Yes / With the technological advances in the field of building materials, there has been an increasing focus on the research of lightweight concrete made with coated aggregates for improving the durability of concrete. In this study, pumice aggregates were coated with cast-based polyester to obtain polymer-coated pumice aggregates (PCPA). Lightweight concretes were produced with different cement dosages (200, 250 and 300) and PCPAs at different ratios (0%, 50% and 100%). Physical properties, mechanical strength, thermal properties and internal structure analysis (SEM-EDS) of the produced concrete samples were performed. According to the RILEM functional classification of lightweight concrete, the test results showed that REF D300 and REF D250 dosage series are in the semi-load-bearing lightweight concrete class, and the other all series are in the insulation concrete class, and the produced concretes can be classified as lightweight insulation materials. It can also be used in non-load-bearing walls or as an alternative lightweight insulation material. / The first author wish to thank the support of Scientific and Technical Research Council (TUBITAK) BIDEB-2219 Postdoctoral Research (Project Number: 1059B192100644) and the second author also thank to the Düzce University.

The immediate goal of this thesis was the analysis of a three-component system whose major component was water. This analysis was to be the result of a procedure which could be readily extended to more complex systems.

The main objective of the thesis is to study the thermal properties of Si-based polymer derived ceramics (PDCs) at elevated temperatures and to classify the main factors affecting the thermal transport through these ceramics. The polymer derived ceramics with the chemistry Si- O-C-N were prepared starting from commercial polycarbosilane, polysiloxane, and polysilazane precursors. These precursors are cross-linked at room temperature to obtain the preceramic, followed by controlled pyrolysis (at different temperatures ranging from 1200 oC to 1800 oC in argon, nitrogen or carbon-di-oxide atmospheres), to get the final ceramic. The first part of the thesis discusses on development and studies of dense polymer derived thin disks having a basic chemistry, Si-C, Si-O- C, and, Si-C-N-O, developed via a casting technique followed by specific pyrolysis cycles. Having a thickness in the range of 100 μm- 300 μm, these ceramic disks were studied to be nanocrystalline/amorphous at least up to a temperature of 1400 oC and were found to have a significant amount of Cfree phase existing in them along with the intended chemistry. The high-temperature thermal properties were primarily investigated on ceramics prepared at a pyrolysis temperature of 1200 oC (ceramic still in nanocrystalline/amorphous glassy phase). The disks were found to have very low expansion coefficients (CTE) measured up to ~900 oC and the thermal diffusivity (k) and thermal conductivity (l) of these disks were also measured. An attempt to understand the influence of the different phases in a SiOC ceramic (mainly the Cfree phase, studied by enriching the carbon percentages using DVB) in determining the final thermal properties was also conducted. The influence of carbon enrichment on the mechanical properties of these disks is also studied as a sub-part of this work. The second part of the work deals with testing the possibility to use these ceramics for high-temperature insulation applications. ‘Reticulated’ ceramic foams of relatively same chemistries as that of the disks were prepared by a template replica approach, using polyurethane (PU) foams (more open-celled to more closed-celled types of PU foams were used in the study) as the template. Porous structures having densities ranging from as low as 0.02 g.cm-3 to 0.56 g.cm-3 and with a porosity ~ 80 % to ~99% were prepared and tested. The developed foams showed excellent thermal stability up to a temperature of 1400 oC and possessed very low thermal expansion. The thermal conductivity measured on them at RT gave values in the range 0.03 W.m-1.K-1- 0.25 W.m-1.K-1. A Gibson-Ashby modeling approach to explain the thermal conductivity of the porous ceramics was also attempted. The developed foams were also found to be mechanically rigid. In a nutshell, the thesis work studies the thermal properties of Si-O-C- N ceramics in detail and probes into the possibility to develop these class of Si-O-C-N ceramics into promising high-temperature insulation material.

