Coordenação de Aperfeiçoamento de Pessoal de Nível Superior / Os gêneros de peixes fósseis Oshunia e Placidichthys são holósteos pertencentes à Ordem Ionoscopiformes e provenientes do Cretáceo Inferior do Brasil, das bacias do Araripe e de Tucano. No clado Ionoscopiformes sensu Grande & Bemis (1998) estão incluídas as famílias Ionoscopidae e Ophiopsidae, todavia as relações internas deste grupo ainda são duvidosas. Oshunia e Placidichthys fazem parte das famílias Ionoscopidae e Ophiopsidae, respectivamente, sendo o gênero Oshunia considerado como mono-específico (cf., O. brevis), enquanto que Placidichthys apresenta duas espécies nominais (cf., P. bidorsalis e P. tucanensis). Em função destas espécies terem sido descritas a partir de poucos espécimes, ainda existiam várias lacunas no conhecimento em relação as mesmas, como, por exemplo, a possibilidade da existência de outras espécies no gênero Oshunia e a falta de informações anatômicas, especialmente do crânio, da região occipital, dos ossos da face e da nadadeira caudal das espécies de Placidichthys. Outro ponto em aberto na literatura era a posição filogenética dos dois gêneros. Frente a estas questões, o objetivo da presente dissertação foi realizar uma revisão anatômica dos gêneros Oshunia e Placidichthys, a fim de ampliar o conhecimento anatômico e taxonômico acerca dos mesmos, além realizar uma análise filogenética da Ordem Ionoscopiformes, baseada em matrizes de caracteres existentes na literatura, para se obter um melhor posicionamento dessas espécies brasileiras. Em função da facilidade de acesso a material mexicano, também foram incluídos nesta revisão os gêneros Teoichthys e Tuetzalichthys provenientes do Cretáceo da Formação Tlayúa, estes também peixes fósseis holósteos pertencentes à Ordem Ionoscopiformes. Do ponto de vista taxonômico, não foi possível confirmar a existência de novas espécies para o gênero Oshunia, entretanto ficou clara a presença de uma nova espécie pertencente ao gênero mexicano Teoichthys. A presente revisão proporcionou uma série de novas informações sobre a anatomia destas espécies de Ionoscopiformes, tais como a descrição dos ossos circumorbitais e do teto craniano e uma reinterpretação acerca da nadadeira dorsal de Placidichthys bidorsalis, ou ainda sobre a forma do rostral de Teoichthys kallistos. Da mesma maneira, esta revisão também ofereceu novos dados para a construção de uma nova hipótese filogenética para Ionoscopiformes, a qual se mostrou consideravelmente distinta das hipóteses filogenéticas anteriores (cf., relações internas de Ionoscopidae e o posicionamento do gênero Teoichthys). O baixo suporte para grande parte dos clados torna evidente a fragilidade das hipóteses de relacionamento interno do clado Ionoscopiformes, bem como a necessidade de uma revisão mais aprofundada das outras espécies deste grupo e dos caracteres a serem utilizados em futuras análises filogenéticas. / The fossil genera Oshunia and Placidichthys are holosteans, belonging to the Order Ionoscopiformes, from the Early Cretaceous of the Araripe and Tucano basins in Brazil. Ionoscopiformes sensu Grande & Bemis (1998) includes the families Ionoscopidae and Ophiopsidae, however the inner relationships of this clade are still uncertain. Oshunia and Placidichthys belong to the families Ionoscopidae and Ophiopsidae, respectively, and while the genus Oshunia is considered to be monospecific (cf., O. brevis), Placidichthys presents two nominal species (cf., P. bidorsalis and P. tucanensis). Especially due to the fact that these species where described from just a few specimens, there were still several gaps on the knowledge about them, as for example, the possible existence of additional species from the genus Oshunia and the lack of anatomical information, notably from the skull roof, occipital region, check bones, and caudal fin of Placidichthys species. Another debatable matter was the phylogenetic position of these two genera. Given these issues, the objective of the present thesis was to make a revision of the genera Oshunia and Placidichthys, with the aim of increasing the anatomical and taxonomic knowledge about them, and also to make a phylogenetic analysis of Ionoscopiformes, based on data matrixes from the literature, in order to achieve a stronger hypothesis over the relationships of these Brazilian genera. Granted the easy access to Mexican specimens from the Cretaceous of the Tlayúa Formation, the genera Teoichthys and Quetzalichthys were also reviewed on the present work. From a taxomomical point of view, it was not possible to conclude over the existence of new species from the genus Oshunia, however it was evident the presence of a new species belonging to the Mexican genus Teoichthys. The present revision brought a series of new information over the anatomy of these Ionoscopiformes species, such as a first description of the circumorbital and skull roof bones and a reinterpretation over the dorsal fin of Placidichthys bidorsalis, or about the shape of the rostral bone of Teoichthys kallistos. Likewise, this revision also offered new data for the construction of a new phylogenetic hypothesis for Ionoscopiformes, which was considerably distinct from the anterior ones (cf., inner relationships of Ionoscopidae and the placement of the genus Teoichthys). The low support for many clades makes evident the fragility of the phylogenetic hypotheses of Ionoscopiformes, as well as the necessity of a more detailed revision of other species from this group and also of the characters to be used on future phylogenetic analyses.

