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No description available.

No description available.

Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Earth and Planetary Sciences; and, (B.S.)--Massachusetts Institute of Technology, Dept. of Biology, 1978. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND LINDGREN. / Includes bibliographical references. / B.S. / M.S.

This project included the following goals: 1. To review and assess the geomorphology and lake morphometry of Mountain Lake, Giles County, Virginia with regard to its age and origin. This included production of an updated bathymetric map of Mountain Lake using Sonar imaging of the lake bottom. 2. To evaluate present trophic conditions in the lake waters. This analysis included the first-reported nutrient conditions for input streams to the lake and rainwater. 3. To collect representative "modern" bottom sediment samples and to analyze these sediment samples for sedimentological characteristics, diatoms , and terrestrial pollen. This analysis focussed on present environmental conditions in the lake, and the determination of modern diatom thanatocommunities. 4. To collect complete bottom sediment cores from the lake. Coring was done using a diver-assisted manual coring device designed specifically for this project. 5. To analyze Mountain Lake sediment cores for sedimentology, age determination, and temporal differences in sediment characteristics, diatoms and pollen. This analysis focussed on interpretation and documentation of environmental changes through the lake's history. Primary discharge from the lake presently occurs through a leaky subterranean pathway associated with the deepest, crevice-like portion of the lake. This discharge results in the crevice drain not filling shut with sediment despite its location within the lowest portion of the lake. The lake structure, crevice, and subterranean drain are associated with a regional lineation feature represented in part by the path of Salt Pond Drain and a small input stream ("I-4") to the lake. Initial damming was caused by downdrop of overlying rock. The damming is not complete, and the rate of discharge through time is controlled, in part, by regional tectonic events and by a balance of hydrologic conditions and sedimentation factors. The present lake is generally oligotrophic in nature, with phosphorus representing the major limiting nutrient. Rainfall presently represents the largest source of nutrient to the lake. Present diatom flora in Mountain Lake includes 66 individual taxa, representing 25 genera. Of these, 12 forms or species have not been reported in Virginia inland waters prior to this project. The diatoms reflect the oligotrophic and circumneutral nature of the lake. At least seven diatom thanatocommunities can be defined in the lake, based on taxa, delineated by depth and nutrient conditions. The ratio metric of planktonic to littoral diatoms can be used to estimate past water depths in the lake from bottom sediment. An orange clay layer at 5 cm from the modern sediment/water interface represents human intervention in lake history, namely the hotel and road building in the early 20th Century. The age of the lake is greater than 6000 years. Specific 14C from sediment produced dates of 1860 +100, 4220 +50 and 6160 +70 bp. Within this interval, at least 6 extended periods of low or empty lake level occurred (at approximately 100, 400, 900, 1200, 1800, and 4200 yrs bp). Several of these low intervals are likely to correspond with cool dry conditions co-incident with solar minima events. When the lake has been low or empty, it has tended to develop Sphagnum bog conditions with the low lake surrounded by open or wooded meadows. Terrestrial flora surrounding the lake appears to have remained relatively similar through 6100 years, although red spruce originally accompanied hemlock. / Ph. D.

The Llanos de Mojos is a tropical savanna in the Bolivian Amazon with strong seasonality. Abundant earthworks and anthropogenically shaped landscapes suggest that precolumbian inhabitants had a much larger impact on the region than previously believed. This study examines changes in the hydrological landscapes of the savanna as a proxy for precolumbian land-use practices over time in West Central Mojos. A sediment core from the Quinato Wetland was sampled for diatom analysis. Although diatoms were poorly preserved, they were present and had changing species compositions at different depths. Comparison to other diatom assemblages reported in the Quinato Wetland suggests that the diatom taxa present in individual sediment cores are distinctly shaped by the hydrological conditions at that location rather than the larger scale conditions of the entire wetland. Further diatom analysis could help identify location specific changes in water levels over time to reconstruct the timing of earthwork construction and maintenance. The application of diatom analysis methods to archaeological questions about land-use practices in West Central Mojos has the potential to demonstrate how large-scale human settlements in parts of the Amazon were made possible through the management of landscapes once thought of as untouched by human influence.