This study focused on determining the groundwater flow paths in the crystalline subsurface rocks of the Bulawayo metropolitan, Zimbabwe, through analysing the discontinuities of the electrical properties of the ground, as well as in the magnetic field of the underlying rocks. Further, borehole water quality was analysed by measuring and mapping several chemical parameters, specifically TDS, salinity and the electrical conductivity. The electrical and magnetic anomalies were measured at two field sites within the Bulawayo province, the Harry Allen Golf Course and the Barbour Fields dumpsite, while 120 boreholes were sampled for water quality in a large part the province. Two magnetometers were used to measure the magnetic field and the time and location of the measurements, which resulted, after processing in SURFER, into the magnetic field map of these areas. This was used, in conjunction with the geologic map of the Bulawayo province, in order to determine useful locations for the electrical resistivity surveys. These included electrical resistivity tomography and vertical electrical sounding and were performed with an earth resistivity/induced polarization (IP) meter in order to measure the electrical resistivity of the ground. Inverse modelling was used in the RES2DINV software program to produce the topographic image of resistivity. The results for the borehole sampling showed that the maps for the three chemical parameters were very similar, with the western and northern parts of the mapped area displaying higher concentration values. The results of the electrical resistivity surveying showed probable areas of groundwater flow with its relationship to electric conductivity.

This dissertation presents an investigation of the properties, especially the electrical properties, of doped ZnO films grown by plasma-assisted molecular beam epitaxy (MBE) under different conditions. The interest in investigating ZnO films is motivated by the potential of ZnO to replace the currently dominant ITO in industries as n-type transparent electrodes and the difficulty in achieving reliable and reproducible p-type ZnO. On the one hand, n-type ZnO heavily doped with Al or Ga (AZO or GZO) is the most promising to replace ITO due to the low cost, abundant material resources, non-toxicity , high conductivity, and high transparency. On the other hand, ZnO doped with a large-size-mismatched element of Sb (SZO) or co-doped with N and Te exhibits the possibility of achieving p-type ZnO. In this dissertation, the effects of MBE growth parameters on the properties of GZO have been investigated in detail. The ratio of oxygen to metal (Zn+Ga) was found to be critical in affecting the structural, electrical, and optical properties of GZO layers as revealed by x-ray diffraction (XRD), transmission electron microscopy (TEM), Hall measurement, photoluminescence (PL), and transmittance measurements. Highly conductive (~2×10-4 Ω-cm) and transparent GZO films (> 90% in the visible spectral range) were achieved by MBE under metal-rich conditions (reactive oxygen to incorporated Zn ratio < 1). The highly conductive and transparent GZO layers grown under optimized conditions were applied as p-side transparent electrodes in InGaN-LEDs, which exhibited many advantages over the traditional thin semi-transparent Ni/Au electrodes. The surface morphologies of GaN templates were demonstrated to be important in affecting the structural and electrical properties of GZO layers. In those highly conductive and transparent GZO layers with high-quality crystalline structures, studies revealed ionized impurity scattering being the dominant mechanism limiting the mobility in the temperature range of 15-330 K, while polar optical phonon scattering being the mechanism responsible for the temperature-dependence for T>150 K. The majority Sb ions were found to reside on Zn sites instead of O sites for lower Sb concentrations (~0.1 at.%), which can lead to a high electron concentration of above 1019 cm-3 along with a high electron mobility of 110 cm2/V-s at room temperature. The reduction in electron concentration and mobility for higher Sb concentrations (~1 at.%) was caused by the deterioration of the crystalline quality. ZnO co-doped with N and Te was also studied and the advantages of the co-doping technique and problems in achieving p-type conductivity are discussed.