PhD (Geology) / Department of Mining and Environmental Geology / Cretaceous-Tertiary Periods marked the break-up of Gondwana, a large landmass composed of most of the present-day southern continents. In understanding the events of the supercontinental break-up, paleoenvironmental studies need to be carried out. In such studies, kaolinites could be used as paleoenvironmental proxies due to their small particle sizes and large surface area. It is in this context that this research sought to reconstruct the paleoenvironments in which selected Cretaceous-Tertiary kaolin deposits in the Douala Sub-Basin in Cameroon formed. To achieve this objective, mineralogical and geochemical characterisations were carried out using x-ray diffractometry, scanning electron microscopy, Fourier transform infrared spectrometry, thermal analyses and x-ray fluorescence spectroscopy. Trace elements and stable isotopes were analysed using mass spectrometries. Ages of zircons in the kaolins were determined using laser ablation magnetic sector-field inductively coupled plasma mass spectrometry (LA-SF-ICP-MS) U-Pb geochronology. Diagnostic evaluation for industrial applications of the kaolins were carried out using particle size distribution, texture, moisture content, pH, and electric conductivity. Six kaolin deposits from Cretaceous-tertiary Formations of the Douala Sub-Basin were studied; namely, Bomkoul (Tertiary), Dibamba (Tertiary), Ediki (Cretaceous), Logbaba (Cretaceous), Missole (Tertiary) and Yatchika (Cretaceous). The nature and occurrences of these kaolin deposits in Cameroon were determined through thorough mineralogical and geochemical characterisations of bulk (< 2 mm size fraction), silt (2-63 μm size fraction) and clay samples (< 2 μm size fraction). By quantifying the mineral phases present, the morphology and the functional groups in the kaolins are presented as the mineralogical characteristics of kaolins of each study site; whereas, the major oxides geochemistry and the micro-elemental composition constitute the geochemical characteristics of these kaolins. The minerals’ geneses were also determined and the prevailing paleoenvironmental and paleoclimatic conditions in which they were formed were reconstructed using trace elements and stable isotopes of oxygen and hydrogen in kaolinite. The maximum age of the kaolins were determined using U-Pb LA-SFICP-MS dating of zircons in the kaolin deposits. Diagnostic evaluation of the kaolins was carried out, and involved the determination of physical characteristics (particle size, texture, colour and moisture content) and physico-chemical characteristics (pH and electrical conductivity). Results showed that kaolinite and quartz (as major phases), smectite and/or illite (as minor phases), anatase and rutile (as minor or trace phases), goethite and hematite (as trace viii phases) were the mineral phases present in bulk and silt samples. Whereas, in the < 2 μm fractions, the mineral phases are made up of kaolinite and smectite (as major phases), smectite and/or illite (as minor phases), anatase and rutile (as minor or trace phases), goethite and hematite (as trace phases). The kaolins are mostly made up of thin platy or pseudo-hexagonal particles or flakes, books or stacks of kaolinite. The Dibamba, Logbaba and Missole II kaolins have well-ordered structures. Exothermic peak temperatures were generally between 943-988oC. The most abundant major oxides are silica and alumina, followed by iron oxide and titania; though Logbaba and Missole II had higher titania than iron oxide. 