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published_or_final_version / Earth Sciences / Doctoral / Doctor of Philosophy

Thesis (MSc)--Stellenbosch University, 2005. / ENGLISH ABSTRACT: The availability of multispectral data from the satellite-borne ASTER (Advanced Space borne Thermal Emission Reflection Radiometer) sensor with 14 spectral bands, launched on 18 December 1999, ushers in a new dimension in large-scale mineral exploration. The ASTER bands are strategically positioned to map distinctive absorptive features for mapping alteration mineralogy, which has increased the potential to map hydrothermal alteration zones as compared to the conventional Landsat TM satellite and aerial photographs. This research tests the ability of ASTER to map hydrothermal alteration zones by applying various image enhancement techniques and comparing them. The study area is the Haib copper prospect in Namibia. The Crosta technique, standard colour composites, spectral band ratioing, the software defoliant technique, log residuals and spectral linear unmixing were applied and compared against results from the previous detailed geophysical and geochemical exploration. The results from all the techniques corresponded with published geological maps from previous work and indicated ASTER's ability to detect alteration zonations. Comparison of the methods applied showed that choice of technique is usually dependent of the level of detail which one seeks to achieve. Standard colour composite and log residuals are more useful for a generalized overview of the alteration mineralogy, whilst uniquely defining mineral end members is achieved by application of the Crosta technique, ratioing and spectral linear unmixing. Application of the software defoliant techniques involved ratioing results, which are affected by spectral interferences from other minerals. The presence of a highly fractured system has been established by application of Sobel filtering. A spatial association of the extracted fracture system with alteration areas suggest mineralization at the Haib is fracture controlled. The results support the presence of argillicphyllic and prophylitic alteration zones on a regional scale, a scenario which can be equated to the Lowell-Guilbert model. The potassic-phyllic zone boundary could not be spectrally detected which also supports previous studies which suggest the potassic zone is nondefinitive and is over-printed by the phyllic zone. The results demonstrate that ASTER is an effective tool to map hydrothermal alteration systems in arid areas. / AFRIKAANSE OPSOMMING: Multispektrale data van die ASTER (' Advanced Space Borne Thermal Emmission Reflection Radiometer') sensors bestaande uit 14 spektrale bande, afkomstig van 'n satelliet gelanseer op 18 Desember 1999 lui 'n nuwe era in vir grootskaalse minerale eksplorasie. Die ASTER bande is strategies sodanig op die spektrum geposisioneer om onderskeidende absorberende verskynsels van veranderde mineralisasie te identifiseer. Hierdie data het die potensiaal verhoog om hidrotermale veranderingstelsels meer suksesvol te karteer as met konvensionele Landsat TM beelde en lugfotos. Hierdie navorsing toets die vermoeëns van ASTER om hidrotermale veranderingstelsels te karteer deur 'n wye reeks beeldverrykings tegnieke toe te pas en te vergelyk. Die studiegebied IS die Haib koperafsetting in Namibië. Die Crosta tegniek, standaard kleursamestellings ('colour composites'), ratio-tegnieke, plantegroeistroping ('software defoiliant'), log residuele ('log residual '), en spektrale lineêre ontmenging ('spectral linear unmixing') is toegepas en die resultate met vorige gedetailleerde geofisiese en geo-chemiese veldopnames te vergelyk. Die verkreë resultate van al die verskillende tegnieke het grootliks met gepubliseerde geologiese kaarte van die gebied ooreengestem en bevestig dat ASTER data geskik is om sulke mineralogies veranderde gebiede te karteer. Vergelykings tussen die tegnieke het getoon dat die keuse van tegniek bepaal word deur die vlak en tipe detail wat verlang word. Standaard kleursamestellings en die log residuele tegnieke lewer goeie resultate om veralgemeende oorsigte van mineralogies veranderde sones te verskaf, terwyl die Crosta-, ratio- en spektrale lineêre ontmengingstegnieke meer suksesvol is om spesifieke minerale te identifiseer. Die plantegroei stropingtegniek is nodig in gevalle waar spektrale ratios deur plantegroeiresponse geaffekeer word. Die aanwesigheid van 'n intensief gefraktuurde sisteem is bepaal deur 'n Sobel filter toe te pas. Ruimtelike assosiasies tussen die voorkoms van die gefraktuurde sone met en die minealogies gewysigde sones dui aan dat mineralogiese wysiging in die Haib gebied deur frakturering beheer is. Die resultate steun die aanwesigheid van argillities-fillitiese enpropolities gewysigde sones op 'n streekskaal, 'n scenario wat deur die Lowell-Guilbertmodel voorgehou word. Die grense van die kalium-fillitiese sone kon nie spektraal waargeneem word nie. Dit steun ook vorige studies wat suggereer dat die kaliumsone nieafbakenbaar is en waarskynlik deur die fillitiese sone oorlê word. Die resultate bevestig onomwonde dat ASTER data benut kan word om hidrotermaal veranderde sones in semiariede gebiede effektief te karteer.