O presente trabalho teve por objetivo avaliar o potencial do ensaio de ascensão capilar e de uma técnica de otimização de parâmetros para estimar os parâmetros hidráulicos dos solos. O ensaio de ascensão capilar é de execução simples e rápida e reflete um fenômeno condicionado pelas propriedades hidráulicas do solo. Na representação matemática da ascensão capilar, utilizou-se o modelo de Terzaghi (1943) que considerou tratar-se de uma condição de fluxo governada pela condutividade hidráulica saturada (ks), e o modelo de Lu & Likos (2004b), que utilizaram a equação de Gardner (1958) para representar a função condutividade hidráulica, considerando que o fluxo se dá em meio não saturado. O processo de otimização utilizou a rotina SOLVER componente do programa EXCEL, e foi testado utilizando-se os dados experimentais de Lane & Washburn (1946) e de Zhang & Fredlund (2009). Em seguida, resultados de ascensão capilar de oito amostras de solos típicos do Estado do São Paulo, Brasil, foram modelados com os parâmetros derivados da técnica. Observou-se que tanto o modelo de Terzaghi (1943) quanto o de Lu & Likos (2004b) conseguiram reproduzir os resultados experimentais de ascensão capilar, com melhores resultados associados ao modelo de Lu & Likos (2004b) para a maior parte dos solos analisados. A previsão da condutividade hidráulica saturada, de forma geral, diferiu menos de uma ordem de grandeza dos valores medidos experimentalmente, embora maiores discrepâncias tenham sido notadas para determinados tipos de solos. O parâmetro de Gardner da função condutividade hidráulica resultou em valores da mesma ordem de grandeza dos valores reportados na literatura para solos similares. Os resultados sobre a aplicação do ensaio de ascensão capilar e da técnica de otimização mostraram-se promissores para a determinação de parâmetros hidráulicos dos solos analisados, com a vantagem de ter-se um procedimento simples e rápido para a finalidade descrita. / This study evaluates the potential of capillary rise test and a parameter optimization technique to estimate soil hydraulic parameters. The capillary rise is a simple and expedite test that is conditioned by soil hydraulic properties. In the mathematical representation of the capillary rise we used the model of Terzaghi (1943), who considered that saturated hydraulic conductivity commands the phenomeno and the model of Lu & Likos (2004b) who used the Gardner equation (1958) to represent the hydraulic conductivity function, considering that the flow takes place in a non-saturated condition. The optimization process used the SOLVER routine, component of the EXCEL program, that was firstly tested using experimental data of Lane & Washburn (1946) and Zhang & Fredlund (2009). Then, results of capillary rise of eight samples of typical soils of the State of São Paulo, Brazil, were modeled with the parameters derived from the technique. It was observed that both the Terzaghi (1943) and Lu & Likos (2004b) models were able to reproduce the experimental results of capillarity, although the best results were yielded by the model Lu & Likos (2004b) for most soils. The prediction of saturated hydraulic conductivity, in general, differed less than one order of magnitude of experimentally measured values, although larger discrepancies have been noted for certain types of soils. The resulting Gardner parameter of the hydraulic conductivity function were of the same order of magnitude of the values reported in the literature for similar soils. The results on the application of capillary rise test and optimization technique proved promising for the determination of soil hydraulic parameters analyzed, with the advantage of having a simple and rapid procedure for the purpose described.

The goal of this research is to show the feasibility of detecting density variations in green-state powder metallurgy (P/M) compacts from surface voltage measurements. By monitoring a steady electric current flow through the sample and recording the voltages over the surface, valu-able information is gathered leading to the prediction of the structural health of the compacts. Unlike prior research that concentrated on the detection of surface-breaking and subsurface de-fects, the results presented in this thesis target the density prediction throughout the volume of the sample. The detection of density variations is achieved by establishing a correlation between the conductivity and their respective density. The data obtained from the surface measurements is used as part of an inversion algorithm, calculating the conductivity distribution, and subse-quently the density within the compact. In a first step, the relationship between conductivity and density of green-state P/M com-pacts was investigated. Tests were conducted for a number of parts of various powder mixtures. In all cases a clear correlation between conductivity and density could be established, indicating that measurements of electric conductivity could indeed be exploited in an effort to render valid information about the density of the sample under test. We found a linear correlation for non-lubricated parts and a non-linear behavior for lubricated samples. Specifically, it was found that the conductivity increases with increasing density only up to a maximum value obtained at ap-proximately 6.9g/cm3. Interestingly, any additional density increase leads to a reduction of the conductivity. This behavior was confirmed to be inherent in all powder mixtures with lubricants. The thesis research is able to provide a physical model and a mathematical formulation describ-ing this counter-intuitive phenomenon. A finite element solver in conjunction with an inversion algorithm was then implemented to study arbitrarily shaped part geometries. Based on the principles of electric impedance imag-ing, the developed algorithm faithfully reconstructs the density distribution from surface voltage measurements. The feasibility of the instrumentation approach for both simple and complex parts can be demonstrated using a new sensor concept and measurement arrangement. Measurements were performed on both geometrically simple and complex parts.