85% of the kaolins, portrayed extreme silicate weathering (chemical index of alteration > 80%) and are compositionally mature (index of compositional variability > 0.78). The geochemical composition of the kaolins showed that source rocks of these kaolins vary between rhyolite/granite and rhyolite/granite + basalt. The geochemistry also suggested that the kaolins formed in a marine environment (except Logbaba samples). Trace elements results revealed that Cretaceous-Tertiary kaolins in the Douala Sub-Basin are mainly enriched in rare earth elements compared to the upper continental crust, and have negative Eu anomaly. Large ion lithophiles (mainly Rb and U) were highly enriched in samples, high field strength elements (Y and Nb) were enriched in studied samples of all fractions; and transition trace elements generally had concentrations quite similar to upper continental crust values. Stable isotopes showed that the kaolins were formed in a supergene environment; and temperatures of kaolinitisation (assuming equilibrium with the global meteoric water line) were 26.58oC ± 9.65oC for Cretaceous kaolins and 29.40oC ± 7.22oC for Tertiary kaolins. Assuming equilibrium with the local (Douala) meteoric water line, the temperatures of kaolinitisation were 24.64oC ± 9.48oC for Cretaceous and 27.42oC ± 7.08oC for Tertiary kaolins. Four main zircon populations were identified from radiogenic dating: the 1st between 550 and 650 Ma, the 2nd between 950 and 1050 Ma, the 3rd around 1600 Ma and the 4th between 2800-3200 Ma. These four zircon populations belong to the Proterozoic (Neo-, Meso- and Paleoproterozoic) and the Archean. The maximum depositional ages of the kaolins, reflected by the youngest weighted averages of zircon populations varied between 588 ± 2 Ma and 612 ± 2 Ma, all belonging to the Ediacaran Period (Neoproterozoic). The diagnostic evaluation of the kaolins revealed that the kaolins are very sandy, with 50% of the samples having a sandy loamy clay or sandy loam texture. The colour of the samples varied considerably from white to darker colours (dark grey); with 15% of the kaolins being light reddish brown. The moisture content was generally very low (< 2 wt %) in all size fractions, except in Yatchika samples (moisture content > 2 wt %). The kaolins are generally acidic, with ix a pH(KCl) varying between 3.06 and 3.81, except in Missole I samples, which had a pH (KCl) < 2. The electrical conductivity (EC) generally varied between 20 to ~ 50 μS/cm, except Dibamba and MSL II 01 samples which had EC values in the interval 50 μS/cm < EC < 80 μS/cm; and Missole I samples having an EC > 7500 μS/cm. In conclusion, no great distinction was found between Cretaceous and Tertiary kaolins of the Douala Sub-Basin based on their mineralogy and geochemistry. The best kaolins in terms of these characteristics, and in comparison with the Georgia Kaolins (known for their high kaolinite quality), were the Dibamba (Tertiary), Logbaba (Cretaceous) and Missole II (Tertiary) kaolins. Based on their compositional maturity and mineralogical characteristics, these three kaolins are considered to be second cycle sediments; unlike Bomkoul, Yatchika and Ediki kaolins, which are believed to be first cycle sediments. Based on the trace elements and stable isotopes composition, Cretaceous and Tertiary kaolins of the Douala Sub-Basin were derived from felsic rocks. However, Cretaceous kaolins were formed in a cooler anoxic reducing environment; whereas the Tertiary kaolins were formed in a warmer oxidising environment, with higher precipitation. Ages of zircons in Cretaceous-Tertiary kaolins suggested that the zircon formed during two main tectonic events: the Eburnean orogeny, during which older zircons crystallised and the Pan-African orogeny, during which younger zircons crystallised. The maximum depositional ages of the kaolins varied between 588 ± 2 Ma and 612 ± 2 Ma. The main identified sources of these zircons are the Archean Ntem Complex, the Paleoproterozoic Nyong Group and the Neoproterozoic Yaounde Group. The diagnostic evaluation indicated that the particle size greatly influences the mineralogy and geochemistry of the kaolins because the finer particles (< 2 μm) have higher amounts of kaolinite and Al2O3. The moisture content of the kaolins makes them suitable as paint fillers and in soap production. Paper coating, paper filler, ceramics, pharmaceutics and cosmetics are potential applications for the kaolins, though particle size reduction and beneficiation will give them a higher quality. However, because these kaolin deposits are not big and extensive, they cannot be recommended for large scale industrial applications; but they can be used for bricks, pottery and stoneware manufacturing.