Kansanshi mine sulphide ore circuit did not achieve target flotation recovery in 2016, hence it was deemed necessary to carry out a research aimed at optimizing this circuit. The objective of the research was to optimise the Kansanshi milling and flotation circuit processing a copper sulphide ore. In line with this, samples were obtained around the circuit and processed in the laboratory for moisture content, slurry concentration, particle size distribution, and flotation response. This information was then used to build a computer-based model of the Kansanshi milling and flotation circuit. This was done in MODSIM®, a software package specialising in the design and simulation of mineral processing operations. After careful appraisal, appropriate models were selected for the semi autogenous grinding (SAG) and ball mills, SAG mill discharge screen, hydrocyclones, pebble crusher, and the flotation cells. The calibrated model was then used to simulate the effects of key operating parameters on flotation recovery. Analysis using the attainable region technique revealed that the SAG mill feed-rate should be adjusted from 1719 tph to 2090 tph. This would lead to a better utilisation of the pebble crusher that can process 358 tph of pebbles from the current 198 tph. From the simulation work, it was established that rougher flotation recovery can be improved from the current 80.0 % to 82.3 %. The technoeconomic benefits of the proposition are yet to be investigated. Findings from the research concluded that the milling circuit optimum operating parameter; which generated a final product falling predominantly in the range - 150 +38 μm were SAG and ball mills conditions of ball sizes 200 and 40mm respectively, ball mill ball filling 32% and rotational speed between 75 and 80% for both SAG and ball mills. The optimum hydrocyclone feed slurry concentration was found to be 62% solids. Additionally, the SAG mill discharge screen aperture size of 6 mm was the optimum. It must be noted that slurry concentration did not show any impact on both the SAG and ball mills performance. The SAG mill ball filling did not show any significant improvement on performance. / College of Engineering, Science and Technology / M. Tech. (Chemical Engineering)

Use of Re-Os systematics in sulfides from the Bagdad porphyry Cu-Mo deposit provide information on the timing of mineralization and the source of the ore -forming elements. Analyzed samples of pyrite, chalcopyrite and molybdenite mainly from the quartz monzonite and porphyritic quartz monzonite units are characterized by a moderate to strong potassic alteration (secondary biotite and K- feldspar). Rhenium concentrations in molybdenite are between 330 and 730 ppm. Two molybdenite samples from the quartz monzonite and porphyritic quartz monzonite provide a Re-Os isotope age of 71.7 ± 0.3 Ma. A third sample from a molybdenite vein in Precambrian rocks yields an age of 75.8 ± 0.4 Ma. These molybdenite ages support previous suggestions of two mineralization episodes in the Bagdad deposit. An early event at 76 Ma and a later episode at 72 Ma. Pyrite Os and Re concentrations range between 0.008-0.016 and 3.9-6.8 ppb, respectively. Chalcopyrite contains a wide range of Os (6 to 91 ppt) and Re (1.7 to 69 ppb) concentrations and variable ¹⁸⁷Os/¹⁸⁸Os ratios that range between 0.13 to 22.27. This variability in the chalcopyrite data may be attributed to different copper sources, one of them the Proterozoic volcanic massive sulfides in the district, or to alteration and remobilization of Re and Os. Analyses from two pyrite samples yield an eight point isochron with an age of 77 ± 15 Ma and an initial ¹⁸⁷Os/¹⁸⁸Os ratio of 2.12. This pyrite Re-Os isochron age is in good agreement with the molybdenite ages. We interpret the highly radiogenic initial 1870s/188Os as an indication that the source of Os and, by inference, the ore-forming elements for the Bagdad deposit, was mainly the crust. This conclusion agrees with previous Pb and Nd isotope studies and supports the notion that a significant part of the metals and magmas have a crustal source.