published_or_final_version / Botany / Master / Master of Philosophy

The Northern Isles are strongly influenced by changes in the North Atlantic Ocean atmosphere system and, as they project northwards from the British Isles, provide an ideal geographical opportunity to study changing climatic gradients during the last glacial/interglacial transition along with the detection of regime shifts. Three proxies, diatoms, pollen, and micro-XRF sediment chemistry, have been employed to explore the nature and timing of environmental changes within the water columns and the wider catchments of Loch of Sabiston, Orkney, and Loch of Clumlie and Loch of Grimsetter, Shetland to better understand the nature and timing of environmental change within and among the island groups. The records are constrained by radiocarbon dating, supported by tephrochronology, and the Greenland ice core chronology to enable the comparison of the records produced by this study with previous research in the North Atlantic region. The diatom and lithological results from Loch of Sabiston suggest early deglaciation at c. 23,000 cal BP followed by gradual warming (GI-1e) punctuated by the cooling events coeval with GS-1 and GI-1b. However, the pollen record reflects a lagged response in the development from colonising cold tolerant vegetation to more temperate shrub and woodland communities. The Oracadian signal is dominated by the switching on and off of the accumulation of marl which serves as a supporting indicator of warmer conditions. The Shetland landscape appears to have been deglaciated later at c. 16,400 cal BP, but also has clear representation of GI-1e and the cooling events of GI-1b and GS-1. Both the Shetland and Orkney records record the dramatic cooling of the Younger Dryas but also suggest a two stage change from colder and drier to colder and wetter conditions before the onset of the Holocene. Shetland appears to have experienced less extreme climatic changes in comparison to Orkney despite being in the same present phytogeographical region. This is likely due to the former persisting in the arctic domain and the latter being closer to the latitudinal shifts in the warmer ocean circulation of the North Atlantic during the LGIT. Comparison of the three proxies demonstrates that they may differ by several hundred years in their response to dramatic climatic changes and, therefore, highlights the strength of multi-proxy approaches to reconstructing Quaternary environments. Combining proxies such as diatom and μ-XRF scanning techniques will provide a greater understanding of the processes occurring during environmental change in this region.

La distribution stratigraphique des diatomées pyritisées et leur répartition paléogéographique sont étudiées dans les sédiments du Paléocène supérieur et principalement de l’Eocène inférieur des Bassins Danois (Ølst et Hinge), de Dieppe-Hampshire (Saint-Josse et Ailly) et Belge (Knokke). Différents types de fossilisation ont été observés. D’une part, dans un stade précoce de la diagenèse, un moulage du frustule est construit par la croissance de minéraux authigéniques (pyrite et barytine). D’autre part, le frustule siliceux est remplacé épigénitiquement par de la pyrite. Ces deux processus de fossilisation, pouvant coexister, gardent les diatomées identifiables. Une méthodologie fiable et reproductible pour l’extraction de ces dernières a été mise en point. Une évolution des zones de diatomées (zonation) est mise en évidence : quatre zones (D0 à D3) d’association ou d’abondance et deux sous-zones (D3a et D3b) sont reconnues. Cette zonation est établie pour les bassins méridionaux et orientaux du Bassin de la Mer du Nord. Elle est corrélable avec les biozonations de King (1983), Fenner (1985), Mudge & Copestake (1992a) et Mitlehner (1994, 1996) valables pour la partie centrale du Bassin de la Mer du Nord. Les zones D0 à D3 autorisent les corrélations entre les unités lithostratigraphiques des différents bassins étudiés et celui de la Mer du Nord. Cela a permis, entre autres, de corréler les sédiments des faciès sparnaciens du Bassin de Dieppe-Hampshire aux formations de la Mer du Nord. Enfin, les diatomées pyritisées sont un nouvel argument pour encadrer la position de la C.I.E. (dont la base est le critère de reconnaissance de la limite Paléocène-Eocène), celle-ci étant située dans la partie inférieure de la zone D1 sous le pic d’abondance de l’espèce Coscinodiscus morsianus var. moelleri. / The stratigraphic distribution of the pyritized diatoms and their paleogeographic repartition are studied in Upper Paleocene and especially Lower Eocene from the Danish (Ølst Hinge), Dieppe-Hampshire (Saint-Josse and Ailly) and Belgian (Knokke) Basins. Different kinds of fossilisation are observed. In a first step of the diagenesis, a mould of the frustule is built thanks to the growth of authigenic minerals (pyrite and barite). The siliceous skeleton may also be completely replaced epigenetically by pyrite. These two types of fossilisation, that may coexist, keep diatoms identifiable. A reliable and reproducible methodology for the extraction of pyritized diatoms has been developed. The evolution of the diatom zones is underlined : four zones (D0 until D3) of association or abundance are recognized. This zonation is established for the southern and eastern basins of the North Sea Basin. It is interrelated with the biozonations of King (1983), Fenner (1985), Mudge & Copestake (1992a) and Mitlehner (1994, 1996) valid for the central part of the North Sea Basin. The zones D0-D3 allow correlations between the lithostratigraphic units of the various studied basins and the one of the North Sea. This enables among others to correlate the sediments of the sparnacien facies of the Dieppe-Hampshire with the formations of the North Sea. At last, the pyritized diatoms represent a new argument to locate the C.I.E. which base is the criterion for the identification of the Paleocene-Eocene boundary. The C.I.E. is located in the lower part of the D1 zone under the abundance peak of the Coscinodiscus morsianus var. moelleri species.

Diatoms possess characteristics such as abundance, diversity, and high reproductivity, which make their nano-structured frustules (diatom frustules) attractive for a wide range of applications. To overcome the limitation of their silica based frustule composition, diatom frustules have been converted into a variety of materials including silicon, silicon carbide, silver, gold, palladium and carbon in the present study. The compositions and the extent of shape preservation of the replicas are examined and evaluated with different characterization methods such as X-ray diffraction, SEM, TEM and FTIR analyses. These replicas still retained the complex 3D structures and nano-scaled features of the starting diatom frustules. Some properties and possible applications of converted materials are explored and the kinetics and thermodynamics related to the successful replications (conversions) are also studied and discussed.