The positive temperature coefficient of resistivity (PTCR) sensors is resistor materials that undergo a sharp change in resistivity at a designed Curie temperature due to its unique structure and chemical composition. This effect serves important control functions in a wide variety of electronic circuitry and similar applications. Conventional calcining of mixed oxides method (CMO) is used for fabricating lanthanum doped barium titanate (BaTiO3) for PTCR behaviour through solid-state-sintering route, at 1100°C, 1350°C. Two batches of samples were fabricated at low and high sintering temperatures of 1100°C, 1350°C respectively. The effect of different concentrations of donor dopant on BaTiO3 on the electrical properties of Ba(1-x)LaxTiO3 with x= 0.0005, 0.001, 0.002, 0.0025, 0.003 mol%, is investigated at low sintering temperature. The influence of lantanum doping with Al2O3+SiO2+TiO2 (AST) as sintering aids on the electrical properties of Ba(1-x)LaxTiO3 with x= 0.0005, 0.001, 0.003 mol%, is also investigated. The results of the electrical characterization for the first batch of samples showed an increase in room temperature resistance with increaisng donor concentration. Also the results of the electrical characterization for the second batch of samples also showed the same increase in room temperature resistance with increasing donor concentration. For first batch of sensors the high room temperature resistance keeps the jump small and these materials showed V-shaped NTCR-PTCR multifunctional cryogenic sensor behavior with a strong negative coefficient of resistance effect at room temperature.Where as the second batch of sensors showed few orders of magnitude rise in resistivity values. The La-doped BaTiO3 ceramics co-doped with Mn gives an enhanced PTCR effect which can be exploited for various sensor applications.

No description available.

The present work provides a micromechanics approach based on the generalized self-consistent composite cylinders method as a non-Eshelby approach towards for assessing the impact of carbon nanotubes on the multi-functional nature of nanocom-posites in which they are a constituent. Emphasis is placed on the effective elastic properties as well as electrical and thermal conductivities of nanocomposites con-sisting of randomly oriented single walled carbon nanotubes in epoxy. The effective elastic properties of aligned, as well as clustered and well-dispersed nanotubes in epoxy are discussed in the context of nanotube bundles using both the generalized self-consistent composite cylinders method as well as using computational microme-chanics techniques. In addition, interphase regions are introduced into the composite cylinders assemblages to account for the varying degrees of load transfer between nanotubes and the epoxy as a result of functionalization or lack thereof. Model pre-dictions for randomly oriented nanotubes both with and without interphase regions are compared to measured data from the literature with emphasis placed on assessing the bounds of the effective nanocomposite properties based on the uncertainty in the model input parameters. The generalized self-consistent composite cylinders model is also applied to model the electrical and thermal conductivity of carbon nanotube-epoxy nanocomposites. Recent experimental observations of the electrical conductivity of carbon nanotube polymer composites have identified extremely low percolation limits as well as a per-ceived double percolation behavior. Explanations for the extremely low percolation limit for the electrical conductivity of these nanocomposites have included both the creation of conductive networks of nanotubes within the matrix and quantum effects such as electron hopping or tunneling. Measurements of the thermal conductivity have also shown a strong dependence on nanoscale effects. However, in contrast, these nanoscale effects strongly limit the ability of the nanotubes to increase the thermal conductivity of the nanocomposite due to the formation of an interfacial thermal resistance layer between the nanotubes and the surrounding polymer. As such, emphasis is placed here on the incorporation of nanoscale effects, such as elec-tron hopping and interfacial thermal resistance, into the generalized self-consistent composite cylinder micromechanics model.