The presented PhD thesis is compiled as a commentary to four published papers, which deal with planktonic assamblages of the Upper Jurassic and Cretaceous, namely with calcareous nannofossils and calpionellids. The first part of the dissertation thesis describes the main characteristics of the studied fossil groups with focus on their morphology, palaeoecology, evolution and systematics. The chapter of calcareous nannoplankton gives special attention to the biostratigraphicaly important genus Nannoconus Kampter 1931. Next chapters describe the methods of the laboratory processing of the sediments and the geological settings of the studied areas. The thesis is focused on two areas. At first the selected localities in the Bohemian Cretaceous Basin, i.e. Upper Turonian and Upper Coniacian, are described. Generally, the Upper Cretaceous platform sediments of the middle European basins are rich in calcareous nannoplankton. These fossils represent important marker for biostratigraphical and palaeoecological interpretations. The second part describes carbonate rocks of the Upper Jurassic and Lower Cretaceous of the Tethyan area. In this case, calcareous nannoplankton and calpionellids are an essential part of the modern multidisciplinary form of the Jurassic- Cretaceous (J/K) boundary interval research....

No description available.

No description available.

No description available.

No description available.

Heightened industry focus on the Upper Cretaceous (Cenomanian-Turonian) Eagle Ford has resulted from recent discoveries of producible unconventional petroleum resource in this emerging play. However, little has been published on the facies and facies variabilities within this mixed carbonate-clastic mudrock system. This rock-based study is fundamental to understanding the controls, types, and scales of inherent facies variabilities, which have implications for enhanced comprehension of the Eagle Ford and other mixed carbonate-clastic mudrock systems worldwide. This study utilizes 8 cores and 2 outcrops with a total interval equaling 480 feet and is enhanced by synthesis of thin section, XRD, XRF, isotope, rock eval/TOC, and wireline log data. Central Texas Eagle Ford facies include 1) massive argillaceous mudrock, 2) massive argillaceous foraminiferal mudrock, 3) laminated argillaceous foraminiferal mudrock, 4) laminated foraminiferal wackestone, 5) cross-laminated foraminiferal packstone/grainstone, 6) massive bentonitic claystone, and 7) nodular foraminiferal packstone/grainstone. High degrees of facies variability are observed even at small scales (50 ft) within the Eagle Ford system and are characterized by pinching and swelling of units, lateral facies changes, truncations, and locally restricted units. Facies variability is attributed to erosional scouring, productivity blooms, bottom current reworking, and bioturbation. At the 10-mile well spacing scale and greater, the data significantly overestimates intra-formational facies continuity but is successful in defining the following four-fold stratigraphy: The basal Pepper Shale is an argillaceous, moderate TOC, high CGR and GR mudrock. The Waller Member is a newly designated name used in this study for an argillaceous and foraminiferal, high TOC, massive mudrock with a generally moderate CGR and GR profile. The Bouldin Member is a high energy, carbonate-rich (foraminiferal), low TOC, low and variable CGR but high GR zone. Finally, the South Bosque Formation is an argillaceous and foraminiferal, moderate TOC, massive and laminated mudrock with a moderate CGR and GR signature. GR logs alone are inadequate for determination of facies, TOC content, depositional environment, and sequence stratigraphic implications. Using integrated lithologic, isotopic, and wireline log data, cored wells in the study area are correlated across the San Marcos Arch. Geochemical proxies (enrichment in Mo, Mn, U, and V/Cr) indicate that maximum basin restriction occurred during deposition of the Bouldin Member. Bottom current activity influenced depositional processes and carbonate sediment input was driven by water column productivity. These primary controls on Eagle Ford stratigraphy and character are independent from eustatic fluctuation, rendering classical sequence stratigraphy unreliable. / text

