improved with a better mold manufacturing. A cost analyses is also performed with real manufacturing parameters and it is shown that grid parity can be achieved with this kind of light guide solar concentrators.

This research investigates the collection of concentrating solar energy and its transmission through optical fibres for use in high temperature applications such as lunar in-situ resource utilisation (ISRU) programmes, solar power generation and solar surgery. A prototype collector, known as the Fibre Optic Concentrating Utilisation System (FOCUS), has been developed and is capable of delivering high energy fluxes to a remote target. Salient performance results include flux concentrations approaching 1000 suns with an overall optical efficiency of 13%, measured from the inlet of the collector to the fibre outlet. The system comprises a novel solar concentrator designed to inject solar energy into a four metre long fibre optic cable for the transmission of light to the target. A nonimaging reflective lens in the form of a 600 mm diameter ring array concentrator was chosen for the collection of solar energy. Advantageous characteristics over the more common parabolic dish are its rearward focusing capacity and single stage reflection. The ring array comprises a nested set of paraboloidal elements constructed using composite material techniques to demonstrate a low-cost, effective fabrication process. At concentrator focus, a fibre optic cable of numerical aperture 0.37 is positioned to transport the highly concentrated energy away from the collector. The cable is treated to withstand UV exposure and high solar energy flux, and allows flexibility for target positioning. A computational analysis of the optical system was performed using ray tracing software, from which a predictive model of concentrator performance was developed to compare with experimental results. Performance testing of FOCUS was conducted using energy balance principles in conjunction with a flat plate calorimeter. Temperatures approaching 1500°C and flux levels in the region of 1800 suns were achieved before injection to the cable, demonstrating the optical system's suitability for use in high flux applications. During testing, peak temperatures exceeding 900°C were achieved at the remote target with a measured flux of 104 W/cm2 at the cable outlet. The predicted optical efficiency was 22%, indicating that further refinements to the ray trace model are necessary, specifically with regard to losses at the inlet to the cable. FOCUS was able to demonstrate its usefulness as a test bed for lunar in-situ resource utilisation technologies by successfully melting a lunar soil simulant. The system permits further terrestrial-based ISRU research, such as oxygen production from regolith and the fabrication of structural elements from lunar soil. / Thesis (M.Sc.Eng.)-University of KwaZulu-Natal, Durban, 2011.

Lanthanide (III) complexes are used extensively in solar conversion devices, such as Luminescent Solar Concentrators (LSCs) and Luminescent Down-Shifting (LDS) for their peculiar characteristics of narrow band emission, avoidance of re-absorption losses due to large Stokes shift and possibility of high photoluminescence quantum yield (PLQY). The study has looked into the synthesis of Ln (III) complexes of the general formula: [Ln(hfac)3DPEPO], where DPEPO = bis(2-(diphenylphosphino)phenyl)ether oxide, and hfac = hexafluoroacetylacetonate. The work presented in this thesis focuses on the synthesis, and subsequent photophysical characterisation of these Ln(III) complexes, plus characterisation and spectroscopic study of [Tb(pobz)3(hacim)2], (where Hpobz = phenoxybenzoic acid, and Hacim = acetylacetone imine), yielding results that open new design of functional Ln(III) systems. Spectroscopic study of Chromium dioxalate and analogous compounds has revealed that with the appropriate design, Cr(III)Ln(III) energy transfer can be achieved, while study of polyaromatic hydrocarbons (PAH) such as coronene, enable to explore a ligand with better absorption in the whole UV region. These results open attractive perspectives for light-conversion systems, such as LSC devices.

Thesis (M. S.)--Mechanical Engineering, Georgia Institute of Technology, 2008. / Committee Chair: Sheldon Jeter; Committee Member: Sam Shelton; Committee Member: Srinivas Garimella