Bimodal and nanocrystalline aluminum alloys are being investigated as stronger replacements for conventional polycrystalline aluminum alloys. Higher strengths are achieved by reducing the grain size of a metal; however, as the grain size is reduced the ductility diminishes. One solution that limits this decrease in ductility is the addition of a few microcrystalline grains into a nanocrystalline alloy, creating a bimodal microstructure that offers a better balance of strength and ductility. Two- and three-dimensional microstructural finite element (FE) simulations of monotonic and fatigue failures in Al-5083 having bimodal grain structures are conducted. To reduce the computational time and facilitate the modeling of microstructural features, a global-local model is developed. Macroscopic linear elastic and nonlinear plastic properties for each of the bimodal compositions are first used to simulate the tensile and fatigue tests in a global FE model. Subsequently, a local model that represents a single element at the center of the global model is built with distinct coarse grains (CGs) distributed throughout an ultra-fine grain (UFG) matrix. Ten percent of the elements in this model are defined as CGs, after which nanocrystalline and polycrystalline properties are assigned to the UFG and CG regions, respectively. Available fatigue test data is utilized to generate a low cycle fatigue damage model for bimodal grains size Al-5083 and obtain the damage model constants for varied levels of coarse grains. This fatigue damage model is then used in conjunction with a finite element continuum damage modeling approach, namely, successive initiation, to predict the damage and crack initiation sites and propagation paths in bimodal grains size alloys. The successive initiation method is used to continually accumulate damage in elements and initiate and propagate the crack through grains that reach the failure criteria defined for monotonic and cyclic loading. It is observed from the monotonic FE model that cracks initiate on the boundaries between CGs and UFGs then propagate through the UFG matrix around the CG until they become large enough to extend into the CGs themselves. In the cyclic FE models, the crack is observed to initiate in a CG and propagate along the CG and the surrounding UFG matrix.

Current degradable orthopedic fixation devices do not typically facilitate tissue integration during healing. Proposed here is a novel combination of processing methods to enhance the tissue integration capability of degradable thermoplastics used in temporary orthopedic fixation devices. The provision of open pores in devices used to affix reconstructed hard tissues would allow for local cells to infiltrate during the healing process. Any openly porous structure is inherently weakened in comparison to its monolithic peers (i.e. decreased relative bulk modulus), such that the matrix materials must be made more resilient in keep the device from becoming friable. These processing methods aim to improve degradable surgical fixation devices at multiple levels of design: both through the inclusion of porous morphology, processing changes, and additives to regain mechanical integrity. Biomimetic pores are added for cellular infiltration by dissolving a porogen’s interpenetrating polymer network. The addition of open pores significantly reduces the bulk stiffness. More uniform phase separation has led to better pores, but the objects still need more resilience. Carbon nanomaterials are used to improve on the mechanics and surface chemistry of the polymer matrix material, composites of polylactide/nanodiamond are produced through cryogenic milling and solid state polycondensation. The addition of minute amounts of functionalized nanodiamond has remedied the brittle failure of the material, by cryogenic milling and solid state polycondensation of poly((D,L)lactide-co-glycolide) and hydroxyl functionalized detonation nanodiamonds. This composite has also demonstrated increased cytocompatability with 7F2 osteoblasts, as analyzed by cellular adhesion through fluorescence microscopy and alamar blue assay. / Bioengineering

Ball milling has been shown to produce nanostructures in metal powders through severe repetitive deformation. Ball milling at cryogenic temperatures (cryomilling) is more effective in this capacity due to the low temperature by slowing recovery and minimizing diffusion distances between different components. Nanostructured metals are of interest because of their unique physical and mechanical properties. The result of cryomilling is powder consisting of crystallites on the order of 30 – 50 nm. In order to characterize the properties of this material, it is often necessary to consolidate the powder, which is often difficult without causing significant grain growth. In this work, aluminum-rich and magnesium-rich alloys of varying composition are produced by cryomilling and characterized by x-ray diffraction. A novel consolidation process called high shear powder consolidation (HSPC) is used to densify as-received and as-milled powders with minimal growth. The construction of a cryomill, along with a modification for improving process yield, has provided a platform for the study of nanocrystalline metals. It has been shown that bulk nanocrystalline materials are attainable and that alloy composition influences mechanical properties. / Master of Science

The ideal properties of a structural material are light weight with extensive strength and ductility. A composite with high strength and tailorable ductility was developed consisting of nanocrystalline AA5083, boron carbide and coarser grained AA5083. The microstructure was determined through optical microscopy and transmission electron microscopy. A technique was developed to determine the nitrogen concentration of an AA5083 composite from secondary ion mass spectrometry utilizing a nitrogen ionimplanted standard. Aluminum nitride and amorphous nitrogen-rich dispersoids were found in the nanocrystalline aluminum grain boundaries. Nitrogen concentration increased as a function of cryomilling time up to 72hours. A greater nitrogen concentration resulted in an enhanced thermal stability of the nanocrystalline aluminum phase and a resultant increase in hardness. The distribution of the nitrogen-rich dispersoids may be estimated considering their size and the concentration of nitrogen in the composite. Contributions to strength and ductility from the Orowan relation can be more accurately modeled with the quantified nitrogen concentration.