In this thesis I document the biostratigraphy of two Cretaceous sections in Pakistan, the Chichali Nala Section and the Moghal Kot Section. Furthermore, I document the stratigraphy of the so-called Oceanic Anoxic Events (OAEs) in the Moghal Kot Section. In addition, I establish potential links between the planktonic foraminiferal evolution and these OAEs in the Moghal Kot Section. Sea Surface Temperatures (SSTs) are established for the Valanginian time by using the TEX86 and δ18O proxies in the Chichali Nala Section. The new biostratigraphy of the Chichali Nala Section shows that the ages of the sediments are mainly Valanginian. The biostratigraphy of the Moghal Kot Section show ranges in age from the Early Aptian to Early Maastrichtian. Seven OAEs were recorded in the Moghal Kot Section based on the combined study of biostratigraphy, microfacies, and δ13C analysis. These OAEs correlate well with previously documented OAEs elsewhere, therefore the new record of the OAEs in the Moghal Kot Section confirms the widespread occurrence of these events, possibly all global in nature. A quantitative review of the planktonic foraminiferal evolution in the Moghal Kot Section indicates that the environmental changes along the OAE2 have strongly forced the evolution of the planktonic foraminifera. Conversely, no clear relationship is observed between other OAEs and planktonic foraminiferal evolution in the same section. The SST results based on the TEX86 in the Chichali Nala Section show that the surface ocean was consistently much warmer (10-12 oC) than today at the paleolatitude of ~-35o during the Valanginian time. Such warm conditions are also supported by the spore and pollen assemblages of the Chichali Nala Section. Collectively the two datasets indicate strongly that the Valanginian world was overall extremely warm. Such warming during the Valanginian is incompatible with previously suggested cooler conditions during this time period.

The applications of calcium-isotope measurements in marine carbonates are explored in several different contexts within this thesis. As a record of global ion fluxes, seawater calcium-isotope ratios can be used as tracers for large weathering imbalances, which develop as a feedback system in response to intervals of climate change. This approach provides valuable constraints on the complex climatic and oceanographic phenomena known as the Oceanic Anoxic Events. Over much longer timescales, the calcium-isotope ratio of seawater is influenced by steady-state processes that reflect the evolution of seawater chemistry. To understand these influences, the modern calcium-isotope budget is assessed quantitatively using a compilation of marine carbonate samples, revealing several distinctive components of the carbonate burial sink that can affect the steady-state balance of the calcium cycle. Changes in the major ion composition of seawater and in the organisms that contribute to sedimentary carbonate burial are shown to contribute significantly to the geological record of seawater calcium-isotope ratios. The importance of skeletal carbonate in the calcium cycle leads to another application of calcium isotopes towards understanding biomineralization. This large and complex topic is approached with calcium-isotope data from two unique growth experiments that constrain some of the mechanisms by which biogenic aragonite acquires its geochemical signatures. This range of topics presents a diverse, but by no means exclusive, sample of the topics that are accessible for investigation through calcium-isotope analysis. The potential of this isotopic tool is demonstrated by the breadth of environments and timescales represented in this work.